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13568-33-7

Basic Information
CAS No.: 13568-33-7
Name: lithium nitrite
Molecular Structure:
Molecular Structure of 13568-33-7 (lithium nitrite)
Formula: HN O2 . Li
Molecular Weight: 52.9465
Synonyms: Lithiumnitrite (6CI); Nitrous acid, lithium salt (8CI,9CI); LINI 25; LINI 40; Lithiumnitrite (LiNO2)
EINECS: 236-976-1
Density: g/cm3
Melting Point: >100℃ [CRC10]
Boiling Point: °Cat760mmHg
Flash Point: °C
Solubility: very soluble H2O [CRC10]
PSA: 52.49000
LogP: 0.25060
Synthetic route
10102-43-9

nitrogen(II) oxide

1310-65-2

lithium hydroxide

A

13568-33-7

lithium nitrite

B

7727-37-9

nitrogen

C

lithium nitrate

D

10024-97-2

dinitrogen monoxide

Conditions
ConditionsYield
byproducts: H2O; at room temp.;
10102-43-9

nitrogen(II) oxide

1310-65-2

lithium hydroxide

13568-33-7

lithium nitrite

Conditions
ConditionsYield
In neat (no solvent) byproducts: N2O, H2O; slowly reaction with gaseous NO, at 280°C and 90 hours, formation of LiNO2, N2O and H2O;;
In neat (no solvent) byproducts: N2, H2O; slowly reaction with gaseous NO, at 280°C and 90 hours, formation of LiNO2, N2 and H2O;;
In neat (no solvent) byproducts: N2, H2O; slowly reaction with gaseous NO, at 280°C and 90 hours, formation of LiNO2, N2 and H2O;;
In neat (no solvent) byproducts: N2O, H2O; slowly reaction with gaseous NO, at 280°C and 90 hours, formation of LiNO2, N2O and H2O;;
10102-44-0

Nitrogen dioxide

1310-65-2

lithium hydroxide

13568-33-7

lithium nitrite

Conditions
ConditionsYield
With NO In water reaction with nitrous gases, formation of LiNO2;;
7782-77-6

cis-nitrous acid

1310-65-2

lithium hydroxide

13568-33-7

lithium nitrite

Conditions
ConditionsYield
In water neutralization of aq. LiOH with aq. HNO2;;

lithium nitrate

13568-33-7

lithium nitrite

Conditions
ConditionsYield
byproducts: O2; thermal decompn.;
In neat (no solvent) byproducts: O2; on heating LiNO3 above the melting point, decomposition in LiNO2 and O2;;
In neat (no solvent) byproducts: O2; thermal dissociation of LiNO3 above 420°C;;

lithium nitrate

A

13568-33-7

lithium nitrite

B

80937-33-3

oxygen

Conditions
ConditionsYield
In neat (no solvent) Kinetics; temp. 580-620 °C;

lithium nitrate

7440-22-4

silver

A

13568-33-7

lithium nitrite

B

silver(I) chloride

Conditions
ConditionsYield
With KCl In melt 1 h, 400°C;A n/a
B 0%
554-13-2

lithium carbonate

A

13568-33-7

lithium nitrite

B

lithium nitrate

Conditions
ConditionsYield
With nitrous gases In not given reaction with nitrous gases, formation of nitrite, no formation of nitrate;;A n/a
B 0%

indium chloride

lithium nitrate

A

13568-33-7

lithium nitrite

B

indium(III) hydroxide

C

10025-82-8

indium(III) chloride

Conditions
ConditionsYield
In water reaction of an excess of InCl with aq. LiNO3 solns. 20°C;
13453-77-5

lithium nitrite monohydrate

13568-33-7

lithium nitrite

Conditions
ConditionsYield
In neat (no solvent) byproducts: H2O; dehydration on heating at 160°C;;
In neat (no solvent) byproducts: H2O; dehydration in vac. over P2O5;;
In neat (no solvent) byproducts: H2O; dehydration in vac.;;
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