Detail of "12317-46-3"

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CAS Number:
12317-46-3
Name:
Palladium, [(2,3,5,6-h)-bicyclo[2.2.1]hepta-2,5-diene]dichloro-
Molecular Structure:
Formula:
C₇H₈Cl₂Pd
Molecular Weight:
269.46
Synonyms:
Palladium,dichloro(2,5-norbornadiene)- (6CI,7CI,8CI);Bicyclo[2.2.1]hepta-2,5-diene,palladium complex;Bicyclo[2.2.1]hepta-2,5-diene(dichloro)palladium;Dichloro(norbornadiene)palladium;Dichloro(norbornadiene)palladium(II);NSC176915;Norbornadiene palladium dichloride;(Bicyclo[2.2.1]hepta-2,5-diene)dichloropalladium(II);
EINECS:
235-583-2
Melting Point:
260 °C (dec.)(lit.)
Boiling Point:
89.5 °C at 760 mmHg
Hazard Symbols:
Xi
Risk Codes:
36/37/38
Safety:
26-37/39 Details

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Dichloro(norbornadiene)palladium(II), 99%

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PdCl2(C7H8)

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Phase-transfer-catalyzed synthesis of iminoaziridines and preparation of their palladium dichloride complexes: Phase-transfer-catalyzed synthesis of iminoaziridines and preparation of their palladium dichloride complexes. Schuchardt, Ulf; Ortellado G. Zelada, Luis A. 12317-46-3 and 88967-66-2 are also occured in this study. (Inst. Quim., Univ. Estadual Campinas, Campinas 13100, Brazil). J. Chem. Res., Synop., (10), 270-1 (English) 1983. CODEN: JRPSDC. ISSN: 0308-2342. DOCUMENT TYPE: Journal CA Section: 27 (Heterocyclic Compounds (One Hetero Atom)) Section cross-reference(s): 78 Treatment of PhN:C(NHR)CMe2Br (R = Me, Ph) with KOH and PhCH2N+Et3 Cl- in Et2O at -60° for 2 h, and 25° for 4 h, resp., gave the corresponding aziridines I in 50 and 63% yield, resp. I with (PhCN)2PdCl2 in C6H6 at 25° for 24 and 8 h, resp., gave imino N-coordinated I2PdCl2 in 95 and 66% yield, resp. .