CAS No.13756-42-8,Benzoic acid,4-methyl-, 1,1-dimethylethyl ester Suppliers

Detail of "13756-42-8"

CAS Number:

13756-42-8

Name:

Superlist Name:

Molecular Structure:

Formula:

C₁₂H₁₆O₂

Molecular Weight:

192.26

Synonyms:

p-Toluicacid, tert-butyl ester (8CI);4-Methylbenzoic acid tert-butyl ester;tert-Butyl p-methylbenzoate;tert-Butyl p-toluate;

Density:

0.995 g/cm³

Boiling Point:

256.231 °C at 760 mmHg

Flash Point:

112.237 °C

Decomposition of benzoate ester radical anions: Decomposition of benzoate ester radical anions. Wagenknecht, John H.; Goodin, Richard D.; Kinlen, Patrick J.; Woodard, F. E. (Corp. Res. Lab., Monsanto Co., St. Louis, MO 63167, USA). J. Electrochem. Soc., 131(7), 1559-65 (English) 1984. CODEN: JESOAN. ISSN: 0013-4651. DOCUMENT TYPE: Journal CA Section: 72 (Electrochemistry) Section cross-reference(s): 22, 25 The electrochem. redn. of benzoate esters in aprotic media leads to relatively stable radical anions. The radical anions decomp. to electroinactive products in an initial EC mechanism. At long-time scales and/or higher concns., the benzoate esters begin to exhibit more complicated mechanistic behavior. The initial rates of decompn. of several benzoate ester radical anions were detd. by digital simulations of cyclic voltammograms, double potential step expts. and rotating ring-disk techniques. On short-time scales, the redn. of tert-Bu p-toluate [13756-42-8] is a good example of pure EC mechanistic behavior. The final decompn. products are many and complex for most of the esters studied, but tert-Bu benzoate [774-65-2] cleanly gives benzoate anion [766-76-7] and tert-Bu p-tert-/butylbenzoate [92279-83-9].

Detail of "13756-42-8"