Detail of "13159-52-9"

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CAS Number:
13159-52-9
Name:
2-Propenoic acid,2-methyl-, 3-chloro-2-hydroxypropyl ester
Molecular Structure:
Formula:
C7H11 Cl O3
Molecular Weight:
178.61
Synonyms:
Methacrylicacid, 3-chloro-2-hydroxypropyl ester (7CI,8CI); 1,2-Propanediol, 3-chloro-,1-methacrylate (8CI); 1-Chloro-3-methacryloxy-2-propanol;2-Hydroxy-3-chloropropyl methacrylate; 3-Chloro-2-hydroxyprop-1-ylmethacrylate; 3-Chloro-2-hydroxypropyl methacrylate; Noimer M; Topolene M; b-Hydroxy-g-chloropropyl methacrylate
Density:
1.177g/cm³
Boiling Point:
287.4°Cat760mmHg
Flash Point:
127.6°C
Hazard Symbols:
Risk Codes:
22-38-41-43
Safety:
Hazard Codes Xn
Risk Statements 22-38-41-43
Safety Statements 26-36
WGK Germany 3

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Fluorine-containing copolymers: Fluorine-containing copolymers. Korzeniowski, Stephen Howard (du Pont de Nemours, E. I., and Co. , USA). Eur. Pat. Appl. EP 124236 A1 7 Nov 1984, 22 pp. DESIGNATED STATES: R: BE, CH, DE, FR, GB, IT, LI, LU, NL, SE. (English). (European Patent Organization). CODEN: EPXXDW. CLASS: IC: C08F220-24; D06M015-38. APPLICATION: EP 84-301916 21 Mar 1984. PRIORITY: US 83-479738 28 Mar 1983; US 84-578009 13 Feb 1984. DOCUMENT TYPE: Patent CA Section: 40 (Textiles) Fluoropolymers contg 65-75 parts fluorinated monomers and 25-35 parts 3-chloro-2-hydroxypropyl (meth)acrylate are prepd. for use as soil proofing, oil proofing, and water proofing agents for polyaminde fibers. Thus, methacrylic acid [79-41-4] 86.0, epichlorihydrin [106-89-8] 84.0, PhCH2N+Et3Cl- 8.6, and MeOH 21.4 g were heated 18 h at 40-50° to give 122.1 g 3-chloro-3-hydroxypropyl methacrylate (I) [13159-52-9]. I 30, 2:::3 F3CCF2(CF2)nC2H4O2CCMe:CH2 mixt. (n = 2,4,6,8,10,12) 170, and C12H25SH 2 g in 220 g MIBK were heated 1 h at 67-73°, mixed with 4 g 2,2'-azobis(2-methylbutanenitrile) in 20 g MIBK over 15 min, heated 18 h at 67-73°, and heated 1 h at 90° to give 438 g copolymer [94290-15-0] having 46.15% solids. The copolymer was dissolved in CF2ClCCl2F-Me2CO mixt. to give a soln. contg. 0.84 g copolymer, applied to nylon 66 fibers, heat set 2 min at 200° and washed 5 times to give samples having F retention 86% and oil/water repellencey 5/5.

Reaction of methacrylic acid and epichlorohydrin during catalysis by tertiary amines: Reaction of methacrylic acid and epichlorohydrin during catalysis by tertiary amines. Maslyuk, A.Some chemicals with cas registry numbers like 100-37-8 and 13159-52-9 are also used. F.; Bereznitskii, G. K.; Grishchenko, V. K.; Degtyarev, V. A. (Inst. Khim. Vysokomol. Soedin., Kiev, USSR). Ukr. Khim. Zh. (Russ. Ed.), 50(1), 92-7 (Russian) 1984. CODEN: UKZHAU. ISSN: 0041-6045. DOCUMENT TYPE: Journal CA Section: 35 (Chemistry of Synthetic High Polymers) Section cross-reference(s): 23 3-Chloro-2-hydroxypropyl methacrylate [13159-52-9] which could be used without preliminary purifn. in reactions with isocyanates to give light-sensitive oligourethanes with terminal chloropropyl methacrylate groups was prepd. in 97-98% yields by reaction of epichlorohydrin (I) [106-89-8] with methacrylic acid (II) [79-41-4] at 85° and I-II molar ratio 1.1 in the presence of 0.284-0.323 mol/L Et3N [121-44-8] or b-(diethylamino)ethanol [100-37-8] catalyst. The reaction of I with II was an overall 2nd-order reaction, being 1st order in I and the tertiary amine and 0 order in II. An intermediate ionic complex between II and the amine was formed in the reaction. .