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13477-34-4

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Basic Information
CAS No.: 13477-34-4
Name: Calcium nitrate tetrahydrate
Article Data: 204
Molecular Structure:
Molecular Structure of 13477-34-4 (Calcium nitrate tetrahydrate)
Formula: Ca(NO3)2.4(H2O)
Molecular Weight: 164.088
Synonyms: Calciumdinitrate tetrahydrate;Calciumnitrate tetrahydrate;Nitric acid calcium salt (2:1) tetrahydrate;
EINECS: 233-332-1
Density: 1.86 g/cm3
Melting Point: 44 °C (dec.)(lit.)
Boiling Point: 83 °C at 760 mmHg
Flash Point: 132°C
Solubility: water: 1 M at 20 °C, clear, colorless
Appearance: white crystal
Hazard Symbols: OxidizingO,IrritantXi
Risk Codes: 8-36-36/37/38
Safety: 17-26-36/37/39-39-36
Transport Information: UN 1454 5.1/PG 3
PSA: 174.68000
LogP: 0.31100
Synthetic route

soda lime

156-62-7

calcium cyanamide

13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
With air; copper(II) oxide; copper(II) carbonate; nickel(II) carbonate In neat (no solvent) storage of thin layer of mixt. of lime nitrogen, soda lime and CuO on air for few days; addn. of catalyst, heating in dry stream of air at 400°C, until oxidn. of C is complete; heating up to 3 h at 450°C; acceleration by min. of H2O vapor;;38%
10102-43-9

nitrogen(II) oxide

A

calcium nitrite

B

7727-37-9

nitrogen

C

13477-34-4

calcium(II) nitrate

D

10024-97-2

dinitrogen monoxide

Conditions
ConditionsYield
With calcium oxide 400°C, 21 h;A 0.9%
B n/a
C <1
D n/a
With CaO 400°C, 21 h;A 0.9%
B n/a
C <1
D n/a

dolomite

7697-37-2

nitric acid

calcium oxide

A

13477-34-4

calcium(II) nitrate

B

magnesium oxide

Conditions
ConditionsYield
In water addn. of HNO3 to dolomite also dissolves Mg; removal as Mg(OH)2 with CaO;;

dolomite

7697-37-2

nitric acid

13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
In water dolomite slurry filtered and treated with HNO3; CaCO3 dissolves, and MgCO3 remains undissolved;;
With calcium(II) nitrate In water dolomite dissolved in Ca(NO3)3 soln. containing at most 1% HNO3;;
In water amt. of applied acid insufficient to dissolve also MgCO3;;

dolomite

7697-37-2

nitric acid

calcium hydroxide

A

13477-34-4

calcium(II) nitrate

B

magnesium oxide

Conditions
ConditionsYield
In water addn. of HNO3 to dolomite also dissolves Mg; removal as Mg(OH)2 with Ca(OH)2;;

ammonium nitrate

dolomite

13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
In ammonia CaCO3 portion of dolomite dissolves in liquid ammonia containing an equivalent amt. of NH4NO3;;

tricalcium diphosphate

2696-92-6

nitrosylchloride

13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
In water intermediately formed nitrogen oxides react to form the nitrates;;
In water intermediately formed nitrogen oxides react to form the nitrates;;

calcium(II) sulfide

7697-37-2

nitric acid

A

7783-06-4

hydrogen sulfide

B

13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
In water

calcium(II) sulfide

ammonium nitrate

13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
trituration at moderate temp.;;
trituration at moderate temp.;;

calcium oxide

A

10544-73-7

dinitrogen trioxide

B

13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
With nitrogen oxides; Fe(OH)3 or Al(OH)3 or Cr(OH)3 In water absorption of nitrogen oxides in suspensions of heavy metal hydroxides and with CaO; then interaction of the intermediately formed nitrates;;
With nitrogen oxides In water absorption of nitrogen oxides in suspensions of heavy metal hydroxides and with CaO; then interaction of the intermediately formed nitrates;;
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Chemistry

Product Name: Calcium nitrate tetrahydrate (CAS NO.13477-34-4)

Molecular Formula: Ca(NO3)2.4(H2O)
Molecular Weight: 236.15g/mol
Mol File: 13477-34-4.mol
Appearance: White colourless deliquescent crystals
Melting Point: 44 °C (dec.)(lit.)
Boiling point: 83 °C at 760 mmHg
Storage Temperature: Store at RT.
Water Solubility: H2O: 1 M at 20 °C, clear, colorless
Sensitive: Hygroscopic
Stability: Stable. Strong oxidizer.
Surface Tension:
Enthalpy of Vaporization: 37.72 kJ/mol
Vapour Pressure: 49.8 mmHg at 25°C
H-Bond Donor: 6
H-Bond Acceptor: 10
Structure Descriptors of Calcium nitrate tetrahydrate (CAS NO.13477-34-4):
  IUPAC Name: calcium nitric acid tetrahydrate
  Canonical SMILES: [N+](=O)(O)[O-].[N+](=O)(O)[O-].O.O.O.O.[Ca+2]
  InChI: InChI=1S/Ca.2HNO3.4H2O/c;2*2-1(3)4;;;;/h;2*(H,2,3,4);4*1H2/q+2;;;;;;
  InChIKey: DKCJOKYHYIAZQH-UHFFFAOYSA-N
Product Categories: Inorganic Salts; Synthetic Reagents; CalciumAnalytical Reagents; Puriss; ACS GradeSynthetic Reagents; Essential Chemicals; Routine Reagents; Analytical Reagents for General Use; C-D, Puriss p.a. ACS; Puriss p.a. ACS

Uses

  Calcium nitrate tetrahydrate (CAS NO.13477-34-4) is mainly used as a component in fertilizers.

Safety Profile

Safety Information of Calcium nitrate tetrahydrate (CAS NO.13477-34-4):
Hazard Codes: OOxidizing,XiIrritant
Risk Statements: 8-36-36/37/38   
R8 :Contact with combustible material may cause fire. 
R36:Irritating to eyes. 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 17-26-36/37/39-39-36
S17:Keep away from combustible material. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S39:Wear eye / face protection. 
S36:Wear suitable protective clothing.
RIDADR: UN 1454 5.1/PG 3
WGK Germany: 1
RTECS: EW3000000
HazardClass: 5.1
PackingGroup: III

Specification

 Calcium nitrate tetrahydrate , its CAS NO. is 13477-34-4, the synonyms are Calcium dinitrate tetrahydrate ;  Dusicnan vapenaty ; Nitric acid, calcium salt, tetrahydrate .