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13686-66-3

Basic Information
CAS No.: 13686-66-3
Name: DIMETHYLSILYLDIETHYLAMINE
Article Data: 3
Molecular Structure:
Molecular Structure of 13686-66-3 (DIMETHYLSILYLDIETHYLAMINE)
Formula: C6H17NSi
Molecular Weight: 131.293
Synonyms: Silylamine,N,N-diethyl-1,1-dimethyl- (8CI);Dimethylsilyldiethylamine;N,N-Diethyl-1,1-dimethylsilanamine;
EINECS: 237-202-5
Density: 0.8
Boiling Point: 117 °C at 760 mmHg
Flash Point: 24.6 °C
Hazard Symbols: FlammableF,IrritantXi
Risk Codes: 11-36/37/38
Safety: 16-23-26-36
PSA: 3.24000
LogP: 1.31160
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Specification

The Silanamine,N,N-diethyl-1,1-dimethyl- is an organic compound with the formula C6H17NSi. The systematic name of this chemical is N,N-diethyl-1,1-dimethylsilanamine. With the CAS registry number 13686-66-3, it is also named as Dimethylsilyldiethylamine. The product's categories are Organometallic Reagents; Organosilicon; Others. Besides, it should be stored in a closed cool and well-ventilated place.

Physical properties about Silanamine,N,N-diethyl-1,1-dimethyl- are: (1)ACD/LogP: 2.60; (2)ACD/LogD (pH 5.5): -0.37; (3)ACD/LogD (pH 7.4): 0.95; (4)ACD/BCF (pH 5.5): 1; (5)ACD/BCF (pH 7.4): 1.26; (6)ACD/KOC (pH 5.5): 1; (7)ACD/KOC (pH 7.4): 13.99; (8)#H bond acceptors: 1; (9)#Freely Rotating Bonds: 3; (10)Polar Surface Area: 3.24 Å2; (11)Flash Point: 24.6 °C; (12)Enthalpy of Vaporization: 35.53 kJ/mol; (13)Boiling Point: 117 °C at 760 mmHg; (14)Vapour Pressure: 17.7 mmHg at 25°C.

Preparation: this chemical can be prepared by chlorodiethylaminodimethylsilane. This reaction will need reagent LiAlH4 and solvent diethyl ether. The reaction time is 2.5 hours by heating. The yield is about 80%.

Uses of Silanamine,N,N-diethyl-1,1-dimethyl-: it can be used to produce diethyl-(4-chloro-benzyl)-amine at temperature of 20 °C. It will need reagent TiCl4 and solvent CH2Cl2 with reaction time of 36 hours. The yield is about 78%.

When you are using this chemical, please be cautious about it as the following:
It is highly flammable. Please keep away from sources of ignition - No smoking. Besides, this chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable protective clothing and do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer). In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: N(CC)(CC)[SiH](C)C
(2)InChI: InChI=1/C6H17NSi/c1-5-7(6-2)8(3)4/h8H,5-6H2,1-4H3
(3)InChIKey: KYIHWAKEVGKFOA-UHFFFAOYAO
(4)Std. InChI: InChI=1S/C6H17NSi/c1-5-7(6-2)8(3)4/h8H,5-6H2,1-4H3
(5)Std. InChIKey: KYIHWAKEVGKFOA-UHFFFAOYSA-N