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13478-10-9

Basic Information
CAS No.: 13478-10-9
Name: Ferrous chloride tetrahydrate
Article Data: 2
Molecular Structure:
Molecular Structure of 13478-10-9 (Ferrous chloride tetrahydrate)
Formula: FeCl2.4(H2O)
Molecular Weight: 198.814
Synonyms: Iron chloride tetrahydrate;Iron dichloridetetrahydrate;Iron(II) chloride tetrahydrate;Iron dichloride tetrahydrate;
EINECS: 231-843-4
Density: 1.93 g/cm3
Melting Point: 670 °C
Boiling Point: 100 °C at 760 mmHg
Solubility: soluble in water
Appearance: light green or blue-green crystals
Hazard Symbols: HarmfulXn, CorrosiveC
Risk Codes: 22-38-41-34
Safety: 26-39-45-36/37/39
Transport Information: UN 3260 8/PG 3
PSA: 36.92000
LogP: 1.11930
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Chemistry


IUPAC Name: Iron(2+) dichloride tetrahydrate
Molecular Formula: Cl2FeH8O4
Molecular Weight: 198.81212 g/mol
Canonical SMILES: O.O.O.O.[Cl-].[Cl-].[Fe+2]
InChI: InChI=1S/2ClH.Fe.4H2O/h2*1H;;4*1H2/q;;+2;;;;/p-2
EINECS: 231-843-4
Melting Point: 105 °C
Water Solubility: soluble
Stability: Air, moisture and light-sensitive. Incompatible with strong oxidizing agents, most common metals.
Enthalpy of Vaporization: 40.65 kJ/mol
Boiling Point: 100 °C at 760 mmHg
Vapour Pressure of Iron(2+) chloride, tetrahydrate (CAS NO.13478-10-9): 24.5 mmHg at 25 °C

Uses

 Iron(2+) chloride, tetrahydrate (CAS NO.13478-10-9) can be used in the laboratory synthesis of iron complexes, serves as a reducing flocculating agent in wastewater treatment.

Production

Preparation Products is 1,1'-Dimethylferrocene .

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 93mg/kg (93mg/kg)   Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 244, Pg. 17, 1962.
rabbit LDLo oral 890mg/kg (890mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rabbit LDLo rectal 984mg/kg (984mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rabbit LDLo subcutaneous 189mg/kg (189mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rat LDLo rectal 498mg/kg (498mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.

Safety Profile

Poison by intraperitoneal and subcutaneous routes. Moderately toxic by ingestion and rectal routes. When heated to decomposition it emits toxic fumes of Cl
Hazard Codes:HarmfulXn,CorrosiveC
Risk Statements:
R22:Harmful if swallowed. 
R38:Irritating to skin. 
R41:Risk of serious damage to the eyes. 
R34:Causes burns.
Safety Statements:
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S39:Wear eye / face protection. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
RIDADR: UN 3260 8/PG 3
WGK Germany: 1
RTECS: NO5600000
F:
F 3: Hygroscopic.
F 23: Sensitive to air.
HazardClass: 8
PackingGroup: III
HS Code: 28273300

Standards and Recommendations

ACGIH TLV: TWA 1 mg(Fe)/m3

Specification

  Iron(2+) chloride, tetrahydrate (CAS NO.13478-10-9), its Synonyms are Ferrous chloride, tetrahydrate ; Iron (II) chloride, tetrahydrate ; Iron chloride tetrahydrate ; Iron dichloride tetrahydrate . It is light green or blue-green crystals.