CAS No.12107-56-1,Dichloro(1,5-cyclooctadiene)palladium(II) Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	12107-56-1
Name:	Dichloro(1,5-cyclooctadiene)palladium(II)
Article Data:	20

Formula:	C₈H₁₂Cl₂Pd
Molecular Weight:	285.509
Synonyms:	Palladium,dichloro(1,5-cyclooctadiene)- (6CI,7CI,8CI);1,5-Cyclooctadiene, palladiumcomplex;(1,5-Cyclooctadiene)palladium dichloride;Dichloro(1,5-cyclooctadiene)palladium;Dichloro(cyclooctadiene)palladium;Dichloro(h4-1,5-cyclooctadiene)palladium;Dichloro[(1,2,5,6-h)-1,5-cyclooctadiene]palladium;NSC 169973;
EINECS:	235-161-8
Melting Point:	210 °C (dec.)(lit.)
Boiling Point:	153.5 °C at 760 mmHg
Flash Point:	31.7 °C
Solubility:	insoluble in water
Appearance:	brown-black crystals
Hazard Symbols:	Xi
Risk Codes:	36/37/38
Safety:	26-37/39
PSA:	0.00000
LogP:	4.05180

Synthetic route

: 1552-12-1, 111-78-4
1,5-cis,cis-cyclooctadiene

: palladium dichloride

: 12107-56-1
dichloro(1,5-cyclooctadiene)palladium(II)

Conditions

Conditions	Yield
Stage #1: palladium dichloride With hydrogenchloride In water Inert atmosphere; Schlenk technique; Stage #2: 1,5-cis,cis-cyclooctadiene In ethanol; water Inert atmosphere; Schlenk technique;	98%
Stage #1: palladium dichloride With hydrogenchloride In ethanol Stage #2: 1,5-cis,cis-cyclooctadiene In ethanol

: palladium dichloride

: 5259-72-3, 10060-40-9, 111-78-4
1,5-dicyclooctadiene

: 12107-56-1
dichloro(1,5-cyclooctadiene)palladium(II)

Conditions

Conditions	Yield
In hydrogenchloride; ethanol for 0.333333h; liquid HCl;	96%
In methanol suspn. of PdCl2 (28.2 mmol) in MeOH reacted with COD (84.6 mmol) for 48 h at room temp. with stirring; filtered off, washed (MeOH), vacuum-dried;	91%
In methanol at 20℃; for 48h;	84%
With hydrogenchloride In water

: 7647-01-0
hydrogenchloride

: palladium dichloride

: 5259-72-3, 10060-40-9, 111-78-4
1,5-dicyclooctadiene

: 12107-56-1
dichloro(1,5-cyclooctadiene)palladium(II)

Conditions

Conditions	Yield
Stage #1: hydrogenchloride; palladium dichloride at 20℃; Inert atmosphere; Stage #2: cyclo-octa-1,5-diene for 0.333333h; Inert atmosphere;	95%

...Expand

: 7647-14-5
sodium chloride

: palladium dichloride

: 5259-72-3, 10060-40-9, 111-78-4
1,5-dicyclooctadiene

: 12107-56-1
dichloro(1,5-cyclooctadiene)palladium(II)

Conditions

Conditions	Yield
In methanol for 19h;	93%

...Expand

: 865-49-6
chloroform-d1

: [Pd(acetonyl)Cl]

: 5259-72-3, 10060-40-9, 111-78-4
1,5-dicyclooctadiene

: 12107-56-1
dichloro(1,5-cyclooctadiene)palladium(II)

: 1042309-89-6
[Pd(acetonyl)Cl(1,5-cyclooctadiene)]

Conditions

Conditions	Yield
In acetone under N2; cyclooctadiene added to suspn. of Pd complex in acetone; detd. by (1)H NMR spectra in CDCl3;

...Expand

: 1042309-89-6
[Pd(acetonyl)Cl(1,5-cyclooctadiene)]

: 12107-56-1
dichloro(1,5-cyclooctadiene)palladium(II)

