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13752-51-7

Basic Information
CAS No.: 13752-51-7
Name: 4-[(4-Morpholinylthio)thioxomethyl]-morpholine
Article Data: 5
Molecular Structure:
Molecular Structure of 13752-51-7 (4-[(4-Morpholinylthio)thioxomethyl]-morpholine)
Formula: C9H16N2O2S2
Molecular Weight: 248.37
Synonyms: Morpholine,4-[(4-morpholinylthio)thioxomethyl]- (9CI);Morpholine,4-[(morpholinothiocarbonyl)thio]- (8CI);4-[(Morpholinothio)thiocarbonyl]morpholine;Accelerator OTOS;Cure-rite 18;Curite 18;N,N:N',N'-Bis(oxydiethylene)thiocarbamoylsulfenamide;N,N'-Bis(oxydiethylene)thiocarbamoylsulfenamide;N,N'-[(Thiocarbonyl)thio]dimorpholine;N-Oxydiethylene thiocarbamyl-N-oxydiethylenesulfenamide;N-Oxydiethylenethiocarbamoyl-N'-oxydiethylenesulfenamide;OTOS;
EINECS: 237-335-9
Density: 1.34 g/cm3
Melting Point: 139 °C
Boiling Point: 378.1 °C at 760 mmHg
Flash Point: 182.4 °C
Solubility: 127mg/L at 20℃
PSA: 82.33000
LogP: 0.45970
Synthetic route
110-91-8

morpholine

72087-88-8

acetyl-trichloromethyl-disulfane

13752-51-7

4-(morpholine-4-carbothioylsulfanyl)-morpholine

Conditions
ConditionsYield
In diethyl ether Mechanism; further α-chloroalkyd disulfides, <18 deg C;32%
In diethyl ether <18 deg C;22%
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Reported in EPA TSCA Inventory.

Specification

 

The N-Oxydiethylenethiocarbamoyl-N-oxydiethylene sulfenamide is an organic compound with the formula C9H16N2O2S2. The IUPAC name of this chemical is morpholin-4-yl morpholine-4-carbodithioate. With the CAS registry number 13752-51-7, it is also named as 4-[(morpholin-4-ylcarbonothioyl)sulfanyl]morpholine. The product's classification codes are Mutation data; Reproductive Effect.

Physical properties about N-Oxydiethylenethiocarbamoyl-N-oxydiethylene sulfenamide are: (1)ACD/LogP: -0.90; (2)ACD/LogD (pH 5.5): -0.9; (3)ACD/LogD (pH 7.4): -0.9; (4)ACD/BCF (pH 5.5): 1; (5) ACD/BCF (pH 7.4): 1; (6)ACD/KOC (pH 5.5): 7.69; (7)ACD/KOC (pH 7.4): 7.69; (8)#H bond acceptors: 4; (9)#H bond donors: 0; (10)#Freely Rotating Bonds: 2; (11)Polar Surface Area: 82.33 Å2; (12)Index of Refraction: 1.631; (13)Molar Refractivity: 66 cm3; (14)Molar Volume: 185 cm3; (15)Polarizability: 26.16×10-24cm3; (16)Surface Tension: 64.1 dyne/cm; (17)Density: 1.34 g/cm3; (18)Flash Point: 182.4 °C; (19)Enthalpy of Vaporization: 62.59 kJ/mol; (20)Boiling Point: 378.1 °C at 760 mmHg; (21)Vapour Pressure: 6.45E-06 mmHg at 25°C.

Preparation: this chemical can be prepared by morpholine and acetyl-trichloromethyl-disulfane. This reaction will need solvent diethyl ether. The reaction temperature is <18 °C. The yield is about 22%.

You can still convert the following datas into molecular structure:
(1)SMILES: S=C(SN1CCOCC1)N2CCOCC2
(2)InChI: InChI=1/C9H16N2O2S2/c14-9(10-1-5-12-6-2-10)15-11-3-7-13-8-4-11/h1-8H2
(3)InChIKey: HOEFWOBLOGZQIQ-UHFFFAOYAQ
(4)Std. InChI: InChI=1S/C9H16N2O2S2/c14-9(10-1-5-12-6-2-10)15-11-3-7-13-8-4-11/h1-8H2
(5)Std. InChIKey: HOEFWOBLOGZQIQ-UHFFFAOYSA-N