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| CAS No.: | 122-42-9 |
|---|---|
| Name: | Propham |
| Article Data: | 73 |
| Molecular Structure: | |
|
|
|
| Formula: | C10H13NO2 |
| Molecular Weight: | 179.219 |
| Synonyms: | Carbamicacid, phenyl-, 1-methylethyl ester (9CI);Carbanilic acid, isopropyl ester(6CI,8CI);Agermin;Birgin;Chem-Hoe;Collavin;IFK;INPC;IPC;IPPC;Isopropylcarbanilate;Isopropyl phenylcarbamate;Isopropyl phenylurethane;N-Phenyl-O-isopropylurethane;NSC 2105;O-Isopropyl N-phenylcarbamate;Profam;Propham;Tixit;Tuberit;Tuberite;Y 2; |
| EINECS: | 204-542-0 |
| Density: | 1.104 g/cm3 |
| Melting Point: | 90 °C |
| Boiling Point: | 221.35 °C at 760 mmHg |
| Flash Point: | 87.67 °C |
| Solubility: | 250mg/L |
| Appearance: | Colorless crystalline solid |
| Hazard Symbols: |
 F, T, Xn
|
| Risk Codes: | 36/37/38-39/23/24/25-23/24/25-11-22 |
| Safety: | 26-36-45-16-7 |
| Transport Information: | UN 1230 3/PG 2 |
| PSA: | 38.33000 |
| LogP: | 2.71650 |
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Chemistry
Chemistry informtion about Carbanilic Acid Isopropyl Ester (CAS NO.122-42-9) is:
IUPAC Name: Propan-2-Yl N-Phenylcarbamate
Synonyms: Propham ; Phenylcarbamic Acid 1-Methylethyl Ester ; O-Isopropyl N-Phenylcarbamate ; Tuberite ; 1-Methylethyl Phenylcarbamate ; 1-Methylethylphenylcarbamate[Qr] ; Agermin ; Ban-Hoe
MF: C10H13NO2
MW: 179.22
EINECS: 204-542-0
Density: 1.104 g/cm3
Melting Point: 90°C
Flash Point: 87.7 °C
Boiling Point: 221.4 °C at 760 mmHg
Vapour Pressure: 0.108 mmHg at 25°C
Enthalpy of Vaporization: 45.78 kJ/mol
Storage temp.: APPROX 4°C
Merck: 13,7908
Product Categories: N-PPesticides&Metabolites ; Plant growth regulatorsAlphabetic ; Alpha sort ; CarbanilatePesticides&Metabolites ; Herbicides ; P Pesticides ; Pesticides&Metabolites ; PON - PT
Following is the molecular structure of Carbanilic Acid Isopropyl Ester (CAS NO.122-42-9) is:
Uses
Carbanilic Acid Isopropyl Ester (CAS NO.122-42-9) can be used as herbicide, plant growth regulator.
Toxicity Data With Reference
| 1. | cyt-omi 550 µmol/L | JCLBA3 Journal of Cell Biology. 63 (1974),84. | ||
| 2. | sce-hmn:lym 2 mg/L | MUREAV Mutation Research. 147 (1985),296. | ||
| 3. | orl-hmn LDLo:714 mg/kg | CRSBAW Comptes Rendus des Seances de la Societe de Biologie et de Ses Filiales. 175 (1981),496. | ||
| 4. | orl-rat LD50:1000 mg/kg | RREVAH Residue Reviews. 10 (1965),97. | ||
| 5. | ipr-rat LD50:600 mg/kg | CRSBAW Comptes Rendus des Seances de la Societe de Biologie et de Ses Filiales. 175 (1981),496. | ||
| 6. | orl-mus LD50:2160 mg/kg | 85GMAT Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,79. | ||
| 7. | ipr-mus LD50:200 mg/kg | NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) AD277-689 . | ||
| 8. | unr-mam LD50:1000 mg/kg | 30ZDA9 Chemistry of Pesticides .Melnikov, N.N.,New York, NY.: Springer-Verlag,1971,199. |
Consensus Reports
IARC Cancer Review: Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 , 1987,p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 12 , 1976,p. 189.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.
Safety Profile
Poison by intraperitoneal route. Moderately toxic to humans by ingestion. Moderately toxic experimentally by ingestion and possibly other routes. An experimental teratogen. Human mutation data reported. Questionable carcinogen with experimental neoplastigenic data. An herbicide. When heated to decomposition it emits toxic fumes of NOx. See also CARBAMATES.
Hazard Codes:
F
T
Xn
Risk Statements:
R36/37/38:Irritating to eyes, respiratory system and skin.
R39/23/24/25:Toxic by inhalation, in contact with skin and if swallowed and danger of very serious irreversible effects.
R11:Highly flammable.
R22:Harmful if swallowed.
Safety Statements:
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S16:Keep away from sources of ignition.
S7:Keep container tightly closed.
RIDADR: UN 1230 3/PG 2
RTECS: FD9100000
Specification
Carbanilic Acid Isopropyl Ester (CAS NO.122-42-9) is a carbamate ester. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates.