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125323-99-1

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Basic Information
CAS No.: 125323-99-1
Name: BOC-LYS(Z)(ISOPROPYL)-OH
Molecular Structure:
Molecular Structure of 125323-99-1 (BOC-LYS(Z)(ISOPROPYL)-OH)
Formula: C22H34 N2 O6
Molecular Weight: 422.522
Synonyms: t-Boc-Met-Leu-Phe-OH;Boc-Met-Leu-Phe;t-butyloxycarbonyl-methionyl-leucyl-phenylalanine;Boc-MLF,Boc-1;Boc-Met-Leu-Pje-OH;Boc-L-Met-L-Leu-L-Phe-OH;tert-butoxycarbonyl-Met-Leu-Phe peptide;N-T-BOC-MET-LEU-PHE;tert-butyloxycarbonyl-methionyl-leucyl-phenylalanine;
Density: 1.136±0.06 g/cm3(Predicted)
Boiling Point: 580.3±50.0 °C(Predicted)
PSA: 117.20000
LogP: 8.20500
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Nα-tert-butyloxycarbonyl-Nε-isopropyl-L-lysine

501-53-1

benzyl chloroformate

125323-99-1

Nα-tert-butyloxycarbonyl-Nε-benzyloxycarbonyl-Nε-isopropyl-L-lysine

Conditions
ConditionsYield
With sodium hydroxide Ambient temperature; Yield given;
15761-39-4

1-(tert-butoxycarbonyl)-L-proline

13139-15-6

N-tert-butoxycarbonyl-L-leucine

108-24-7

acetic anhydride

125323-99-1

Nα-tert-butyloxycarbonyl-Nε-benzyloxycarbonyl-Nε-isopropyl-L-lysine

114346-31-5

(R)-3-(4-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)phenyl)-2-((tert-butoxycarbonyl)amino)propanoic acid

Boc-D-Ala-OHBoc-D-2Nal-OH

Boc-D-Ala-OHBoc-D-2Nal-OH

C83H106ClN19O16

Conditions
ConditionsYield
Multistep reaction;42 mg
...Expand
13139-15-6

N-tert-butoxycarbonyl-L-leucine

3744-87-4, 7764-95-6, 15761-38-3

Boc-(R)-Ala

23680-31-1

BOC-O-benzyl-L-serine

108-24-7

acetic anhydride

125323-99-1

Nα-tert-butyloxycarbonyl-Nε-benzyloxycarbonyl-Nε-isopropyl-L-lysine

Boc-Leu

Boc-Leu

Boc-Pro

Boc-Pro

acyline

Conditions
ConditionsYield
Multistep reaction.;
...Expand

polyethylene glycol polyamide resin

15761-39-4

1-(tert-butoxycarbonyl)-L-proline

13139-15-6

N-tert-butoxycarbonyl-L-leucine

3744-87-4, 7764-95-6, 15761-38-3

Boc-(R)-Ala

23680-31-1

BOC-O-benzyl-L-serine

98266-33-2

Boc-DPal

57292-44-1

N-Boc-D-(4-Cl)Phe-OH

76985-10-9

Boc-D-2Nal-OH

125323-99-1

Nα-tert-butyloxycarbonyl-Nε-benzyloxycarbonyl-Nε-isopropyl-L-lysine

114346-31-5

(S)-3-(4-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)phenyl)-2-((tert-butoxycarbonyl)amino)propanoic acid

