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1314-80-3

Basic Information
CAS No.: 1314-80-3
Name: Phosphorus pentasulfide
Molecular Structure:
Molecular Structure of 1314-80-3 (Phosphorus pentasulfide)
Formula: P4S10
Molecular Weight: 444.54
Synonyms: Phosphorus sulfide(Tech Grade);Phosphorus Pentasulphide;Phosphoric sulfide;Phosphorus pentasulfide, free from yellow or white phosphorus (DOT);Sulfur phosphide;Rcra waste number U189;Pentasulfure de phosphore (french);Phosphorus persulfide;Sirnik fosforecny (czech);Thiophosphoric anhydride;
EINECS: 215-242-4
Density: 2.09 g/cm3
Melting Point: 288 °C (561 K)
Boiling Point: 514 °C (787 K)
Solubility: hydrolyses in water, 0.222 g / 100g CS2 (at 17 °C), insoluble in C6H6, insoluble in hot xylene, insoluble in hot anisole
Appearance: yellow solid
Hazard Symbols: FlammableF,HarmfulXn,DangerousN
Risk Codes: 11-20/22-29-50
Safety: 61
Transport Information: UN 1340
PSA: 221.94000
LogP: 4.96340
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  • Phosphorus pentasulfide

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    1314-80-3

    Phosphorus pentasulfide

    Min.Order: 1 Kilogram

    FOB Price:  USD $ 0.0-0.0

    Phosphorus pentasulfide CAS NO. 1314-80-3 diphosphorus pentasulfide; Phosphorus(V)sulfide; Phosphorous Pentasulfide; Phosphorus(V) sulfide; tricyclo[3.3.1.1~3,7~]tetraphosphathiane 1,3,5,7-tetrasulfide; dithiodiphosphoric acid Appearance:Gray t

    QINGDAO SUN TECH INDUSTRIES & TRADING CO., LTD. is specialized in the research, development, manufacturing and marketing of various chemicals. Stick to the mission of "quality, se

  • QINGDAO SUN TECH INDUSTRIES & TRADING CO., LTD

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    Tel:13792446908

    Address:Chengyang District

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  • Phosphorus pentasulfide

  • Casno:

    1314-80-3

    Phosphorus pentasulfide

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    Phosphorus pentasulfide CAS#1314-80-3 Storage:Keep container tightly closed in a dry, cool and well-ventilated place. Package:25Kg/drum, 150Kg/drum, 200kg/drum, According to request. Transportation:By sea, by air.

    Orchid Chemical was established in 2009; we are headquartered in Hangzhou, which is 200 km from China's biggest sea port, Shanghai. Orchid chemical is a joint-venture company, com

  • ORCHID CHEMICAL SUPPLIES LTD

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    Address:607, North Zhongshan Road, Hangzhou 310000 China

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  • Phosphorus pentasulfide

  • Casno:

    1314-80-3

    Phosphorus pentasulfide

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

    United Scientific Company (USC) Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. USC has both the expertise and flexibility

  • Shanghai united Scientific Co.,Ltd.

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    Tel:+86-21-53535353

    Address:28F No.900 huaihai Road Shanghai China

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  • Phosphorus pentasulfide

  • Casno:

    1314-80-3

    Phosphorus pentasulfide

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    Joyinchem have been committed to chemical supply for several years and have built good cooperation records with multinational chemical corporations and importers from all over the world. Our services include:-Spot goods-Contract manufacturing-Custom

    Chungking Joyinchem Co.,Ltd is a specialized Chinese chemical supplier focusing on product R&D, manufacture and marketing. Our head office locates in Wulong district and the facto

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    Tel:+86-23-77778019

    Address:No. 55, Longhu Road, Xiangkou Town, Wulong District, Chungking City, 408500, P.R China

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  • Phosphorus pentasulfide

  • Casno:

    1314-80-3

    Phosphorus pentasulfide

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    The product is mainly used in Lubricant Additives, Metal Flotation Reagent, Agricultural chemicals-pesticide, dye and so on. It is packed in steel Drums with 200 KG or Tote Bins with more than 2.0 MT.…

    With a factory area up to 11,800 square meters, Tianjin yongtai Xingbang Chemical Company ?is a limited company featuring a combination of products research, manufacturing and sale

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Consensus Reports

Reported in EPA TSCA Inventory.

Standards and Recommendations

OSHA PEL: TWA 1 mg/m3; STEL 3 mg/m3
ACGIH TLV: TWA 1 mg/m3; STEL 3 mg/m3
DFG MAK: 1 mg/m3
DOT Classification:  4.3; Label: Dangerous When Wet

Specification

The Phosphorus pentasulfide, with the CAS registry number 1314-80-3, is also known as Pentasulfure de phosphore. It belongs to the product category of Inorganics. Its EINECS registry number is 215-242-4. This chemical's molecular formula is P4S10 and molecular weight is 444.555. Its systematic name is called tricyclo[3.3.1.13,7]tetraphosphathiane 1,3,5,7-tetrasulfide. What's more, this chemical's classification code is Skin / Eye Irritant.

Physical properties of Phosphorus pentasulfide: (1)#H bond acceptors: 0; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 0; (4)Polar Surface Area: 319.4 Å2; (5)Index of Refraction: 2.029; (6)Molar Refractivity: 98.95 cm3; (7)Molar Volume: 194.1 cm3; (8)Surface Tension: 175.7 dyne/cm; (9)Density: 2.28 g/cm3.

Preparation of Phosphorus pentasulfide: this chemical is obtained by the reaction of liquid white phosphorus (P4) with sulfur above 300 °C. The first synthesis of P4S10 by Berzelius in 1843 was by this method. Alternatively, P4S10 can be formed by reacting elemental sulfur or pyrite, FeS2, with ferrophosphorus, impure Fe2P (a byproduct of P4 production from phosphate rock):

4 Fe2P + 18 S → P4S10 + 8 FeS
4 Fe2P + 18 FeS2 + heat → P4S10 + 26 FeS

Uses of Phosphorus pentasulfide: The compound is mainly converted to other derivatives for use as lubrication additives such zinc dithiophosphates. It is also used in the production of pesticides such as Parathion and Malathion. It is also a component of some amorphous solid electrolytes (e.g. Li2S-P2S5) for some types of lithium batteries. Phosphorus pentasulfide is a dual-use material, as it can be used for manufacture of the VX nerve agent.

When you are using this chemical, please be cautious about it as the following:
This chemical may catch fire in contact with air and only need brief contact with an ignition source which has a very low flash point or evolve highly flammable gases in contact with water. Meanwhile. this chemical may cause damage to health and may present an immediate or delayed danger to one or more components of the environment. On the other hand, it is highly flammable and is harmful by inhalation and if swallowed. Contact with water, it will liberate toxic gas. You should avoid releasing it to the environment.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: P12(=S)SP3(=S)SP(=S)(S1)SP(=S)(S2)S3
(2)InChI: InChI=1S/P4S10/c5-1-9-2(6)12-3(7,10-1)14-4(8,11-1)13-2
(3)InChIKey: CYQAYERJWZKYML-UHFFFAOYSA-N

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rabbit LD50 skin 3160mg/kg (3160mg/kg) SKIN AND APPENDAGES (SKIN): "DERMATITIS, OTHER: AFTER SYSTEMIC EXPOSURE" National Technical Information Service. Vol. OTS0571217,
rat LD50 oral 389mg/kg (389mg/kg)   "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972Vol. -, Pg. 16, 1972.