Conditions

Conditions	Yield
In not given slowly decompd. in chlorinated solvents;

: 12107-56-1
dichloro(1,5-cyclooctadiene)palladium(II)

: 1425562-48-6
1-[N,N’,N’’-trimethyl-(4-butyl)ammonium]-4-(2-pyridyl)-1H-1,2,3-triazolechloride

: 1425725-67-2
[palladium(II) 1-(4-N,N’,N’’-trimethylbutylammonium)-4-(2-pyridyl)-1H-1,2,3-triazoledichloride]chloride

Conditions

Conditions	Yield
In methanol; dichloromethane for 1h;	100%

: 12107-56-1
dichloro(1,5-cyclooctadiene)palladium(II)

: 13954-38-6
tripiperidino-phosphine

: 68494-72-4, 955117-31-4
dichloro{bis[1,1’,1’’-(phosphinetriyl)tripiperidine]}palladium(II)

Conditions

Conditions	Yield
In toluene at 20℃; for 0.166667h;	100%

: 12107-56-1
dichloro(1,5-cyclooctadiene)palladium(II)

: 13170-43-9
(trimethylsilyl)methylmagnesium chloride

: 225931-80-6
bis[(trimethylsilyl)methyl](1,5-cyclooctadiene)palladium(II)

Conditions

Conditions	Yield
In diethyl ether at -25℃; for 1.5h; Inert atmosphere;	100%
In diethyl ether at 0℃; for 0.5h; Inert atmosphere;	72%
In diethyl ether at 0℃; for 0.333333h; Inert atmosphere;	65%

: 12107-56-1
dichloro(1,5-cyclooctadiene)palladium(II)

: [{Fe(κ2-dppe)(η5-C5Me5)(C≡C)PPh2}2][PF6]2

: [{[Fe(κ2-dppe)(η5-C5Me5)(C≡CPPh2)]Pd(μ-Cl)Cl}2][PF6]2

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 1h; Inert atmosphere; Schlenk technique;	100%

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Chemistry

Chemical Name: Dichloro(1,5-cyclooctadiene)palladium(ii)
IUPAC NAME: (1Z,5Z)-cycloocta-1,5-diene,palladium(2+),dichloride
CAS No.: 12107-56-1
EINECS: 235-161-8
Molecular Formula: C₈H₁₂Cl₂Pd
Formula Weight: 285.51 g/mol
Melting Point: 210 °C (dec.)(lit.)
Flash Point: 31.7 °C
Boiling Point: 153.5 °C at 760 mmHg
Sensitive: Hygroscopic
Following is the structure of Dichloro(1,5-cyclooctadiene)palladium(ii) (12107-56-1):

Product Categories about Dichloro(1,5-cyclooctadiene)palladium(ii) (12107-56-1) are Catalysts for Organic Synthesis ; Classes of Metal Compounds ; Homogeneous Catalysts ; Metal Complexes ; Pd (Palladium) Compounds ; Synthetic Organic Chemistry ; Transition Metal Compounds ; Catalysis and Inorganic Chemistry ; Homogeneous Pd Catalysts ; Palladium
The chemical synonymous of Dichloro(1,5-cyclooctadiene)palladium(ii) (12107-56-1) are Dichloro[(1,2,5,6-eta)-1,5-cyclooctadiene]-palladiu ; (1,5-Cyclooctadiene)palladium(ii)chloride ; 1,5-Cyclooctadienepalladium(ii) dichloride ; Dichloro(cycloocta-1,5-diene)palladium(ii) ; Dichloro(eta-cycloocta-1,5-diene)palladium (ii) ; Dichloro(1,5-cyclooctyldiene)palladium(ii)

Safety Profile

Hazard Codes:
Xi: Irritant
Risk Statements about Dichloro(1,5-cyclooctadiene)palladium(ii) (12107-56-1):
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements about Dichloro(1,5-cyclooctadiene)palladium(ii) (12107-56-1):
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39: Wear suitable gloves and eye/face protection.
Attentions:
1. Storage: Store in a cool, dry place. Store in a tightly closed container.
2. Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.