Nα-(tert-butyloxycarbonyl)-p-ureido-D-phenylalanine

acetylating agent

acetylating agent

C107H120ClN16O17Pol

Conditions
ConditionsYield
Stage #1: polyethylene glycol polyamide resin; Boc-(R)-Ala With benzotriazol-1-ol; diisopropyl-carbodiimide for 4h; MBHA resin;
Stage #2: With trifluoroacetic acid In dichloromethane MBHA resin;
Stage #3: 1-(tert-butoxycarbonyl)-L-proline; N-tert-butoxycarbonyl-L-leucine; BOC-O-benzyl-L-serine; Boc-DPal; N-Boc-D-(4-Cl)Phe-OH; Boc-D-2Nal-OH; Nα-tert-butyloxycarbonyl-Nε-benzyloxycarbonyl-Nε-isopropyl-L-lysine; (S)-3-(4-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)phenyl)-2-((tert-butoxycarbonyl)amino)propanoic acid; Nα-(tert-butyloxycarbonyl)-p-ureido-D-phenylalanine; acetylating agent Further stages;
...Expand

polyethylene glycol polyamide resin

15761-39-4

1-(tert-butoxycarbonyl)-L-proline

3744-87-4, 7764-95-6, 15761-38-3

Boc-(R)-Ala

23680-31-1

BOC-O-benzyl-L-serine

6404-28-0

Boc-Nle-OH

98266-33-2

Boc-DPal

57292-44-1

N-Boc-D-(4-Cl)Phe-OH

76985-10-9

Boc-D-2Nal-OH

125323-99-1

Nα-tert-butyloxycarbonyl-Nε-benzyloxycarbonyl-Nε-isopropyl-L-lysine

114346-31-5

(S)-3-(4-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)phenyl)-2-((tert-butoxycarbonyl)amino)propanoic acid

Nα-(tert-butyloxycarbonyl)-p-ureido-D-phenylalanine

acetylating agent

acetylating agent

C107H120ClN16O17Pol

Conditions
ConditionsYield
Stage #1: polyethylene glycol polyamide resin; Boc-(R)-Ala With benzotriazol-1-ol; diisopropyl-carbodiimide for 4h; MBHA resin;
Stage #2: With trifluoroacetic acid In dichloromethane MBHA resin;
Stage #3: 1-(tert-butoxycarbonyl)-L-proline; BOC-O-benzyl-L-serine; Boc-Nle-OH; Boc-DPal; N-Boc-D-(4-Cl)Phe-OH; Boc-D-2Nal-OH; Nα-tert-butyloxycarbonyl-Nε-benzyloxycarbonyl-Nε-isopropyl-L-lysine; (S)-3-(4-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)phenyl)-2-((tert-butoxycarbonyl)amino)propanoic acid; Nα-(tert-butyloxycarbonyl)-p-ureido-D-phenylalanine; acetylating agent Further stages;
...Expand

polyethylene glycol polyamide resin

15761-39-4

1-(tert-butoxycarbonyl)-L-proline

13139-16-7

N-(tert-butyloxycarbonyl)-L-isoleucine

3744-87-4, 7764-95-6, 15761-38-3

Boc-(R)-Ala

23680-31-1

BOC-O-benzyl-L-serine

98266-33-2

Boc-DPal

57292-44-1

N-Boc-D-(4-Cl)Phe-OH

76985-10-9

Boc-D-2Nal-OH

125323-99-1

Nα-tert-butyloxycarbonyl-Nε-benzyloxycarbonyl-Nε-isopropyl-L-lysine

114346-31-5

(S)-3-(4-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)phenyl)-2-((tert-butoxycarbonyl)amino)propanoic acid

Nα-(tert-butyloxycarbonyl)-p-ureido-D-phenylalanine

acetylating agent

acetylating agent

C107H120ClN16O17Pol

Conditions
ConditionsYield
Stage #1: polyethylene glycol polyamide resin; Boc-(R)-Ala With benzotriazol-1-ol; diisopropyl-carbodiimide for 4h; MBHA resin;
Stage #2: With trifluoroacetic acid In dichloromethane MBHA resin;
Stage #3: 1-(tert-butoxycarbonyl)-L-proline; N-(tert-butyloxycarbonyl)-L-isoleucine; BOC-O-benzyl-L-serine; Boc-DPal; N-Boc-D-(4-Cl)Phe-OH; Boc-D-2Nal-OH; Nα-tert-butyloxycarbonyl-Nε-benzyloxycarbonyl-Nε-isopropyl-L-lysine; (S)-3-(4-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)phenyl)-2-((tert-butoxycarbonyl)amino)propanoic acid; Nα-(tert-butyloxycarbonyl)-p-ureido-D-phenylalanine; acetylating agent Further stages;
...Expand

