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127-20-8

Basic Information
CAS No.: 127-20-8
Name: 2,2-DICHLOROPROPIONIC ACID SODIUM SALT
Article Data: 1
Molecular Structure:
Molecular Structure of 127-20-8 (2,2-DICHLOROPROPIONIC ACID SODIUM SALT)
Formula: C3H4 Cl2 O2 . Na
Molecular Weight: 164.951
Synonyms: Propanoicacid, 2,2-dichloro-, sodium salt (9CI); Propionic acid, 2,2-dichloro-, sodiumsalt (8CI); 2,2-DPA Na salt; 2,2-Dichloropropionic acid sodium salt;Antigramigna; Basfapon; Dalapon sodium; Dalapon sodium salt; Dikopan; Dowpon;Dowpon S; Gramevin; Omnidel; Omnidel Spezial; Propinate; Radapon; SYS 67Omnidel; Sodium 2,2-dichloropropionate; Sodium 2,2-dichloropropionic acid;Sodium Dalapon; Sodium dichloropropionate; Sodium a,a-dichloropropionate; Tafapon; a,a-Dichloropropionic acid sodiumsalt
Density: 1.497g/cm3
Melting Point: 193-197oC
Boiling Point: 187.5°Cat760mmHg
Flash Point: 76.1°C
Hazard Symbols:
Risk Codes: 20/21/22-34-36/37/38
Safety: Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of Na2O and Cl.
PSA: 40.13000
LogP: -0.06990
Synthetic route
127-20-8

sodium 2,2-dichloropropionate

26073-26-7

2,2-dichloropropionyl chloride

Conditions
ConditionsYield
With oxalyl dichloride In pyridine; dichloromethane at 25℃; for 2h;70%
With dmap; oxalyl dichloride In dichloromethane
127-20-8

sodium 2,2-dichloropropionate

107905-50-0

α,α-Dichloropropionic anhydride

Conditions
ConditionsYield
With thionyl chloride In dichloromethane for 2h; Heating;43%
5179-82-8

C3H2Cl6NOP

127-20-8

sodium 2,2-dichloropropionate

36076-45-6

C12H11Cl9NO7P

Conditions
ConditionsYield
In acetone
39074-64-1

Isopropyl-N-chloromethyl-N-(3-chlorophenyl)-carbamate

127-20-8

sodium 2,2-dichloropropionate

40151-75-5

2,2-Dichloro-propionic acid [(3-chloro-phenyl)-isopropoxycarbonyl-amino]-methyl ester

39073-78-4

(5-Chloro-2-methoxy-phenyl)-chloromethyl-carbamic acid isopropyl ester

127-20-8

sodium 2,2-dichloropropionate

50887-80-4

2,2-Dichloro-propionic acid [(5-chloro-2-methoxy-phenyl)-isopropoxycarbonyl-amino]-methyl ester

127-20-8

sodium 2,2-dichloropropionate

125973-26-4

2,2-dichloropropionyl hypofluorite

Conditions
ConditionsYield
With water; fluorine In various solvent(s) at -78℃;
127-20-8

sodium 2,2-dichloropropionate

74-88-4

methyl iodide

17640-02-7

methyl 2,2-dichloropropionate

73050-78-9

2-(5-chloro-2-hydroxy-phenyl)-propan-2-ol

127-20-8

sodium 2,2-dichloropropionate

73050-93-8

6-chloro-2,4,4-trimethyl-[4H]-1,3-benzodioxin-2-carboxylic acid

Conditions
ConditionsYield
With hydrogenchloride In 1,4-dioxane
74271-47-9

chloro-5 hydroxy-2 α-methyl α-phenyl benzene methanol

127-20-8

sodium 2,2-dichloropropionate

6-chloro-2,4-dimethyl-4-phenyl-[4H]-1,3-benzodioxin-2-carboxylic acid

Conditions
ConditionsYield
In water; toluene
127-20-8

sodium 2,2-dichloropropionate

7758-99-8

copper(II) sulfate

Copper(II); 2,2-dichloro-propionate

Conditions
ConditionsYield
In water a soln. of Cu comp. added to a soln. of acid (pH 4.5-5, 1:2 molar ratio), left to stand at room temp.;
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Chemistry

IUPAC Name: Sodium 2,2-dichloropropanoate
CAS: 127-20-8
EINECS: 204-828-5
Product Categories: Organics .
Following is the Molecular Structure of α,α-Dichloropropionic acid sodium salt (127-20-8):

