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126-72-7

Basic Information
CAS No.: 126-72-7
Name: TRIS(2,3-DIBROMOPROPYL)PHOSPHATE
Molecular Structure:
Molecular Structure of 126-72-7 (TRIS(2,3-DIBROMOPROPYL)PHOSPHATE)
Formula: C9H15 Br6 O4 P
Molecular Weight: 697.613
Synonyms: 1-Propanol,2,3-dibromo-, phosphate (3:1) (6CI,8CI,9CI);Phosphoric acid,tris(2,3-dibromopropyl) ester (6CI);Anfram 3PB;Apex 462-5;Bromkal P67-6HP;ES 685;FireMaster LV-T 23P;FireMaster T 23;FireMaster T 23P;FlammexAP;Flammex LV-T 23P;Flammex T 23P;Fyrol HB 32;NSC 3240;Phoscon FR 150;Phoscon PE 60;Phoscon UF-S;T 23P;TDBPP;Tris;Tris (flame retardant);Tris(2,3-dibromopropyl) phosphate;Zetofex ZN;
EINECS: 204-799-9
Density: 2.321g/cm3
Melting Point: 5.5°C
Boiling Point: 544.2°Cat760mmHg
Flash Point: 282.9°C
Solubility: 8mg/L(24 oC)
Hazard Symbols:
Risk Codes: 45-22-38-51/53
Safety: Confirmed carcinogen with experimental carcinogenic, neoplastigenic, tumorigenic, and teratogenic data. Poison by intraperitoneal route. Moderately toxic by ingestion. Experimental reproductive effects. Human mutation data reported. An eye and severe skin irritant. Can cause testicular atrophy and sterility. Once used as a flame retardant additive to synthetic textiles and plastics, particularly in children’s sleepwear. Use discontinued because it can be absorbed by human skin, or chewed or sucked off sleepwear by infants. May be flammable when exposed to heat or flame. When heated to decomposition it emits very toxic fumes of Br and POx.
PSA: 54.57000
LogP: 5.61950
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Chemistry

IUPAC Name: Tris(2,3-dibromopropyl) phosphate (126-72-7)
Synonyms: 1-Propanol, 2,3-dibromo-, phosphate ; 1-Propanol, 2,3-dibromo-, phosphate (3:1) ; 1-Propanol,2,3-dibromo-,phosphate(3:1) ; 2,3-Dibromo-1-propanolphosphate(3:1) ; 2,3-Dibromo-1-propanophosphate(3:1) ; 3Pbr ; Anfram 3PB ; Anfram3pb
CAS: 126-72-7
Molecular Formula:C9H15Br6O4P
Molecular Weight: 697.61
 Molecular Structure:
EINECS: 204-799-9
Product Categories: Alpha Sort;BromoVolatiles/ Semivolatiles;Chemical Class;Halogenated;TP - TZ;T-ZAlphabetic
Mol File: 126-72-7.mol
Merck:  13,9821
Surface Tension: 57.1 dyne/cm 
Density: 2.321 g/cm3 
Flash Point: 282.9 °C 
Melting point: -3°C-8°C
Enthalpy of Vaporization: 79.19 kJ/mol 
Boiling Point: 544.2 °C at 760 mmHg 
Vapour Pressure: 2.38E-11 mmHg at 25°C 
Appearance: Tris (126-72-7) is clear colorless to pale yellow viscous liquid
Solubility: Insoluble in water, hydrocarbons, soluble in alcohols, ketones, aromatics, halogenated hydrocarbons.

Uses

 Tris (126-72-7) is used as a synthetic fiber, plastic, flame retardant additives.

Toxicity Data With Reference

1.    

skn-rbt 500 mg/24H SEV

    28ZPAK    Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,206.
2.    

eye-rbt 500 mg/24H MLD

    28ZPAK    Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,206.
3.    

mma-esc 100 µg/plate

    ENMUDM    Environmental Mutagenesis. 7 (Suppl 5)(1985),1.
4.    

dnd-hmn:oth 2 mg/L

    MUREAV    Mutation Research. 56 (1977),89.
5.    

orl-rat TDLo:250 mg/kg (female 6-15D post):TER

    FCTXAV    Food and Cosmetics Toxicology. 19 (1981),67.
6.    

orl-rat TDLo:1330 mg/kg/76W-C:CAR

    NCITR*    National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-76 ,1978.
7.    

orl-mus TDLo:39 g/kg/92W-C:CAR

    NCITR*    National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-76 ,1978.
8.    

orl-rat TD:3600 mg/kg/103W-C:NEO

    NCITR*    National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-76 ,1978.
9.    

orl-rat TD:1820 mg/kg/2Y-C:ETA

    FCTXAV

Consensus Reports

NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2A IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 ,1987,p. 341.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 20 ,1979,p. 575.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human Limited Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 20 ,1979,p. 575.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . NCI Carcinogenesis Bioassay (feed); Clear Evidence: mouse, rat NCITR*    National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-76 ,1978. . Community Right-To-Know List. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Safety Profile

Hazard Codes  T,N
Risk Statements  45-22-38-51/53
22:  Tris (126-72-7) is harmful if swallowed 
38:  Irritating to the skin
45:  May cause cancer 
45:  May cause cancer  
Safety Statements  53-26-37-61
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
37:  Wear suitable gloves 
53:  Avoid exposure - obtain special instruction before use 
61:  Avoid release to the environment. Refer to special instructions safety data sheet  
RIDADR  UN 3082 9/PG 3
RTECS  UB0350000

Specification

Air & Water Reactions :Insoluble in water.
Reactivity Profile: Tris(2,3-dibromopropyl)phosphate is stable at temperatures up to 392-482°F. Major decomposition begins at 586°F. Is hydrolyzed by acids and bases .
Fire Hazard :Tris(2,3-dibromopropyl)phosphate is combustible.