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Basic Information
| CAS No.: | 131211-27-3 | ||||||||
|---|---|---|---|---|---|---|---|---|---|
| Name: | DI-1-ADAMANTYLPHOSPHINE | ||||||||
| Article Data: | 14 | ||||||||
| Molecular Structure: | |||||||||
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| Formula: | C20H31P | ||||||||
| Molecular Weight: | 302.44 | ||||||||
| Synonyms: | DI-1-ADAMANTYLPHOSPHINE;Di-1-adamantylphosphine,min.97%;Bis(adamant-1-yl)phosphine, Bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphine;Di-1-adamantylphosphine, min. 97% | ||||||||
| Melting Point: | 181-185 °C | ||||||||
| Boiling Point: | 407.8±12.0 °C(Predicted) | ||||||||
| Hazard Symbols: |
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| Risk Codes: | 23/24/25-36/37/38 | ||||||||
| Safety: |
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| PSA: | 13.59000 | ||||||||
| LogP: | 5.60250 | ||||||||
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Synthetic route
- 126683-99-6
1-(1-adamantyl)chlorophosphinoyladamantane
- 131211-27-3
di-1-adamantylphosphine
Conditions
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride In tetrahydrofuran for 16h; Ambient temperature; | 94.3% |
| With trichlorosilane In toluene for 264h; Ambient temperature; | 93% |
| With lithium aluminium tetrahydride In tetrahydrofuran at -10 - 20℃; for 14h; | 90% |
- 157282-19-4
di-1-adamantylchlorophosphane
- 131211-27-3
di-1-adamantylphosphine
Conditions
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride In diethyl ether at 20℃; for 4h; | 70% |
- 97580-87-5
(1-adamantyl)magnesium chloride
- 131211-27-3
di-1-adamantylphosphine
Conditions
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: 69 percent / diethyl ether / Heating 2: 70 percent / LiAlH4 / diethyl ether / 4 h / 20 °C View Scheme |
- 23906-91-4
(1-adamantyl)dichlorophosphine
- 131211-27-3
di-1-adamantylphosphine
Conditions
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: 69 percent / diethyl ether / Heating 2: 70 percent / LiAlH4 / diethyl ether / 4 h / 20 °C View Scheme |
Conditions
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: 1.) PCl3, AlCl3, 2.) H2O / 1.) reflux, 6 h, 2.) chloroform 2: 94.3 percent / LiAlH4 / tetrahydrofuran / 16 h / Ambient temperature View Scheme |
- 281-23-2
adamantane
- 131211-27-3
di-1-adamantylphosphine
Conditions
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: 95 percent / phosphorus trichloride, aluminum chloride / 5 h / Heating 2: 62 percent / LiAlH4 / diethyl ether / 3 h / Heating View Scheme | |
| Multi-step reaction with 2 steps 1: phosphorus trichloride; aluminum (III) chloride / 6.17 h / Reflux 2: lithium aluminium tetrahydride / tetrahydrofuran / 20 h / -10 - 20 °C View Scheme | |
| Multi-step reaction with 2 steps 1.1: aluminum (III) chloride; phosphorus trichloride / Reflux 1.2: Cooling with ice 2.1: lithium aluminium tetrahydride / tetrahydrofuran / 1 h / 0 - 20 °C / Inert atmosphere View Scheme |
- 131266-79-0
bis(1-adamantyl)phosphine oxide
- 131211-27-3
di-1-adamantylphosphine
Conditions
| Conditions | Yield |
|---|---|
| With copper(II) trifluoromethanesulfonate; 1,1,3,3-Tetramethyldisiloxane In toluene at 100℃; for 9h; Inert atmosphere; | |
| With diethoxymethylane; Bis(p-nitrophenyl) phosphate In toluene at 110℃; Inert atmosphere; chemoselective reaction; | 99 %Spectr. |
- 131211-27-3
di-1-adamantylphosphine
- 157282-19-4
di-1-adamantylchlorophosphane
Conditions
| Conditions | Yield |
|---|---|
| With tetrachloromethane at 50℃; for 16h; | 100% |
| With tetrachloromethane at 50℃; for 24h; | 98% |
| With 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene for 16h; Ambient temperature; | 93.7% |
| With phosgene; 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene at -10℃; | 67% |
| Multi-step reaction with 2 steps 1: phosgen / toluene / Ambient temperature 2: Et3N / toluene / a) 60 deg C, 4 h, b) reflux, 3 h View Scheme |
- 100-39-0
benzyl bromide
- 131211-27-3
di-1-adamantylphosphine
Conditions
| Conditions | Yield |
|---|---|
| In toluene Glovebox; Schlenk technique; Inert atmosphere; Reflux; | 100% |
| In toluene Glovebox; Schlenk technique; Inert atmosphere; Reflux; | 100% |
| In toluene at 90℃; for 14h; | 92% |
- 131211-27-3
di-1-adamantylphosphine
Conditions
| Conditions | Yield |
|---|---|
| With n-butyllithium In tetrahydrofuran; hexane at 20℃; for 3h; | 100% |
