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| CAS No.: | 1314-23-4 |
|---|---|
| Name: | Zirconium dioxide |
| Article Data: | 18 |
| Molecular Structure: | |
|
|
|
| Formula: | ZrO2 |
| Molecular Weight: | 123.223 |
| Synonyms: | Norton 9839;Nissan Zirconia Sol NZS 20A;NZS 30A;ZD 100;NSC 12958;E 101;CCRIS 6601;CC 10;CAP (oxide);C.I. Pigment White 12;Zirconium oxide;Zirox Zt 35;Zirconium White;Zirconic anhydride;Zircoa 5027;Torayceram;Pigment White 12;PCS (filler);Nyacol Zr (acetate); |
| EINECS: | 215-227-2 |
| Density: | 5.89 g/mL at 25 °C(lit.) |
| Melting Point: | 2700 °C(lit.) |
| Boiling Point: | 4300 °C |
| Flash Point: | 5000°C |
| Solubility: | insoluble in water |
| Appearance: | White to yellow-brown Powder |
| Hazard Symbols: |
 Xi
|
| Risk Codes: | 36/37/38 |
| Safety: | 26-36/37-39 |
| Transport Information: | UN 1993 |
| PSA: | 0.00000 |
| LogP: | -0.23760 |
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zirconium
- 6909-54-2
hydrogen peroxide
A
- 1314-23-4
zirconium(IV) oxide
C
- 872215-17-3
Zr(O(2)H)2
E
- 872207-76-6
Zr(O(2)H)4
| Conditions | Yield |
|---|---|
| In neat (no solvent) laser ablated Zr co-deposited with D2O2 in excess Ar onto a 10K CsI window, annealed at 22-28 K; not isolated, detected by IR; |
- 7440-67-7
zirconium
- 7722-84-1
dihydrogen peroxide
A
- 1314-23-4
zirconium(IV) oxide
C
- 42037-27-4
zirconium dihydroxide
E
- 756456-88-9, 14475-63-9
zirconium tetrahydroxide
| Conditions | Yield |
|---|---|
| In neat (no solvent) byproducts: H2O; Irradiation (UV/VIS); laser ablated Zr co-deposited with H2O2 in excess Ar onto a 10K CsI window, UV irradiated, annealed at 22-30 K; not isolated, detected by IR; | |
| In neat (no solvent) byproducts: H2O; Irradiation (UV/VIS); (further products), laser ablated Zr co-deposited with H2O2 in excess Aronto a 10K CsI window, UV irradiated, annealed at 24-30 K; not isolated, detected by IR; |
- 1314-23-4
zirconium(IV) oxide
- 80937-33-3
oxygen
| Conditions | Yield |
|---|---|
| Stage #1: zirconium(IV) oxide; rhodium (III) acetate; oxygen In water at 20 - 120℃; for 2.5h; Stage #2: at 970℃; for 2h; |
- 108-31-6
maleic anhydride
- 1314-23-4
zirconium(IV) oxide
- 108-91-8
cyclohexylamine
- 1631-25-0
N-cyclohexylmaleimide
| Conditions | Yield |
|---|---|
| In 5,5-dimethyl-1,3-cyclohexadiene |
- 108-31-6
maleic anhydride
- 1314-23-4
zirconium(IV) oxide
- 109-73-9
N-butylamine
- 1631-25-0
N-cyclohexylmaleimide
| Conditions | Yield |
|---|---|
| With sulfuric acid In toluene |
| Conditions | Yield |
|---|---|
| Stage #1: zirconium(IV) oxide; iron(III) oxide; vanadium(V) oxide; phosphorus pentoxide for 3h; Milling; Stage #2: at 749.84℃; for 8h; |
| Conditions | Yield |
|---|---|
| Stage #1: zirconium(IV) oxide; iron(III) oxide; vanadium(V) oxide; phosphorus pentoxide for 3h; Milling; Stage #2: at 749.84℃; for 8h; |
| Conditions | Yield |
|---|---|
| Stage #1: zirconium(IV) oxide; iron(III) oxide; vanadium(V) oxide; phosphorus pentoxide for 3h; Milling; Stage #2: at 749.84℃; for 8h; |
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Chemistry
IUPAC Name: dioxozirconium
Synonyms: AI3-29087 ; C.I. 77990 ; C.I. Pigment White 12 ; CAP (oxide) ; CC 10 ; CCRIS 6601 ; E 101 ; NSC 12958 ; NZS 30A ; Nissan Zirconia Sol NZS 20A ; Norton 9839 ; Nyacol Zr (acetate) ; PCS (filler) ; Pigment White 12 ; Rhuligel ; TZ 3YTSK ; Torayceram ; Sol ZS-OA ; ZD 100 ; Zircoa 5027 ; Zirconic anhydride ; Zirconium White ; Zirconium oxide ; Zirconium oxide (VAN) ; Zirox Zt 35
Molecular Weight: 123.2228 [g/mol]
Molecular Formula: O2Zr
H-Bond Donor: 0
H-Bond Acceptor: 2
EINECS: 215-227-2
Canonical SMILES: O=[Zr]=O
InChI: InChI=1S/2O.Zr
InChIKey: MCMNRKCIXSYSNV-UHFFFAOYSA-N
Density: 5.89 g/mL at 25 °C(lit.)
Melting Point: 2700 °C(lit.)
Flash Point: 5000°C
Boiling Point: 5000 °C(lit.)
Solubility: insoluble
Water Solubility: insoluble
Stability: Stable
Product Categories: Inorganics;Biocompatible CeramicsMaterials Science;Biocompatible/Biodegradable Materials;40: Zr;Catalysis and Inorganic Chemistry;Materials Science;Nanomaterials;Nanoparticles: Oxides, Nitrides, and Other CeramicsChemical Synthesis;Nanopowders and Nanoparticle Dispersions;Oxides;ZirconiumMetal and Ceramic Science;ZirconiumNanomaterials
Following is the molecular structure of Zirconium dioxide (CAS NO.1314-23-4) is:
Uses
Zirconium dioxide (CAS NO.1314-23-4) can be instead of lime for the oxyhydrogen light.
Safety Profile
Safty information about Zirconium dioxide (CAS NO.1314-23-4) is:
Hazard Codes:
Xi
Risk Statements:
R36/37/38:Irritating to eyes, respiratory system and skin.
R36/37:Irritating to eyes and respiratory system.
Safety Statements:
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37:Wear suitable protective clothing and gloves.
S39:Wear eye / face protection.
S36:Wear suitable protective clothing.
RIDADR: UN1993
WGK Germany: 1
RTECS: ZH8800000
HazardClass: 3
PackingGroup: III
HS Code: 28256000
Specification
Zirconium dioxide (CAS NO.1314-23-4) ,also can be known as zirconia (not to be confused with zircon), it is a white crystalline. Its most naturally occurring form, with a monoclinic crystalline structure, is the rare mineral, baddeleyite. It is one of the most studied ceramic materials. Pure ZrO2 has a monoclinic crystal structure at room temperature and transitions to tetragonal and cubic at increasing temperatures. Its expansion caused by the cubic to tetragonal to monoclinic transformation induces very large stresses, and will cause pure ZrO2 to crack upon cooling from high temperatures.