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13454-96-1

Basic Information
CAS No.: 13454-96-1
Name: Platinum tetrachloride
Article Data: 76
Molecular Structure:
Molecular Structure of 13454-96-1 (Platinum tetrachloride)
Formula: PtCl4
Molecular Weight: 336.892
Synonyms: Platinumchloride (PtCl4) (6CI,7CI,8CI);Platinum(IV) chloride;Platinum(IV) tetrachloride;Tetrachloroplatinum;
EINECS: 236-645-1
Density: 4.303 g/cm3
Melting Point: 370 °C
Solubility: 587 g/L (25 °C) in water
Appearance: brown/red crystals
Hazard Symbols: CorrosiveC
Risk Codes: 22-34-42/43
Safety: 26-27-36/37/39-45-24-22
Transport Information: UN 2923 8/PG 3
PSA: 0.00000
LogP: 2.75550
Synthetic route
7791-25-5

sulfuryl dichloride

7440-06-4

platinum

13454-96-1

platinum(IV) chloride

Conditions
ConditionsYield
In neat (no solvent) heating for some days to 150°C;;
In neat (no solvent) some days (150°C); platinum wire;;
In neat (no solvent) heating for some days to 150°C;;
7647-01-0

hydrogenchloride

7440-06-4

platinum

13454-96-1

platinum(IV) chloride

Conditions
ConditionsYield
With tris-(2-chloro-ethyl)-amine In not given byproducts: NH3, N2; Pt is dissolved in a mixture of HCl and HN3;;
With HN3 In not given byproducts: NH3, N2; Pt is dissolved in a mixture of HCl and HN3;;
7782-50-5

chlorine

7440-06-4

platinum

13454-96-1

platinum(IV) chloride

Conditions
ConditionsYield
In neat (no solvent) at 1700°C;;
In neat (no solvent) High Pressure; Pt metal reacted with Cl2 under pressure 50 atm in thick-wall quartz tube at 200°C for 5 d; XRD, IR, elem. anal.;
In neat (no solvent) at 1700°C;;
7782-50-5

chlorine

7440-06-4

platinum

A

25909-39-1

platinum trichloride

B

13454-96-1

platinum(IV) chloride

Conditions
ConditionsYield
In neat (no solvent) platinum black is heated in a Cl2 stream to 360°C, fast cooling;;
In neat (no solvent) platinum black is heated in a Cl2 stream to 360°C, fast cooling;;
10025-99-7

potassium tetrachloroplatinate(II)

13454-96-1

platinum(IV) chloride

Conditions
ConditionsYield
With CoW12O40(5-) In water Kinetics; byproducts: CoW12O40(6-); oxidation of Pt(II) by Co(III)W12O40(5-) in H2O at 25.0°C; mechanism discussed; not isolated, detected by UV spectroscopy;
7790-46-7

platinum tetraiodide

A

dihydrogen hexachloroplatinate

B

7553-56-2

iodine

C

7790-99-0

Iodine monochloride

D

13454-96-1

platinum(IV) chloride

Conditions
ConditionsYield
With chlorine In water composition of product depends on amount of Cl2;
With Cl2 In water composition of product depends on amount of Cl2;
7790-46-7

platinum tetraiodide

A

7790-99-0

Iodine monochloride

B

13454-96-1

platinum(IV) chloride

Conditions
ConditionsYield
With chlorine in cold Cl2 flow;
With Cl2 in cold Cl2 flow;

platinum(IV) chloride pentahydrate

13454-96-1

platinum(IV) chloride

Conditions
ConditionsYield
byproducts: H2O; heating in vacuum at 215°C over KOH;
at 215°C in vacuum over KOH;
byproducts: H2O; heating in vacuum at 215°C over KOH;
at 215°C in vacuum over KOH;

platinum diselenide

13454-96-1

platinum(IV) chloride

Conditions
ConditionsYield
With chlorine in Cl2 flow at 300°C;0%
With Cl2 in Cl2 flow at 300°C;0%

platinum diselenide

7784-34-1

arsenic trichloride

13454-96-1

platinum(IV) chloride

Conditions
ConditionsYield
at 300°C;0%
at 300°C;0%
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Consensus Reports

Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Standards and Recommendations

OSHA PEL: TWA 0.002 mg(Pt)/m3
ACGIH TLV: TWA 0.002 mg(Pt)/m3

Specification

The IUPAC name of Platinum(IV) chloride is tetrachloroplatinum. With the CAS registry number 13454-96-1 and EINECS 236-645-1, it is also named as Platinum chloride (PtCl4). The classification code are Mutation data; Reproductive Effect; Skin / Eye Irritant. It is brown/red crystals which is stable under normal temperature and pressure. Additionally, this chemical should be sealed in the container and stored in the cool and dry place.

The other characteristics of this product can be summarized as: (1)H-Bond Donor 0; (2)H-Bond Acceptor 0; (3)Rotatable Bond Count 0; (4)Exact Mass 336.837235; (5)MonoIsotopic Mass 334.840185; (6)Topological Polar Surface Area 0; (7)Heavy Atom Count 5; (8)Formal Charge 0; (9)Complexity 19.1; (10)Isotope Atom Count 0; (11)Covalently-Bonded Unit Count 1.

Preparation of Platinum(IV) chloride: It is mainly encountered in the handling of chloroplatinic acid, obtained by dissolving of Pt metal in aqua regia. Heating H2PtCl6 gives PtCl4: H2PtCl6 → PtCl4 + 2 HCl

Uses of Platinum(IV) chloride: It is used as analytical reagent and catalytic agent. It is also used in the extension and diffusion processes for semiconductor production.

When you are using this chemical, please be cautious about it as the following:
It is not only harmful if swallowed, but also may cause sensitization by inhalation and skin contact. And it can cause burns. So people should not breathe dust and avoid contact with skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If you want to contact this product, you must wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)

People can use the following data to convert to the molecule structure. 
1. Smiles:[Pt](Cl)(Cl)(Cl)Cl
2. InChI:InChI=1/4ClH.Pt/h4*1H;/q;;;;+4/p-4

The following are the toxicity data which has been tested.

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LD50 oral 276mg/kg (276mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 21(7), Pg. 55, 1977.

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