Detail of "12672-70-7"

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Indium-mediated facile dehydration and Beckmann rearrangement of oximes

Barman, Dhiren C.; Thakur, Ashim J.; Prajapati, Dipak; Sandhu, Jagir S. (Regional Research Laboratory, Jorhat 785006, India). Chemistry Letters, (10), 1196-1197 (English) 2000 Chemical Society of Japan. CODEN: CMLTAG. ISSN: 0366-7022. DOCUMENT TYPE: Journal CA Section: 21 (General Organic Chemistry) Indium chloride was developed as an efficient reagent for the conversion of aldoximes to nitriles and the Beckmann rearrangement of ketoximes to anilides. E.g., treating 1 mmol PhCH:NOH with 0.13 mmol InCl3 in MeCN gave 98% PhCN, whereas similar treatment of Ph2C:NOH gave 95% PhCONHPh.

Synthesis of indium phosphide nanoparticles via catalytic cleavage of phosphorus carbon bond in n-trioctylphosphine by indium

Synthesis of indium phosphide nanoparticles via catalytic cleavage of phosphorus carbon bond in n-trioctylphosphine by indium. Khanna, P. K.; Jun, Ki-Won; Hong, Ki Bum; Baeg, Jin-Ook; Mehrotra, G. K. (Micro-Chemical Technology Lab., Korea Research Institute of Chemical Technology, Yuseong-gu, Daejeon 305-600, S. Korea). Materials Chemistry and Physics, 92(1), 54-58 (English) 2005 Elsevier B.V. CODEN: MCHPDR. ISSN: 0254-0584. DOCUMENT TYPE: Journal CA Section: 66 (Surface Chemistry and Colloids) Section cross-reference(s): 76, 78 Nanocryst. In phosphide was synthesized via catalytic cleavage of P-C bond in n-trioctylphosphine by In nanoparticles at 200-360° under an atm. of Ar. Indium chloride/Na as well as In(0) could be used as raw materials. The products were characterized by EDS, XRD, SEM, FESEM and PL techniques. XRD pattern of the obtained powder showed all the major peaks due to Zn blend In phosphide with the sizes of 30-60 nm. FTIR and TG/DTA studies indicated that InP particles were capped with TOP.