Detail of "13294-71-8"

Reference

3-Methyl-3-pentenenitrile

3-Methyl-3-pentenenitrile. Kametani, Tetsuji (Sendai Heterocyclic Chemical Research Foundation, Japan). Japan. Kokai JP 51122022 25 Oct 1976 Showa, 4 pp. (Japanese). (Japan). CODEN: JKXXAF. CLASS: IC: C07C121-30. APPLICATION: JP 75-44359 14 Apr 1975. DOCUMENT TYPE: Patent CA Section: 23 (Aliphatic Compounds) 2-Halo-2-butenes were treated with alkali metal and HCHO and the resulting MeCH:CMeCH2OH (I) was converted via its halide to MeCH:CMeCH2CN (II). Thus, 20 g MeCH:CMeBr was treated with 2.3 g Li in Et2O at -10.degree.There are some commonly used reagents with their cas registry numbers 13294-71-8 and 4675-87-0 in this article. and HCHO was introduced to give 8 g I. I (10 g) was treated with PBr3 in CH2Cl2 and the resulting bromide was stirred with 10 g CuCN in DMF at room temp. for 25 h to give 6 g II. .