Detail of "13540-50-6"

CAS Number:
13540-50-6
Name:
Benzene,1,4-dimethyl-2-(phenylmethyl)-
Molecular Structure:
Formula:
C₁₅H₁₆
Molecular Weight:
196.29
Synonyms:
2,5-Dimethyldiphenylmethane;2-Benzyl-1,4-dimethylbenzene;1,4-Dimethyl-2-(phenylmethyl)benzene;
Density:
0.974 g/cm³
Boiling Point:
296.6 °C at 760 mmHg
Flash Point:
135.4 °C

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Mechanistic investigations of iron/sulfur-catalyzed bond scission in aromatic hydrocarbons: Mechanistic investigations of iron/sulfur-catalyzed bond scission in aromatic hydrocarbons. A catalytic hydrogen atom transfer step involving a late transition state. Autrey, Tom; Linehan, John C.; Camaioni, Donald M.; Kaune, Lauren E.; Watrob, Heather M.; Franz, James A.There are some reagents with their cas registry numbers 13540-50-6 and 4453-79-6 are used in this study. (Pacific Northwest Laboratory, P.O. Box 999, Richland, WA 99352, USA). Catalysis Today, 31(1-2), 105-111 (English) 1996 Elsevier. CODEN: CATTEA. ISSN: 0920-5861. DOCUMENT TYPE: Journal CA Section: 22 (Physical Organic Chemistry) Section cross-reference(s): 51, 67 The mechanism of carbon-carbon bond scission by 'iron sulfide' catalysts is explored through the use of substituted diphenylmethane model compds. The reaction kinetics are shown to be first order in model compd. with the methylene-arene carbon-carbon bond adjacent to the most substituted arene being selectively cleaved. These results are consistent with the catalyst acting as a hydrogen atom transfer agent. .