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CAS No.: | 137-05-3 | |
---|---|---|
Name: | CYANOACRYLIC ACID METHYL ESTER | |
Molecular Structure: | ||
Formula: | C5H5 N O2 | |
Molecular Weight: | 111.1 | |
Synonyms: | Acrylicacid, 2-cyano-, methyl ester (6CI,8CI); 2-Cyanoacrylic acid methyl ester;ADhere; CA 7; CA 7 (adhesive); Cemedine 3000; Cemedine 3000 Type-II; Cemedine3000DX; Cyanobond 5000; Cyanobond SS; Eastman 910; Eastman 910 Super Glue;Fimofix P 1048; Mecrilat; Mecrilate; Mecrylate; Methyl 2-cyanoacrylate; Methylcyanoacrylate; Methyl a-cyanoacrylate; Sicomet 7000; Three Bond 1701; a-Cyanoacrylic acid methyl ester | |
Density: | 1.08g/cm3 | |
Melting Point: | -40 °C | |
Boiling Point: | 174.5°Cat760mmHg | |
Flash Point: | 67.6°C | |
Hazard Symbols: | Toxic by inhalation. TLV: TWA 2 ppm; STEL 4 ppm. | |
Risk Codes: | 36/37/38 | |
Safety: | Moderately toxic by ingestion and inhalation routes. Experimental reproductive effects. A human eye irritant. Can bond the eyelids or skin surfaces instantly. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx and CN−. | |
Analytical Methods: | For occupational chemical analysis use OSHA: #ID-55. |
|
PSA: | 50.09000 | |
LogP: | 0.23918 |
2-acetoxy-2-cyano-propionic acid methyl ester
mecrilate
Conditions | Yield |
---|---|
With copper at 535 - 550℃; under 200 Torr; Entsteht in polymerer Form; |
Conditions | Yield |
---|---|
With piperidine at 80℃; Destillieren des Reaktionsprodukts bei 150grad und 1mm Druck; | |
With piperidine; methanol Erhitzen des Reaktionsprodukts mit Phosphor(V)-oxid, Schwefeldioxid und Hydrochinon unter vermindertem Druck; |
Conditions | Yield |
---|---|
With sodium methylate at 35℃; Destillieren des Reaktionsprodukts bei 150grad und 1mm Druck; |
mecrilate
(3R,5R,7R)-1-(buta-1,3-dien-2-yl)adamantane
Conditions | Yield |
---|---|
In benzene for 2h; Ambient temperature; | 90% |
isobutyl vinyl ether
mecrilate
2-isobutoxy-5-cyano-6-methoxy-3,4-dihydro-2H-pyran
Conditions | Yield |
---|---|
In benzene at 28℃; for 72h; | 87% |
at 28℃; for 72h; Product distribution; Mechanism; var. temp., time, other solvent; var. electron-rich olefins; | 86% |
In benzene at 25℃; | 62% |
trimethyl((1-(thiophen-2-yl)vinyl)oxy)silane
mecrilate
Conditions | Yield |
---|---|
In benzene at 25℃; for 3h; | 81% |
mecrilate
2-methylcyclohexa-1,3-diene
2-cyano-2-methoxycarbonyl-5-methylbicyclo<2.2.2>oct-5-ene
Conditions | Yield |
---|---|
In benzene Heating; | 75% |
In benzene Heating; |
mecrilate
5′-(4-(diphenylamino)phenyl)(2,2′-bithiophene)-5-carboxaldehyde
Conditions | Yield |
---|---|
With piperidine In dichloromethane; acetonitrile at 20℃; for 1h; Inert atmosphere; | 71% |
mecrilate
Conditions | Yield |
---|---|
With dimethylaluminum chloride In n-heptane; dichloromethane at 0℃; for 1h; | 64% |
Conditions | Yield |
---|---|
In diethyl ether at 20℃; for 48h; | 63% |
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Methyl 2-cyanoacrylate(137-05-3)'s molecular formula is C9H13NO2 and its formula weight is 111.1.
The relative density of methyl 2-cyanoacrylate(137-05-3) is 1.1044(27/4°C) and it has a boiling point of 47-48°C(0.267kPa). The refractive index is about 1.443 (25 °C).
Methyl 2-cyanoacrylate(137-05-3) has the property of being dissolved in ether, chloroform, a chlorinated carbon, benzene, dioxane. It is not soluble in methanol and ethanol, and it gradually aggregated when exposed to air.
The molecular structure of methyl 2-cyanoacrylate(137-05-3):
1. | eye-hmn TD50:4 ppm | AIHAAP American Industrial Hygiene Association Journal. 29 (1968),558. | ||
2. | mmo-sat 100 µg/plate | ENMUDM Environmental Mutagenesis. 9 (Suppl 9)(1987),1. | ||
3. | mmo-sat 300 µg/plate | MUREAV Mutation Research. 188 (1987),97. | ||
4. | orl-rat LD50:1600 mg/kg | 85INA8 Documentation of the Threshold Limit Values and Biological Exposure Indices. 6 (1991),965. | ||
5. | ihl-rat LC50:101 ppm/6H | 85INA8 Documentation of the Threshold Limit Values and Biological Exposure Indices. 6 (1991),965. |
Analytical Methods:
For occupational chemical analysis use OSHA: #ID-55.