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CAS No.: | 126-99-8 |
---|---|
Name: | 2-Chloro-1,3-butadiene |
Article Data: | 78 |
Molecular Structure: | |
Formula: | C4H5Cl |
Molecular Weight: | 88.5367 |
Synonyms: | 2-Chlorobutadiene;Chloroprene;NSC 18589;b-Chloroprene; |
EINECS: | 204-818-0 |
Density: | 0.923 g/cm3 |
Melting Point: | -130 °C |
Boiling Point: | 59.399 °C at 760 mmHg |
Flash Point: | -8.827 °C |
Appearance: | clear colorless liquid |
Hazard Symbols: | F, T |
Risk Codes: | 10-20/22-36-48/20-36/37/38-11-45-39/23/24/25-23/24/25 |
Safety: | 16-45-53-36/37-7 |
Transport Information: | UN 1993 |
PSA: | 0.00000 |
LogP: | 1.92490 |
Conditions | Yield |
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With hydrogenchloride; calcium chloride | |
With hydrogenchloride; calcium chloride |
Conditions | Yield |
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With hydrogenchloride | |
With hydrogenchloride; pyrographite; mercury at 90℃; |
Conditions | Yield |
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With hydrogenchloride; ammonium chloride; copper(l) chloride at 30℃; | |
With hydrogenchloride; ammonium chloride; copper(l) chloride at 30℃; | |
With hydrogenchloride; ammonium chloride; copper(l) chloride at 30℃; |
Conditions | Yield |
---|---|
With chlorine at 500 - 515℃; Leiten durch ein Kohlerohr; |
Conditions | Yield |
---|---|
at 500℃; | |
at 500℃; Pyrolysis; |
Conditions | Yield |
---|---|
With sodium hydroxide at 190℃; |
2,2,3-trichloro-butane
chloroprene
Conditions | Yield |
---|---|
at 400 - 510℃; beim Leiten durch Roehren aus Pyrexglas, Quarz, nichtrostendem Stahl oder Kupfer; | |
With pyrographite; barium(II) chloride at 300℃; | |
With water; silica gel; magnesium sulfate; magnesium chloride at 280 - 300℃; | |
With pyrographite; barium(II) chloride at 300℃; | |
at 400 - 510℃; beim Leiten durch Roehren aus Pyrexglas, Quarz, nichtrostendem Stahl oder Kupfer; |
Conditions | Yield |
---|---|
at 400 - 510℃; | |
at 400 - 510℃; |
Conditions | Yield |
---|---|
at 530℃; Leiten durch ein Quarzrohr; |
Conditions | Yield |
---|---|
at 530℃; im Quarzrohr; |
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Chloroprene(126-99-8) is, chemically, a chlorovinyl ester of hydrochloric acid and can be manufactured by polymerizing acetylene to vinyl acetylene using a weak solution containing ammonium chloride (NH4Cl), cuprous chloride (Cu2Cl2), and potassium chloride (KCl) as catalyst. The off-gas from the reactor has its water condensed out and is then fractionated. Aqueous hydrochloric acid at 35 to 45℃ is then reacted with the vinyl acetylene in the presence of cupric chloride to give chloroprene (2-chloro-1,3-butadiene).
2HC≡CH → CH2=CHC≡CH
CH2=CHC≡CH + HCl → CH2=CHClC=CH2
The contact time is about 15 seconds with a 20 percent conversion per pass. An overall yield of approximately 65 percent can be achieved.
Chloroprene(126-99-8) is also made by chlorination of butadiene at 300℃ followed by dehydrochlorination, using sodium hydroxide at 100℃. Addition of the chlorine to the butadiene occurs at either 1,2 or 1,4 because the intermediate allyl carbocation is delocalized.
CH2=CHCH=CH2 + Cl2 → CH2ClCH=CHCH2Cl
CH2ClCH=CHCH2Cl + Cl2 → CH2=CHC(Cl)=CH2
The 1,4-dichloro isomer can be isomerized to the 1,2-dichloro isomer by heating with cuprous chloride.
CH2ClCH=CHCH2Cl → CH3CH2CCl=CHCl