Detail of "12427-42-8"

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CAS Number:
12427-42-8
Name:
Bis(cyclopentadienyl)cobalt(III) hexafluorophosphate
Molecular Structure:
Formula:
C₁₁H₁₄CoF₆P
Molecular Weight:
334.08
Synonyms:
COBALTICINIUM HEXAFLUOROPHOSPHATE;COBALTOCENE HEXAFLUOROPHOSPHATE;COBALTOCENIUM HEXAFLUOROPHOSPHATE;BIS(CYCLOPENTADIENYL)COBALT HEXAFLUOROPHOSPHATE;BIS(CYCLOPENTADIENYL)COBALT(III) HEXAFLUOROPHOSPHATE;cobaltocenium hexafluorophosphate(1-);BIS(CYCLOPENTADIENYL)COBALT(III);Cobalticiniumhexafluorophosphate,98%
Density:
g/cm³
Boiling Point:
°Cat760mmHg
Flash Point:
°C
Appearance:
yellow powder
Hazard Symbols:
Xn
Risk Codes:
20/21/22-36/37/38
Safety:
26-37/39 Details

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Redox-catalytic reduction of dioxygen by cobaltocene at a carbon paste electrode: application to trace analysis: Redox-catalytic reduction of dioxygen by cobaltocene at a carbon paste electrode: application to trace analysis. Rapicault, Stephane; Paday, Florence; Degrand, Chantal (Universite Blaise Pascal de Clermont-Ferrand, Thermodynamique et Electrochimie en Solution (URA 434), Laboratoire d'Electrochimie Organique, 24 Avenue des Landais, Aubiere 63177, Fr.). Journal of Organometallic Chemistry, 525(1-2), 139-144 (English) 1996 Elsevier. CODEN: JORCAI. ISSN: 0022-328X. DOCUMENT TYPE: Journal CA Section: 1 (Pharmacology) Section cross-reference(s): 80 The redox-catalytic redn. of dioxygen at a carbon paste electrode took place when trace amts. 7440-44-0 and 12427-42-8 which are cas registry numbers are also used here. of cobaltocenium salts substituted by electron-withdrawing groups were added. A potentiometric technique was set up, which allowed the detection of cobaltocenium salts down to ca. 1′10-7 M in a non-deaerated phosphate buffer soln. (pH 7.4). The detection limit of a cobaltocenium-labeled model drug was ca. 2′10-7 M under conditions which mimic competitive immunoassays. .