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124-48-1

Basic Information
CAS No.: 124-48-1
Name: CHLORODIBROMOMETHANE
Article Data: 30
Molecular Structure:
Molecular Structure of 124-48-1 (CHLORODIBROMOMETHANE)
Formula: CHBr2Cl
Molecular Weight: 208.28
Synonyms: Dibromochloromethane;Dibromomonochloromethane;Monochlorodibromomethane;
EINECS: 2810
Density: 2.504 g/cm3
Melting Point: -2 °C(lit.)
Boiling Point: 117.137 °C at 760 mmHg
Flash Point: 19.839 °C
Solubility: Not miscible or difficult to mix in water.
Appearance: clear light yellow to orange liquid
Hazard Symbols: HarmfulXn, IrritantXi, ToxicT
Risk Codes: 22-39/23/24/25-23/24/25
Safety: 45-36/37/39-26-36/37
Transport Information: UN 2810
PSA: 0.00000
LogP: 2.29860
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    Package:5, 10, 50 g in glass bottle Application:Affords bromochlorocarbene under phase-transfer conditions.

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Chemistry

IUPAC: Dibromo(chloro)methane (124-48-1)
CAS: 124-48-1
Synonyms: Cdbm ; CHClBr2 ; Chlorobromoform ; Chlorodibromo-methan ; DBCM ; Dbromochloro-methan ; Dibromomonochloromethane ; Methane,chlorodibromo-

MF : CHBr2Cl
MS :
MW : 208.28
EINECS : 204-704-0
Mol File : 124-48-1.mol
Mp :−22 °C(lit.)
Bp : 115-118  T
Fp : 19.8 °C
Density:  2.451 g/mL at 25 °C(lit.)
Refractive Index :  1.5465
storage temp :  0-6°C 
Solubility : -1.90
Surface Tension : 42.2 dyne/cm
Enthalpy of Vaporization : 34.07 kJ/mol  
Vapour Pressure : 21 mmHg at 25°C 
Sensitive :  Moisture and Light Sensitive
Merck :  14,2135
BRN :  1731046

Production

Product Categories: Analytical Chemistry ; Standard Solution of Volatile Organic Compounds for Water and Soil Analysis ; Standard Solutions (VOC) ; Alpha Sort ; BromoVolatiles/ Semivolatiles ; DAlphabetic ; DIA - DICEPA ; 600 Series Wastewater Methods ; BromoEPA ; Chemical Class ; Halogenated ; Method 601
 

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 oral 800mg/kg (800mg/kg) brain and coverings: changes in circulation (hemorrhage, thrombosis, etc.)
liver: fatty liver degeration
blood: hemorrhage
 
Toxicology and Applied Pharmacology. Vol. 44, Pg. 213, 1978.
 
rat LD50 oral 370mg/kg (370mg/kg) peripheral nerve and sensation: flaccid paralysis without anesthesia (usually neuromuscular blockage)
behavioral: somnolence (general depressed activity) and tremor
 
Science Reports of the Research Institutes, Tohoku University, Series C: Medicine. Vol. 36(1-4), Pg. 10, 1989.

 

Consensus Reports

.

Safety Profile

Hazard Codes :  Xn,Xi,,T
Risk Statement :  22-39/23/24/25
22 : Chlorodibromomethane (124-48-1) is harmful if swallowed
39/23/24/25 : danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
Safety Statements :  45-36/37/39-26
26 :In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
45 :In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
36/37/39:Wear suitable protective clothing, gloves and eye/face protection
Ridadr :  2810
WGK Germany :  3
Rtecs :  PA6360000
 

Specification

Chemical Properties:Chlorodibromomethane (124-48-1) clear light yellow to orange liquid .
Air & Water Reactions: insoluble in water.
Reactivity Profile: Chlorodibromomethane (124-48-1) is incompatible with strong bases, strong oxidizing agents and magnesium.
Fire Hazard :Chlorodibromomethane is probably combustible.