Products Categories
CAS No.: | 13597-92-7 |
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Name: | 2,2,4,4,6,6-hexaamino-2,2,4,4,6,6-hexahydro-1,3,5,2,4,6-triazatriphosphorine |
Article Data: | 15 |
Molecular Structure: | |
Formula: | H12N9 P3 |
Molecular Weight: | 231.077 |
Synonyms: | 1,3,5,2,4,6-Triazatriphosphorine,2,2,4,4,6,6-hexaamino-2,2,4,4,6,6-hexahydro- (7CI,8CI,9CI); Phosphonitrileamide, trimer (6CI);2,2,4,4,6,6-Hexaamino-2,2,4,4,6,6-hexahydro-1,3,5,2,4,6-triazatriphosphorine;Hexaamidocyclotriphosphazine; Hexaaminocyclotriphosphazene;Hexaaminotriazatriphosphorine; NSC 202892; Phosphazene trimer; Phosphonitrileamide, cyclic trimer; Phosphonitrilic hexaamide; Trimer phosphonitrile amide;Triphosphonitrilamide; Triphosphorus trinitridehexamide |
Density: | 3.83g/cm3 |
PSA: | 222.63000 |
LogP: | 2.09940 |
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
ammonia
A
hexaaminocyclotriphosphazene
Conditions | Yield |
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In neat (no solvent) direct react. of (PNCl2)3 with a large excess of liquid NH3 under pressure; react. completed after 48 h;; | A 36% B n/a |
In neat (no solvent) direct react. of (PNCl2)3 with a large excess of liquid NH3 under pressure; react. completed after 48 h;; | A 36% B n/a |
In benzene passing gaseous NH3 in a soln. of (NPCl2)3 in C6H6 for a longer period of time; formation of a mixt. of P3N3(NH2)6 and NH4Cl;; |
phosphorus pentachloride
ammonia
A
hexaaminocyclotriphosphazene
Conditions | Yield |
---|---|
In chloroform addn. of a soln. of PCl5 in CHCl3 to an excess of liquid NH3 at -50 °C;; extraxtion with liquid NH3;; | |
In chloroform addn. of a soln. of PCl5 in CHCl3 to an excess of liquid NH3 at -50 °C;; extraxtion with liquid NH3;; |
phosphorus pentachloride
ammonia
B
hexaaminocyclotriphosphazene
C
P4N12H16
Conditions | Yield |
---|---|
In not given react. of PCl5 with NH3;; |
phosphorus pentachloride
ammonia
A
hexaaminocyclotriphosphazene
B
P4N12H16
Conditions | Yield |
---|---|
In not given react. of PCl5 with NH3; formation of P4N4(NH2)8 and P3N3(NH2)6 as decompn. products of intermediate P(NH2)5;; | |
In not given react. of PCl5 with NH3; formation of an excess of P3N3(NH2)6, P4N4(NH2)8 and higher polymers as decompn. products of intermediate P(NH2)5;; | |
In not given react. of PCl5 with NH3; formation of P4N4(NH2)8 and P3N3(NH2)6 as decompn. products of intermediate P(NH2)5;; | |
In not given react. of PCl5 with NH3; formation of an excess of P3N3(NH2)6, P4N4(NH2)8 and higher polymers as decompn. products of intermediate P(NH2)5;; |
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
ammonia
hexaaminocyclotriphosphazene
hexaaminocyclotriphosphazene
Conditions | Yield |
---|---|
With KNH2 In ammonia NH3 (liquid); High Pressure; react. of semi ammoniate and KNH2 (molar ratio 1:12), 130°C, 110 bar, 5d; |
Conditions | Yield |
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In water hydrolysis;; | |
In water hydrolysis;; |
hexaaminocyclotriphosphazene
Conditions | Yield |
---|---|
In neat (no solvent) heating in vac. at 380°C for 100 h;; | >99 |
In neat (no solvent) heating for a longer period of time;; | |
In neat (no solvent) heating in vac. at 220°C for several days;; | >99 |
Conditions | Yield |
---|---|
In neat (no solvent) evolution of NH3 on air starting at 125 °C;; | |
In neat (no solvent) heating; decompn. rate depending on material of the vessel;; | |
In neat (no solvent) evolution of NH3 on air starting at 125 °C;; | |
In neat (no solvent) heating in vacuum at 380 °C for 100 h; evolution of NH3 starting in vacuum at 40 °C; evolution of a large amount of NH3 at 200-300 °C; no evolution of NH3 at 400-450 °C;; |
hexaaminocyclotriphosphazene
phosphoric acid
Conditions | Yield |
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With HNO3 or acetic acid; H2O In water hydrolysis with acetic acid or diluted HNO3;; | |
With H2O In water hydrolysis in the heat;; |