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| CAS No.: | 13292-87-0 |
|---|---|
| Name: | Borane-methyl sulfide complex |
| Article Data: | 18 |
| Molecular Structure: | |
|
|
|
| Formula: | C2H6S.BH3 |
| Molecular Weight: | 75.9705 |
| Synonyms: | Borane,compd. with thiobis[methane] (1:1);Borine, compd. with Me2S (6CI);Methylsulfide, compd. with BH3 (7CI);Methyl sulfide, compd. with borane (1:1) (8CI);Borane, compd. with methyl sulfide (1:1) (8CI);Methane, thiobis-, compd. with borane (1:1);(Dimethyl sulfide)borane;(Dimethyl sulfide)trihydroboron;Borane-dimethyl sulfide (1:1);Borane-dimethyl sulfide complex (1:1);Dimethylsulfane compd. with borane (1:1);Dimethylsulfide trihydroborane;Trihydro(dimethyl sulfide)boron; |
| EINECS: | 236-313-6 |
| Density: | 1.28 g/cm3 |
| Melting Point: | -40 - -37 °C |
| Boiling Point: | ~34°C |
| Flash Point: | 18 °C |
| Solubility: | reacts with water |
| Appearance: | clear colorless to light yellow solution |
| Hazard Symbols: |
 F,  Xn,  F+,  Xi
|
| Risk Codes: | 12-14/15-19-20/22-37/38-41-67-65-63-48/20-38-11-22-14-40-36-21 |
| Safety: | 36/37-62-36/39-33-26-23-16-36-24/25-7/8 |
| Transport Information: | UN 3399 4.3/PG 1 |
| PSA: | 38.80000 |
| LogP: | -0.47240 |
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| Conditions | Yield |
|---|---|
| In not given equimolar mixt. of products not sepd., detd. by (11)B-NMR spectroscopy; |
- 70160-59-7
C8H14BBrS(CH3)2
A
- 13292-87-0
dimethylsulfide borane complex
B
- 280-64-8
9-bora-bicyclo[3.3.1]nonane
| Conditions | Yield |
|---|---|
| In tetrahydrofuran byproducts: LiBr; 0°C, 0.25 h; detected by 11B NMR; |
| Conditions | Yield |
|---|---|
| With 1,2,2,6,6-pentamethylpiperidine In toluene at 75℃; under 15001.5 Torr; for 4h; Autoclave; | > 90 %Spectr. |
- 353-43-5
boron dimethyl-trifluoro sulphide
- 109-63-7
boron trifluoride diethyl etherate
- 1333-74-0
hydrogen
- 13292-87-0
dimethylsulfide borane complex
| Conditions | Yield |
|---|---|
| With 1,2,2,6,6-pentamethylpiperidine In toluene at 100℃; under 15001.5 Torr; for 2h; Autoclave; | 60 %Spectr. |
| Conditions | Yield |
|---|---|
| at 0 - 5℃; for 1.25h; Inert atmosphere; |
- 29957-59-3
boron tribromide dimethyl sulfide complex
- 13292-87-0
dimethylsulfide borane complex
- 55671-55-1
dibromoborane dimethylsulfide
| Conditions | Yield |
|---|---|
| In benzene at 80℃; for 18h; Inert atmosphere; Glovebox; | 100% |
| In not given molar ratio BH3SMe2:BBr3SMe2 1:2; followed by NMR; |
- 13292-87-0
dimethylsulfide borane complex
- 155566-51-1
2'-hydroxy-2-diphenylphosphinobiphenyl
- 917477-90-8
(2'-hydroxy-biphenyl-2-yl)-diphenylphosphane borane
| Conditions | Yield |
|---|---|
| In tetrahydrofuran; dichloromethane (N2); addn. of soln. of borane complex in THF to soln. of phosphine deriv. in CH2Cl2 at room temp., stirring for 24 h; evapn., NMR; | 100% |
- 50-00-0
formaldehyd
- 627-49-6
Diethylphosphine
- 13292-87-0
dimethylsulfide borane complex
- 635689-45-1
(borane)diethylphosphinomethane alcohol
| Conditions | Yield |
|---|---|
| Stage #1: Diethylphosphine; dimethylsulfide borane complex In tetrahydrofuran for 2h; Stage #2: formaldehyd With potassium hydroxide In tetrahydrofuran; water for 4h; | 100% |
- 13292-87-0
dimethylsulfide borane complex
- 686353-30-0
1-(dipropylphosphanylmethyl-propyl-phosphanyl)-propane
- 1422260-95-4
C13H36B2P2
| Conditions | Yield |
|---|---|
| In diethyl ether for 2h; Inert atmosphere; Schlenk technique; | 100% |
- 13292-87-0
dimethylsulfide borane complex
- 1420831-79-3
[Ir(fac-bis[(2-diphenylphosphino)phenyl]phosphide)(COD)]
| Conditions | Yield |
|---|---|
| In toluene at 20℃; Inert atmosphere; Schlenk technique; | 100% |
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Chemistry
is C2H9BS and its formula weight is 75.97.