SMILES: [Na+].ClC(Cl)(C([O-])=O)C
InChI: InChI=1/C3H4Cl2O2.Na/c1-3(4,5)2(6)7;/h1H3,(H,6,7);/q;+1/p-1
InChIKey: PDEFQWNXOUGDJR-REWHXWOFAR
Std.InChI: InChI=1S/C3H4Cl2O2.Na/c1-3(4,5)2(6)7;/h1H3,(H,6,7);/q;+1/p-1
Std.InChIKey: PDEFQWNXOUGDJR-UHFFFAOYSA-M
Molecular Formula: C3H3Cl2NaO2
Molecular Weight: 164.95
Boiling Point: 187.5℃ at 760mmHg
Flash Point: 76.1℃
Enthalpy of Vaporization: 46.71kJ/mol
Vapour Pressure: 0.282mmHg at 25℃

Uses

 α,α-Dichloropropionic acid sodium salt (127-20-8) can be used for herbicide.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
chicken LD50 oral 5600mg/kg (5600mg/kg)   Down to Earth. Vol. 35, Pg. 25, 1979.
domestic animals - goat/sheep LD50 oral > 4gm/kg (4000mg/kg)   "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A112, Pg. 1984,
guinea pig LD50 oral 3400mg/kg (3400mg/kg)   "Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel," Perkow, W., Berlin, Verlag Paul Parey, 1971-1976Vol. -, Pg. -, 1971/1976.
mammal (species unspecified) LC50 inhalation > 20gm/m3/8H (20000mg/m3)   Pesticide Manual. Vol. 9, Pg. 222, 1991.
mammal (species unspecified) LD50 oral 4gm/kg (4000mg/kg)   "Pflanzenschutz-und Schaedlingsbekaempfungsmittel: Abriss einer Toxikologie und Therapie von Vergiftungen," 2nd ed., Klimmer, O.R., Hattingen, Fed. Rep. Ger., Hundt-Verlag, 1971Vol. -, Pg. 86, 1971.
mammal (species unspecified) LD50 unreported 6600mg/kg (6600mg/kg)   Farm Chemicals Handbook. Vol. -, Pg. C164, 1991.
mouse LD50 oral 4600mg/kg (4600mg/kg)   Japan Pesticide Information. Vol. (11), Pg. 42, 1972.
mouse LD50 unreported 3650mg/kg (3650mg/kg)   Tsitologiya i Genetika. Cytology and Genetics. For English translation, see CYGEDX. Vol. 16(1), Pg. 45, 1982.
rabbit LD50 oral 3400mg/kg (3400mg/kg)   "Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel," Perkow, W., Berlin, Verlag Paul Parey, 1971-1976Vol. -, Pg. -, 1971/1976.
rabbit LD50 skin > 2gm/kg (2000mg/kg)   Pesticide Manual. Vol. 9, Pg. 222, 1991.
rat LD50 oral 3860mg/kg (3860mg/kg)   World Review of Pest Control. Vol. 9, Pg. 119, 1970.
rat LD50 parenteral > 6gm/kg (6000mg/kg)   Defense des Vegetaux. Vol. 14, Pg. 3, 1960.

Consensus Reports

Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Safety Profile

Hazard Codes:  Xi Irritant.
Risk Statements: 20/21/22-34-36/37/38
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed.
R34: Causes burns.
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 26-27-28-36/37/39-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S27: Take off immediately all contaminated clothing.
S28: After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer).
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S36: Wear suitable protective clothing.
RIDADR: UN 3261 8/PG 2
RTECS: UF1225000
Moderately toxic by ingestion. Mutation data reported.

Standards and Recommendations

DFG MAK: 1 ppm (6 mg/m3)

Specification

 α,α-Dichloropropionic acid sodium salt (127-20-8),which also can be called for Dpa sodium ; Dalapone-Na ; Dalapon-sodium ; alpha,alpha-Dichloropropionic acid,sodium salt ; 2,2-Dichloropropionic acid sodium salt ; Sodium dichloropropionate ; Sodium 2,2-dichloropropionate ; 2,2-Dichloro-propanoicacisodiumsalt .When α,α-Dichloropropionic acid sodium salt (127-20-8) was heated,it emits toxic fumes of Na2O and Cl− .This chemical is a white or yellow powder and it should be stored at 4℃.It's soluble in water and most organic solvents.