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13558-31-1

Basic Information
CAS No.: 13558-31-1
Name: RHODAMINE 110
Article Data: 17
Molecular Structure:
Molecular Structure of 13558-31-1 (RHODAMINE 110)
Formula: C20H15ClN2O3
Molecular Weight: 366.804
Synonyms: Benzoicacid, 2-(6-amino-3-imino-3H-xanthen-9-yl)-, monohydrochloride;Benzoic acid,o-(6-amino-3-imino-3H-xanthen-9-yl)-, monohydrochloride (8CI);Xanthylium,3,6-diamino-9-(2-carboxyphenyl)-, chloride (9CI);R 110;RH 110;Rhodamine 110;Rhodamine 560;Rhodamine N;
EINECS: 236-944-7
Density: 1.2504 (rough estimate)
Melting Point: >300 °C(lit.)
Boiling Point: 629.3°C at 760 mmHg
Flash Point: 334.4°C
Appearance: red to bordeaux crystals or crystalline powder
Hazard Symbols: HarmfulXn
Risk Codes: 22
Safety: 22-24/25
PSA: 100.31000
LogP: 5.44740
Synthetic route
81-88-9

rhodamine B

13558-31-1

rhodamine 110 hydrochloride salt

Conditions
ConditionsYield
With fluorinated BiVO4 In water at 20℃; UV-irradiation;
81-88-9

rhodamine B

A

N,N,N’-triethylrhodamine

B

N-ethylrhodamine

C

2768-89-0

N-ethyl-N'-ethylrhodamine

D

13558-31-1

rhodamine 110 hydrochloride salt

Conditions
ConditionsYield
With BiOI/Fe MIL-88B In water for 2h; Catalytic behavior; Kinetics; Mechanism; Reagent/catalyst; Time; Wavelength; Irradiation;
3282-30-2

pivaloyl chloride

13558-31-1

rhodamine 110 hydrochloride salt

N,N'-bis-pivaloyl rhodamine

Conditions
ConditionsYield
With triethylamine In dichloromethane91%
108-24-7

acetic anhydride

13558-31-1

rhodamine 110 hydrochloride salt

3086-43-9

N,N'-bis-acetyl rhodamine

Conditions
ConditionsYield
With pyridine89%
13558-31-1

rhodamine 110 hydrochloride salt

123-62-6

propionic acid anhydride

N,N'-bis-propionyl rhodamine

Conditions
ConditionsYield
With pyridine In dichloromethane83%
13558-31-1

rhodamine 110 hydrochloride salt

79-30-1

isobutyryl chloride

N,N'-bis-isobutyl rhodamine

Conditions
ConditionsYield
With triethylamine In dichloromethane83%
13558-31-1

rhodamine 110 hydrochloride salt

76-05-1

trifluoroacetic acid

N,N' bis-triflouroacetyl rhodamine

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide for 16h;76%
13558-31-1

rhodamine 110 hydrochloride salt

7087-68-5

N-ethyl-N,N-diisopropylamine

95-54-5

1,2-diamino-benzene

60-32-2

6-aminohexanoic acid

2-(6-(2-(6-amino-3-iminio-3H-xanthen-9-yl)benzamido)hexanamido) benzenaminium 2,2,2-trifluoroacetate

Conditions
ConditionsYield
With O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; triethylamine; trifluoroacetic acid
1002-57-9

8-Aminooctanoic acid

13558-31-1

rhodamine 110 hydrochloride salt

7087-68-5

N-ethyl-N,N-diisopropylamine

95-54-5

1,2-diamino-benzene

2-(8-(2-(6-amino-3-iminio-3H-xanthen-9-yl)benzamido)octanamido) benzenaminium 2,2,2-trifluoroacetate

Conditions
ConditionsYield
With O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; triethylamine; trifluoroacetic acid
56-91-7

p-aminomethylbenzoic acid

13558-31-1

rhodamine 110 hydrochloride salt

7087-68-5

N-ethyl-N,N-diisopropylamine

95-54-5

1,2-diamino-benzene

2-(4-((2-(6-amino-3-iminio-3H-xanthen-9-yl)benzamido)methyl)benzamido) benzenaminium 2,2,2-trifluoroacetate

Conditions
ConditionsYield
With O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; triethylamine; trifluoroacetic acid
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Chemistry

Molecular Structure:

Molecular Formula: C20H15ClN2O3
Molecular Weight: 366.7977
IUPAC Name: [6-amino-9-(2-carboxyphenyl)xanthen-3-ylidene]azanium chloride
Synonyms of Rhodamine 110 chloride (CAS NO.13558-31-1): Rhodamine 110 ; CCRIS 4956 ; EINECS 236-944-7 ; 3,6-Diamino-9-(2-carboxyphenyl)xanthylium chloride ; Rhodamine 560 chloride ; Xanthylium, 3,6-diamino-9-(2-carboxyphenyl)-, chloride ; Xanthylium, 3,6-diamino-9-(2-carboxyphenyl)-, chloride (1:1)
CAS NO: 13558-31-1
Classification Code: Q-R ; Stains and Dyes ; Stains&Dyes,A to
Melting Point: >300 °C 
Flash Point: 334.4 °C
Enthalpy of Vaporization: 97.86 kJ/mol
Boiling Point: 629.3 °C at 760 mmHg
Vapour Pressure of Rhodamine 110 chloride (CAS NO.13558-31-1): 1.06E-16 mmHg at 25°C

Safety Profile

Hazard Codes of Rhodamine 110 chloride (CAS NO.13558-31-1): HarmfulXn
Risk Statements: 22 
R22: Harmful if swallowed. 
Safety Statements: 22-24/25 
S22: Do not breathe dust.
S24/25: Avoid contact with skin and eyes.
WGK Germany: 3