polyethylene glycol polyamide resin

15761-39-4

1-(tert-butoxycarbonyl)-L-proline

13734-41-3

t-Boc-L-valine

3744-87-4, 7764-95-6, 15761-38-3

Boc-(R)-Ala

23680-31-1

BOC-O-benzyl-L-serine

98266-33-2

Boc-DPal

57292-44-1

N-Boc-D-(4-Cl)Phe-OH

76985-10-9

Boc-D-2Nal-OH

125323-99-1

Nα-tert-butyloxycarbonyl-Nε-benzyloxycarbonyl-Nε-isopropyl-L-lysine

114346-31-5

(S)-3-(4-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)phenyl)-2-((tert-butoxycarbonyl)amino)propanoic acid

Nα-(tert-butyloxycarbonyl)-p-ureido-D-phenylalanine

acetylating agent

acetylating agent

C106H118ClN16O17Pol

Conditions
ConditionsYield
Stage #1: polyethylene glycol polyamide resin; Boc-(R)-Ala With benzotriazol-1-ol; diisopropyl-carbodiimide for 4h; MBHA resin;
Stage #2: With trifluoroacetic acid In dichloromethane MBHA resin;
Stage #3: 1-(tert-butoxycarbonyl)-L-proline; t-Boc-L-valine; BOC-O-benzyl-L-serine; Boc-DPal; N-Boc-D-(4-Cl)Phe-OH; Boc-D-2Nal-OH; Nα-tert-butyloxycarbonyl-Nε-benzyloxycarbonyl-Nε-isopropyl-L-lysine; (S)-3-(4-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)phenyl)-2-((tert-butoxycarbonyl)amino)propanoic acid; Nα-(tert-butyloxycarbonyl)-p-ureido-D-phenylalanine; acetylating agent Further stages;
...Expand

polyethylene glycol polyamide resin

15761-39-4

1-(tert-butoxycarbonyl)-L-proline

3744-87-4, 7764-95-6, 15761-38-3

Boc-(R)-Ala

23680-31-1

BOC-O-benzyl-L-serine

98266-33-2

Boc-DPal

57292-44-1

N-Boc-D-(4-Cl)Phe-OH

76985-10-9

Boc-D-2Nal-OH

88950-64-5

1-<(tert-butyloxy)carbonylamino>cyclopropane-1-carboxylic acid

125323-99-1

Nα-tert-butyloxycarbonyl-Nε-benzyloxycarbonyl-Nε-isopropyl-L-lysine

114346-31-5

(S)-3-(4-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)phenyl)-2-((tert-butoxycarbonyl)amino)propanoic acid

Nα-(tert-butyloxycarbonyl)-p-ureido-D-phenylalanine

acetylating agent

acetylating agent

C105H114ClN16O17Pol

Conditions
ConditionsYield
Stage #1: polyethylene glycol polyamide resin; Boc-(R)-Ala With benzotriazol-1-ol; diisopropyl-carbodiimide for 4h; MBHA resin;
Stage #2: With trifluoroacetic acid In dichloromethane MBHA resin;
Stage #3: 1-(tert-butoxycarbonyl)-L-proline; BOC-O-benzyl-L-serine; Boc-DPal; N-Boc-D-(4-Cl)Phe-OH; Boc-D-2Nal-OH; 1-<(tert-butyloxy)carbonylamino>cyclopropane-1-carboxylic acid; Nα-tert-butyloxycarbonyl-Nε-benzyloxycarbonyl-Nε-isopropyl-L-lysine; (S)-3-(4-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)phenyl)-2-((tert-butoxycarbonyl)amino)propanoic acid; Nα-(tert-butyloxycarbonyl)-p-ureido-D-phenylalanine; acetylating agent Further stages;
...Expand

