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1319-46-6

Basic Information
CAS No.: 1319-46-6
Name: Lead(II) carbonate basic
Molecular Structure:
Molecular Structure of 1319-46-6 (Lead(II) carbonate basic)
Formula: 2PbCO3.Pb(OH)2
Molecular Weight: 775.63
Synonyms: Silver White;Almex;Bis(carbonato)dihydroxytrilead;Lead,bis[carbonato(2-)]dihydroxytri-;Lead subcarbonate;White lead;C.I. Pigment White 1;Basic carbonate white lead;Berlin White;Lead Carbonate,Basic;Lead(II) carbonate, basic;
EINECS: 215-290-6
Density: 6,14 g/cm3
Melting Point: 400 °C (dec.)(lit.)
Boiling Point: 333.6 °C at 760 mmHg
Flash Point: 169.8 °C
Solubility: insoluble in water
Appearance: dense white powder
Hazard Symbols: ToxicT; DangerousN
Risk Codes: 61-20/22-33-50/53-62
Safety: 53-45-60-61
Transport Information: UN 2291 6.1/PG 3
PSA: 166.84000
LogP: -6.39000
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Specification

The Lead hydroxide carbonate, with the CAS registry number 1319-46-6 and EINECS registry number 215-290-6, has the IUPAC name of lead(2+) dicarbonate dihydroxid. And the molecular formula of this chemical is 2PbCO3.Pb(OH)2. It is a kind of dense white powder, and belongs to the following product categories: Inorganics; Lead Salts; Metal and Ceramic Science; Salts; Analytical Reagents; Analytical Reagents for General Use; Puriss.

The physical properties of Lead hydroxide carbonate are as following: (1)#H bond acceptors: 8; (2)#H bond donors: 6; (3)#Freely Rotating Bonds: 0; (4)Polar Surface Area: 126.38 Å2.

Preparation of Lead hydroxide carbonate: Pass the carbon dioxide in to the reaction solution which contains leadacetate, massicot and deionized water. Then after a series of sedimentation, crystallization, dehydration, washing and drying, you can get the product. And the reactions equation are:
Pb(Ac)2 + PbO + H2O → Pb(Ac)2.Pb(OH)2
3[Pb(Ac)2.Pb(OH)2] + CO2 → 3Pb(Ac)2 + 2PbCO3.Pb(OH)2 + 2H2O

Uses of Lead hydroxide carbonate: It is a white paint used in the production of anticorrosion paint and outdoor paint. And it is also used as the raw material of cosmetics, colored glaze and dope. Besides, it is the stabilizing agent for vinyl chloride plastic, and also used in the tin-lead plating.

You should be cautious while dealing with this chemical. It is harmful by inhalation and if swallowed, and has the danger of cumulative effects. It may also cause harm to the unborn child. In addition, it is very toxic to aquatic organisms, and may cause long-term adverse effects in the aquatic environment. Therefore, you had better take the following instructions: Avoid exposure - obtain special instruction before use; In case of accident or if you feel unwell, seek medical advice immediately (show label where possible); This material and/or its container must be disposed of as hazardous waste; Avoid release to the environment. Refer to special instructions safety data sheet.

You can still convert the following datas into molecular structure:
(1)SMILES: C(=O)([O-])[O-].C(=O)([O-])[O-].[OH-].[OH-].[Pb+2].[Pb+2].[Pb+2]
(2)InChI: InChI=1/2CH2O3.2H2O.3Pb.6H/c2*2-1(3)4;;;;;;;;;;;/h2*(H2,2,3,4);2*1H2;;;;;;;;;/q;;;;3*+2;;;;;;/p-6/r2CH2O3.2H2O.3H2Pb/c2*2-1(3)4;;;;;/h2*(H2,2,3,4);5*1H2/q;;;;3*+2/p-6
(3)InChIKey: RZCMDZAYEFUPDZ-CULGMVJYAU