Detail of "12154-84-6"

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CAS Number:
12154-84-6
Name:
Iridium, [(1,2,5,6-h)-1,5-cyclooctadiene](2,4-pentanedionato-kO2,kO4)-
Molecular Structure:
Formula:
C13H19 Ir O2
Molecular Weight:
404.5455
Synonyms:
Iridium,(1,5-cyclooctadiene)(2,4-pentanedionato)- (8CI); Iridium,(2,4-pentanedionato)(1,5-cyclooctadiene)- (7CI); Iridium, [(1,2,5,6-h)-1,5-cyclooctadiene](2,4-pentanedionato-O,O')-;Iridium, [(1,2,5,6-h)-1,5-cyclooctadiene](2,4-pentanedionato-kO,kO')- (9CI); 1,5-Cyclooctadiene, iridium complex;(Acetylacetonato)(1,5-cyclooctadiene)iridium
Density:
g/cm³
Melting Point:
145-150°C (dec.)
Boiling Point:
152 °C at 760 mmHg
Flash Point:
30 °C
Hazard Symbols:
Xi
Risk Codes:
36/37/38
Safety:
26 Details

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(C8H12)Ir(C5H7O Theoretical % Of Metal 48.1 Weight 399.51

Supplier:Colonial Metals [ United Kingdom]

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Supplier:Umicore Advanced Materials [ United States]

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Synthesis and crystal structure of [Ir(acac-C3)(COD)(phen)]: Synthesis and crystal structure of [Ir(acac-C3)(COD)(phen)]. Oro, L. A.; Carmona, D.; Esteruelas, M. A.; Foces-Foces, C.; Cano, F. H. (Dep.There are some reagents with their cas registry numbers 89436-89-5 and 12154-84-6 are used in this study. Quim. Inorg., Univ. Zaragoza, Zaragoza, Spain). J. Organomet. Chem., 258(3), 357-66 (English) 1983. CODEN: JORCAI. ISSN: 0022-328X. DOCUMENT TYPE: Journal CA Section: 29 (Organometallic and Organometalloidal Compounds) Section cross-reference(s): 75 The first Ir(I) C-bonded diketonate complex [Ir(acac-C3)(COD)(phen)] was prepd. by 2 routes. Its reactions with protic acids, [Rh(COD)2]ClO4 and [MCl(COD)]2 (M = Rh, Ir) were investigated. The Ir atom is pentacoordinated, in a distorted pyramidal stereochem., with the N atoms of the phenanthroline and the midpoints of the olefin bonds of the cyclooctadiene in the base, and the apex is occupied by a s-bonded C atom of the acac group at a rather long distance (Ir-C 2.420(6) ?). .