polyethylene glycol polyamide resin

15761-39-4

1-(tert-butoxycarbonyl)-L-proline

2488-15-5

N-tert-butoxycarbonyl-L-methionine

3744-87-4, 7764-95-6, 15761-38-3

Boc-(R)-Ala

23680-31-1

BOC-O-benzyl-L-serine

98266-33-2

Boc-DPal

57292-44-1

N-Boc-D-(4-Cl)Phe-OH

76985-10-9

Boc-D-2Nal-OH

125323-99-1

Nα-tert-butyloxycarbonyl-Nε-benzyloxycarbonyl-Nε-isopropyl-L-lysine

114346-31-5

(S)-3-(4-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)phenyl)-2-((tert-butoxycarbonyl)amino)propanoic acid

Nα-(tert-butyloxycarbonyl)-p-ureido-D-phenylalanine

acetylating agent

acetylating agent

C106H118ClN16O17PolS

Conditions
ConditionsYield
Stage #1: polyethylene glycol polyamide resin; Boc-(R)-Ala With benzotriazol-1-ol; diisopropyl-carbodiimide for 4h; MBHA resin;
Stage #2: With trifluoroacetic acid In dichloromethane MBHA resin;
Stage #3: 1-(tert-butoxycarbonyl)-L-proline; N-tert-butoxycarbonyl-L-methionine; BOC-O-benzyl-L-serine; Boc-DPal; N-Boc-D-(4-Cl)Phe-OH; Boc-D-2Nal-OH; Nα-tert-butyloxycarbonyl-Nε-benzyloxycarbonyl-Nε-isopropyl-L-lysine; (S)-3-(4-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)phenyl)-2-((tert-butoxycarbonyl)amino)propanoic acid; Nα-(tert-butyloxycarbonyl)-p-ureido-D-phenylalanine; acetylating agent Further stages;
...Expand

polyethylene glycol polyamide resin

15761-39-4

1-(tert-butoxycarbonyl)-L-proline

3744-87-4, 7764-95-6, 15761-38-3

Boc-(R)-Ala

13734-34-4

N-tert-butoxycarbonyl-L-phenylalanine

23680-31-1

BOC-O-benzyl-L-serine

98266-33-2

Boc-DPal

57292-44-1

N-Boc-D-(4-Cl)Phe-OH

76985-10-9

Boc-D-2Nal-OH

125323-99-1

Nα-tert-butyloxycarbonyl-Nε-benzyloxycarbonyl-Nε-isopropyl-L-lysine

114346-31-5

(S)-3-(4-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)phenyl)-2-((tert-butoxycarbonyl)amino)propanoic acid

Nα-(tert-butyloxycarbonyl)-p-ureido-D-phenylalanine

acetylating agent

acetylating agent

C110H118ClN16O17Pol

Conditions
ConditionsYield
Stage #1: polyethylene glycol polyamide resin; Boc-(R)-Ala With benzotriazol-1-ol; diisopropyl-carbodiimide for 4h; MBHA resin;
Stage #2: With trifluoroacetic acid In dichloromethane MBHA resin;
Stage #3: 1-(tert-butoxycarbonyl)-L-proline; N-tert-butoxycarbonyl-L-phenylalanine; BOC-O-benzyl-L-serine; Boc-DPal; N-Boc-D-(4-Cl)Phe-OH; Boc-D-2Nal-OH; Nα-tert-butyloxycarbonyl-Nε-benzyloxycarbonyl-Nε-isopropyl-L-lysine; (S)-3-(4-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)phenyl)-2-((tert-butoxycarbonyl)amino)propanoic acid; Nα-(tert-butyloxycarbonyl)-p-ureido-D-phenylalanine; acetylating agent Further stages;
...Expand
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