CAS No.122-14-5,Fenitrothion Suppliers

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Molecular Structure:
CAS No.:	122-14-5
Name:	Fenitrothion
Article Data:	14

Formula:	C₉H₁₂NO₅PS
Molecular Weight:	277.238
Synonyms:	Phosphorothioicacid, O,O-dimethyl O-(4-nitro-m-tolyl) ester (6CI,8CI);Phosphorothioicacid, O,O-dimethyl O-(3-methyl-4-nitrophenyl) ester;Accothion;Agria 1050;Agriya 1050;Agrothion;Arbogal;BAY 41831;Bayer 41831;Bayer S5660;CL 47300;CP 47114;Dimethyl 4-nitro-m-tolyl phosphorothionate;EI 47300;ENT 25,715;Fenition;
EINECS:	204-524-2
Density:	1.3227 g/cm³
Melting Point:	3.4 °C
Boiling Point:	349.5 °C at 760 mmHg
Flash Point:	165.2 °C
Solubility:	0.003 g/100 mL in water
Appearance:	brownish-yellow oil
Hazard Symbols:	Xn,N
Risk Codes:	50/53-23-21/22-67-65-38-11
Safety:	2-60-61-45-36/37-62
PSA:	115.41000
LogP:	3.97310

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122-14-5 Application:Fenitrothion
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name Fenitrothion Chemical name O,O-dimethyl O-(3-methyl-4-nitrophenyl) phosphorothioate CAS# 122-14-5 formula C9H12NO5PS Mol
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Chemistry

IUPAC Name: Dimethoxy-(3-methyl-4-nitrophenoxy)-sulfanylidene-λ⁵-phosphane
Synonyms of Fenitrothion (CAS NO.122-14-5): 3-Methyl-4-nitrophenyl dimethyl phosphorothioate ; Accothion ; Agrothion ; Cekutrothion ; Dimethyl (3-methyl-4-nitrophenyl) thiophosphate ; Fenitrothion ; Metathionine ; O,O-Dimethyl O-(3-methyl-4-nitrophenyl) phosphorothioate ; Phenitrothion ; m-Cresol, 4-nitro-, O-ester with O,O-dimethyl
phosphorothioate
CAS NO: 122-14-5
Molecular Formula: C₉H₁₂NO₅PS
Molecular Weight: 277.23
Molecular Structure:
EINECS: 204-524-2
H bond acceptors: 6
H bond donors: 0
Freely Rotating Bonds: 5
Polar Surface Area: 115.41 Å²
Index of Refraction: 1.57
Molar Refractivity: 66.55 cm³
Molar Volume: 202.7 cm³
Surface Tension: 54 dyne/cm
Density: 1.367 g/cm³
Flash Point: 165.2 °C
Enthalpy of Vaporization: 57.06 kJ/mol
Boiling Point: 349.5 °C at 760 mmHg
Vapour Pressure: 9.44E-05 mmHg at 25°C
Melting Point: 3.4°C
Storage temp: APPROX 4°C
Water Solubility: 0.003 g/100 mL
Appearance: Brownish-yellow oil
Product Categories: INSECTICIDE;Herbicides;OrganophorousPesticides&Metabolites;Urea structure;Alpha sort;E-GAlphabetic;Pesticides&Metabolites;Alphabetic;F;FA - FLPesticides;Insecticides;Organophorous

Uses

Fenitrothion (CAS NO.122-14-5) is an organophosphate insecticide.

Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
bird - wild	LD50	oral	11mg/kg (11mg/kg)		Archives of Environmental Contamination and Toxicology. Vol. 12, Pg. 355, 1983.
cat	LD50	oral	142mg/kg (142mg/kg)		Agricultural and Biological Chemistry. Vol. 25, Pg. 605, 1961.
cattle	LD50	unreported	217mg/kg (217mg/kg)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY) BEHAVIORAL: EXCITEMENT	Indian Journal of Animal Sciences. Vol. 49, Pg. 314, 1979.
chicken	LD50	oral	280mg/kg (280mg/kg)	PERIPHERAL NERVE AND SENSATION: FLACCID PARALYSIS WITHOUT ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD	Toxicology and Applied Pharmacology. Vol. 11, Pg. 49, 1967.
duck	LD50	oral	1190mg/kg (1190mg/kg)		Toxicology and Applied Pharmacology. Vol. 47, Pg. 451, 1979.
duck	LD50	skin	504mg/kg (504mg/kg)		Toxicology and Applied Pharmacology. Vol. 47, Pg. 451, 1979.
guinea pig	LD50	intravenous	112mg/kg (112mg/kg)		Agricultural and Biological Chemistry. Vol. 27, Pg. 669, 1963.
guinea pig	LD50	intravenous	112mg/kg (112mg/kg)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD LUNGS, THORAX, OR RESPIRATION: DYSPNEA	Agricultural and Biological Chemistry. Vol. 27, Pg. 669, 1963.
guinea pig	LD50	oral	500mg/kg (500mg/kg)		"Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel," Perkow, W., Berlin, Verlag Paul Parey, 1971-1976Vol. -, Pg. -, 1971/1976.
mammal (species unspecified)	LD50	unreported	142mg/kg (142mg/kg)		"Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971Vol. -, Pg. 330, 1971.
man	LDLo	oral	429uL/kg (0.429mL/kg)	BEHAVIORAL: COMA LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION GASTROINTESTINAL: OTHER CHANGES	Human Toxicology. Vol. 6, Pg. 403, 1987.
mouse	LD50	intracrebral	1gm/kg (1000mg/kg)		Pesticide Biochemistry and Physiology. Vol. 8, Pg. 302, 1978.
mouse	LD50	intraperitoneal	280mg/kg (280mg/kg)		Agricultural and Biological Chemistry. Vol. 25, Pg. 605, 1961.
mouse	LD50	oral	229mg/kg (229mg/kg)		Toho Igakkai Zasshi. Journal of Medical Society of Toho University. Vol. 25, Pg. 635, 1978.
mouse	LD50	skin	2500mg/kg (2500mg/kg)		Agricultural and Biological Chemistry. Vol. 25, Pg. 605, 1961.
mouse	LD50	subcutaneous	1gm/kg (1000mg/kg)		Agricultural and Biological Chemistry. Vol. 25, Pg. 605, 1961.
mouse	LD50	unreported	470mg/kg (470mg/kg)		Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 7(5), Pg. 38, 1963.
quail	LD50	oral	56200ug/kg (56.2mg/kg)		Archives of Environmental Contamination and Toxicology. Vol. 12, Pg. 355, 1983.
rabbit	LD50	skin	1250mg/kg (1250mg/kg)		Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 31(10), Pg. 12, 1966.
rat	LC50	inhalation	378mg/m3/4H (378mg/m3)	BEHAVIORAL: TREMOR BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY) LUNGS, THORAX, OR RESPIRATION: DYSPNEA	Egeszsegtudomany. Vol. 24, Pg. 173, 1980.
rat	LD50	intraperitoneal	300mg/kg (300mg/kg)	AUTONOMIC NERVOUS SYSTEM: OTHER (DIRECT) PARASYMPATHOMIMETIC LUNGS, THORAX, OR RESPIRATION: FIBROSIS (INTERSTITIAL)	Toxicology and Applied Pharmacology. Vol. 63, Pg. 91, 1982.
rat	LD50	intratracheal	950mg/kg (950mg/kg)	AUTONOMIC NERVOUS SYSTEM: OTHER (DIRECT) PARASYMPATHOMIMETIC LUNGS, THORAX, OR RESPIRATION: FIBROSIS (INTERSTITIAL) BEHAVIORAL: TREMOR	Toxicology and Applied Pharmacology. Vol. 63, Pg. 91, 1982.
rat	LD50	intravenous	33mg/kg (33mg/kg)		Agricultural and Biological Chemistry. Vol. 27, Pg. 669, 1963.
rat	LD50	intravenous	33mg/kg (33mg/kg)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD LUNGS, THORAX, OR RESPIRATION: DYSPNEA	Agricultural and Biological Chemistry. Vol. 27, Pg. 669, 1963.
rat	LD50	oral	250mg/kg (250mg/kg)		Journal of Economic Entomology. Vol. 61, Pg. 743, 1968.
rat	LD50	skin	1002mg/kg (1002mg/kg)		Arquivos do Instituto Biologico, Sao Paulo. Vol. 37, Pg. 219, 1970.
rat	LD50	subcutaneous	1300mg/kg (1300mg/kg)		Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 13, Pg. 401, 1988.
rat	LD50	unreported	290mg/kg (290mg/kg)		Nippon Yakurigaku Zasshi. Japanese Journal of Pharmacology. Vol. 74, Pg. 41P, 1978.
women	TDLo	oral	800mg/kg (800mg/kg)	GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" GASTROINTESTINAL: NAUSEA OR VOMITING LUNGS, THORAX, OR RESPIRATION: DYSPNEA	Archives of Toxicology. Vol. 56, Pg. 136, 1984.

Safety Profile

Safety Information about Fenitrothion (CAS NO.122-14-5):
Hazard Codes: Harmful Xn Dangerous N, Toxic T,F
Risk Statements: 50/53-23-21/22-67-65-38-11
R11: Highly flammable.
R21/22: Harmful in contact with skin and if swallowed.
R23 : Toxic by inhalation.
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65: Harmful: may cause lung damage if swallowed.
R67: Vapours may cause drowsiness and dizziness.
Safety Statements: 2-60-61-45-36/37-62
S2: Keep out of the reach of children.
S36/37: Wear suitable protective clothing and gloves.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S60: This material and its container must be disposed of as hazardous waste.
S61: Avoid release to the environment. Refer to special instructions / safety data sheets.
S62: If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label.
RIDADR: 3018
RTECS: TG0350000
HazardClass: 6.1(b)
PackingGroup: III

Specification

Health Hazard: Fenitrothion is an organophosphate insecticide. It is a highly toxic cholinesterase inhibitor, that acts on the nervous system. Does not cause delayed neurotoxicity and contact produces little irritation.
Fire Hazard: When heated to decomposition, Fenitrothion emits very toxic fumes of oxides of nitrogen, phosphorus and sulfur. Decomposition at 212-284F produces a mixture of organophosphorus polymers. Unstable in alkaline media. Stable for 2 years if stored at 68-77F. Do not store above 104F.