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| CAS No.: | 13597-99-4 |
|---|---|
| Name: | BERYLLIUM NITRATE |
| Molecular Structure: | |
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| Formula: | Be. 2 H N O3 |
| Molecular Weight: | 133.03 |
| Synonyms: | Berylliumnitrate (6CI); Nitric acid, beryllium salt (8CI,9CI); Beryllium dinitrate;Beryllium nitrate (Be(NO3)2) |
| Density: | g/cm3 |
| Melting Point: | 60oC |
| Boiling Point: | 83°Cat760mmHg |
| Flash Point: | °C |
| Solubility: | g Ba(NO3)2/100g H2O: 97 (0°C), 108 (20°C), 178 (60°C); soluble alcohol [LAN05] [HAW93] |
| Hazard Symbols: | Very toxic. Oxidizing material, dangerous fire risk. |
| Risk Codes: | 49-23-36/38-43-48/23-36/37/38-20-34-26-21/22-8-61-45 |
| Safety: | Confirmed carcinogen. Poison by intraperitoneal, intravenous, and subcutaneous routes. Experimental reproductive effects. When heated to decomposition it emits very toxic fumes of BeO and NOx. See also BERYLLIUM COMPOUNDS and NITRATES. |
| PSA: | 137.76000 |
| LogP: | 0.56820 |
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Chemistry
Molecular Formula: BeN2O6
Molar mass: 133.02 g/mol
EINECS: 237-062-5
Density: 1.02 g/mL at 20 °C
Boiling Point: 83 °C at 760 mmHg
Vapour Pressure: 49.8 mmHg at 25°C
Product categories of Beryllium nitrate (13597-99-4): Beryllium;Synthetic Reagents;Inorganic Salts
Structure of Beryllium nitrate (13597-99-4):
H-Bond Donor: 0
H-Bond Acceptor: 6
IUPAC Name: Beryllium dinitrate
Canonical SMILES: [Be+2].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-]
InChI: InChI=1S/Be.2NO3/c;2*2-1(3)4/q+2;2*-1
InChIKey: RFVVBBUVWAIIBT-UHFFFAOYSA-N
Toxicity Data With Reference
| 1. | ivn-mus LD50:3160 µg/kg | CUSCAM Current Science. 55 (1986),899. | ||
| 2. | ipr-mus LD50:500 µg/kg | EQSSDX Environmental Quality and Safety, Supplement. 1 (1975),1. | ||
| 3. | scu-mus LDLo:50 mg/kg | RDWU** Beitrage zur Pharmakologie des Berylliums, Ursula Richter Dissertation .(Pharmakologischen Institut der Universitat Wurzburg,Germany.: 1930). | ||
| 4. | ipr-gpg LDLo:100 mg/kg | EQSSDX Environmental Quality and Safety, Supplement. 1 (1975),1. | ||
| 5. | scu-frg LDLo:1041 mg/kg | RDWU** Beitrage zur Pharmakologie des Berylliums, Ursula Richter Dissertation .(Pharmakologischen Institut der Universitat Wurzburg,Germany.: 1930). |
Consensus Reports
IARC Cancer Review: Group 1 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 58 (1993),p. 41.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 58 (1993),p. 41.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 1 (1972),p. 17.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 23 (1980),p. 143.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 58 (1993),p. 41.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Beryllium and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.
Safety Profile
Confirmed carcinogen. Poison by intraperitoneal, intravenous, and subcutaneous routes. Experimental reproductive effects. When heated to decomposition it emits very toxic fumes of BeO and NOx. See also BERYLLIUM COMPOUNDS and NITRATES.
Hazard Codes: T.gif){kind=small}
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Risk Statements:
8: Contact with combustible material may cause fire
20: Harmful by inhalation
21: Harmful in contact with skin
22: Harmful if swallowed
23: Toxic by inhalation
34: Causes burns
36: Irritating to the eyes
37: Irritating to the respiratory system
38: Irritating to the skin
45: May cause cancer
48: Danger of serious damage to health by prolonged exposure
49: May cause cancer by inhalation
Safety Statements:
17: Keep away from combustible material
23: Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
28A After contact with skin, wash immediately with plenty of water.
36: Wear suitable protective clothing
37: Wear suitable gloves
39: Wear eye/face protection
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
53: Avoid exposure - obtain special instruction before use
Standards and Recommendations
OSHA PEL: TWA 0.002 mg(Be)/m3; STEL 0.005 mg(Be)/m3/30M; CL 0.025 mg(Be)/m3
ACGIH TLV: TWA 0.002 mg(Be)/m3; Confirmed Human Carcinogen; (Proposed: TWA 0.0002 mg(Be)/m3 (sensitizer); Confirmed Human Carcinogen)
NIOSH REL: CL not to exceed 0.0005 mg(Be)/m3
DOT Classification: 5.1; Label: Oxidizer, Poison
Specification
Beryllium nitrate (13597-99-4) is a polycyclic aromatic hydrocarbon, and also can be called Beryllium dinitrate ; Beryllium nitrate solution and Nitric acid, beryllium salt .