Detail of "1270-98-0"

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CAS Number:
1270-98-0
Name:
Titanium, trichloro(h5-2,4-cyclopentadien-1-yl)-
Molecular Structure:
Formula:
C5H5 Cl3 Ti
Molecular Weight:
215.2902
Synonyms:
Cyclopentadienyltitanium(IV)trichloride (6CI); Titanium, trichloro-p-cyclopentadienyl- (8CI); Titanium, trichlorocyclopentadienyl-(7CI); Cyclopentadienyltitanium trichloride; Cyclopentadienyltrichlorotitanium;Monocyclopentadienyltitanium trichloride; NSC 332761;Trichloro(cyclopentadienyl)titanium; Trichloro(cyclopentyldienyl)titanium;Trichloro(h5-cyclopentadienyl)titanium;Trichloro-p-cyclopentadienyltitanium; h5-Cyclopentadienyltitaniumtrichloride; p-Cyclopentadienyltitaniumtrichloride
Density:
g/cm³
Melting Point:
210 ºC (dec.)(lit.)
Boiling Point:
41.5 ºCat 760 mmHg
Flash Point:
>210ºC
Hazard Symbols:
C
Risk Codes:
34
Safety:
26-28-36/37/39-45 Details

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Crystal structures of trichloro(h5-cyclopentadienyl)titanium(IV) and -zirconium(IV): Crystal structures of trichloro(h5-cyclopentadienyl)titanium(IV) and -zirconium(IV).Some chemicals with cas registry numbers like 1270-98-0 and 87372-89-2 are also used. Engelhardt, Lutz M.; Papasergio, Rocco I.; Raston, Colin L.; White, Allan H. (Dep. Phys. Inorg. Chem., Univ. West. Australia, Nedlands 6009, Australia). Organometallics, 3(1), 18-20 (English) 1984. CODEN: ORGND7. ISSN: 0276-7333. DOCUMENT TYPE: Journal CA Section: 75 (Crystallography and Liquid Crystals) Section cross-reference(s): 29 CpTiCl3 is monoclinic, space group P21, with a 6.588(2), b 10.419(3), c 6.680(2) ?, and b 115.86(2)°; Z = 2. The structure is based on that of TiCl4, comprising monomeric species in which a Cl has been replaced by an h5-Cp ligand. Ti-Cl are 2.201(5)-2.248(5) ?, with Cl-Ti-Cl 102.2(1)-104.1(2)°. CpZrCl3 is triclinic, space group P1, with a 8.629(8), b 7.133(7), c 6.626(6) ?, a 100.68(7), b 91.67(7), and g 98378(7)°; Z = 2. The Zr structure is based on that of the solid-state structure of the parent compd. ZrCl4, a linear polymer with successive atoms, related by crystallog. inversion centers, bridged by pairs of Cl atoms Cl2(ZrCpCl)Cl2(ZrCpCl)Cl2. Zr-Cl (terminal) is 2.419(3) ?, while Zr-Cl (bridging) is 2.518(3)-2.728(3) ?. .

Isoprene polymerization on titanium(IV) complexes supported on alumina-silica gel: Isoprene polymerization on titanium(IV) complexes supported on alumina-silica gel. Skupinski, Wincenty; Walczuk, Przemyslaw (Dep. Chem., Warsaw Tech. Univ., Warsaw, Pol.). Polimery (Warsaw), 31(10), 393-5 (English) 1986. CODEN: POLIA4. ISSN: 0032-2725. DOCUMENT TYPE: Journal CA Section: 39 (Synthetic Elastomers and Natural Rubber) Section cross-reference(s): 35 Soln. polymn. of isoprene (I) in the presence of CpTiCl3 [1270-98-0] (Cp = cyclopentadienyl) supported on alumina-silica gels yielded mixts. of cyclic polymers, trans-1,4- [9003-31-0], and 3,4-polyisoprene [9003-31-0], the compn. of which depended on the solvent and polymn. temp. The yield of polymers in C6H6 increased with increasing temp., whereas the polymer yield in hexane or I decreased with increasing temp.In this experiment, several chemicals are used like 1270-98-0 and 9003-31-0 The yield of oligomers in the above solvents increased with increasing temp. .