The density of Borane-methyl sulfide complex(13292-87-0)
is 1.287 g/mL at 25 °C and it has a melting point of -40~-37°C.
The chemical synonyms of Borane-methyl sulfide complex(13292-87-0)
are METHYL SULFIDE BORANE;DIMETHYL SULFIDE BORANE;DMSB;BORANE-METHYL SULFIDE COMPLEX;BORANE-DIMETHYLSULFIDE;BORANE-DIMETHYLSULFIDE COMPLEX;BORANE DIMETHYL SULPHIDE COMPLEX;BMS
The molecular structure of Borane-methyl sulfide complex(13292-87-0)
:
Toxicity Data With Reference
RTECS#: CAS# 75-09-2: PA8050000
CAS# 13292-87-0: PV5080000
LD50/LC50: RTECS:
CAS# 75-09-2: Draize test, rabbit, eye: 162 mg Moderate;
Draize test, rabbit, eye: 10 mg Mild;
Draize test, rabbit, eye: 500 mg/24H Mild;
Draize test, rabbit, skin: 810 mg/24H Severe;
Draize test, rabbit, skin: 100 mg/24H Moderate;
Inhalation, mouse: LC50 = 14400 ppm/7H;
Inhalation, mouse: LC50 = 49100 mg/m3/6H;
Inhalation, mouse: LC50 = 54000 mg/m3/2H;
Inhalation, mouse: LC50 = 56220 mg/m3/7H;
Inhalation, rat: LC50 = 52 gm/m3;
Inhalation, rat: LC50 = 76000 mg/m3/4H;
Inhalation, rat: LC50 = 52000 mg/m3/6H;
Oral, mouse: LD50 = 873 mg/kg;
Oral, rabbit: LD50 = 2000 mg/kg;
Oral, rat: LD50 = 1600 mg/kg;
Oral, rat: LD50 = 985 mg/kg;
RTECS:
CAS# 13292-87-0: Draize test, rabbit, eye: 100 mg Severe;
Carcinogenicity: Methylene chloride - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to humans California: carcinogen, initial date 4/1/88 NTP: Suspect carcinogen IARC: Group 2B carcinogen
Borane-methyl sulfide complex - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
Other: The toxicological properties have not been fully investigated. See actual entry in RTECS for complete information. Possible carcinogen.
Consensus Reports
Safety Profile
Hazard Codes F+,Xn,F,Xi
Risk Statements 12-14/15-19-20/22-37/38-41-67-65-63-48/20-38-11-22-14-40-36-21
Safety Statements 36/37-62-36/39-33-26-23-16-36-24/25-7/8
RIDADR UN 3399 4.3/PG 1
WGK Germany 3
RTECS PV5080000
F 10-13-23
HazardClass 4.3
PackingGroup II
Specification
Conditions to Avoid: Incompatible materials, ignition sources, exposure to moist air or water.
Incompatibilities with Other Materials Water, water, acids, acid chlorides, alcohols, acid anhydrides.
Hazardous Decomposition Products Hydrogen chloride, carbon monoxide, oxides of sulfur, carbon dioxide, oxides of boron, borane.
Hazardous Polymerization Will not occur.