Products Categories
CAS No.: | 138-24-9 |
---|---|
Name: | Trimethylphenylammonium chloride |
Article Data: | 6 |
Molecular Structure: | |
Formula: | C9H14N.Cl |
Molecular Weight: | 171.67 |
Synonyms: | Ammonium,trimethylphenyl-, chloride (8CI);Benzenaminium, N,N,N-trimethyl-, chloride(9CI);Trimethylphenylammonium chloride (6CI,7CI);Ammonyx 200;N,N,N-Trimethylanilinium chloride;Trimethylanilinium chloride; |
EINECS: | 205-319-0 |
Density: | 1.0683 (rough estimate) |
Melting Point: | 246-248 °C (dec.)(lit.) |
Boiling Point: | 283.2°C (rough estimate) |
Solubility: | soluble in water |
Appearance: | White or greyish-blue crystalline powder |
Hazard Symbols: | T |
Risk Codes: | 24/25 |
Safety: | 53-25-39-45 |
Transport Information: | UN 2811 6.1/PG 3 |
PSA: | 0.00000 |
LogP: | -1.11270 |
bis(chloromethyl)mercury
N,N-dimethyl-aniline
A
phenyltrimethylammonium chloride
B
4,4'-methylene-bis(N,N-dimethylaniline)
Conditions | Yield |
---|---|
In dibutyl ether at 100℃; for 48h; | A n/a B 96% |
Conditions | Yield |
---|---|
With silver(I) chloride |
Conditions | Yield |
---|---|
trichlorophosphate |
phenyltrimethylammonium chloride
Conditions | Yield |
---|---|
With pyrene In acetonitrile Irradiation; CIDNP effects of the photochemical dediazonation; reaction in the absence of pyrene in dioxane; |
A
phenyltrimethylammonium chloride
B
Trp-Aib-Gly-Leu-NHPh
Conditions | Yield |
---|---|
In chloroform-d1 at 24.84℃; Equilibrium constant; complex formation; |
A
phenyltrimethylammonium chloride
B
Trp-Aib-Gly-Leu-NH-C6H3(3,5-Me2)
Conditions | Yield |
---|---|
In chloroform-d1 at 24.84℃; Equilibrium constant; complex formation; |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 42 percent / tetrahydrofuran / 36 h / 20 °C 2: dibutyl ether / 48 h / 100 °C View Scheme |
aniline
methyl trifluoromethanesulfonate
A
N-methylaniline hydrochloride
B
phenyltrimethylammonium chloride
C
aniline hydrochloride
D
N,N-dimethylaniline hydrochloride
Conditions | Yield |
---|---|
Stage #1: aniline; methyl trifluoromethanesulfonate With 1,1,1,3',3',3'-hexafluoro-propanol In d(4)-methanol at 20℃; for 1h; Stage #2: With hydrogenchloride In water for 1h; |
Conditions | Yield |
---|---|
Stage #1: phenyltrimethylammonium chloride; MORPHIN With potassium phosphate In acetone at 50 - 60℃; for 25h; Heating / reflux; Stage #2: With phosphoric acid In water; acetone at 20℃; for 0.5h; Product distribution / selectivity; | 100% |
Stage #1: phenyltrimethylammonium chloride; MORPHIN With potassium hydrogencarbonate In toluene at 50 - 115℃; for 8 - 28h; Heating / reflux; Stage #2: With phosphoric acid In ethanol; water; toluene at 20℃; for 0.5h; Product distribution / selectivity; | 90% |
Stage #1: phenyltrimethylammonium chloride; MORPHIN With potassium phosphate In toluene at 70 - 115℃; for 2h; Heating / reflux; Stage #2: With phosphoric acid In ethanol; water; toluene at 20 - 30℃; for 0.75h; Product distribution / selectivity; | 82% |
phenyltrimethylammonium chloride
codeine phosphate
Conditions | Yield |
---|---|
Stage #1: morphine; phenyltrimethylammonium chloride With potassium hydrogencarbonate In toluene at 50 - 115℃; for 29h; Heating / reflux; Stage #2: In toluene at 20℃; activated carbon (charcoal); Stage #3: With phosphoric acid In ethanol; water at 20℃; for 0.5h; | 99.6% |
Stage #1: morphine; phenyltrimethylammonium chloride With potassium hydrogencarbonate In toluene at 50 - 115℃; for 9h; Heating / reflux; Stage #2: In toluene at 20℃; activated carbon (charcoal); Stage #3: With phosphoric acid In ethanol; water at 20℃; for 0.5h; | 99.8% |
What can I do for you?
Get Best Price
IUPAC Name: Benzenaminium, N,N,N-trimethyl-, chloride
The MF of Benzenaminium, N,N,N-trimethyl-, chloride (138-24-9) is C9H14ClN.
The MW of Benzenaminium, N,N,N-trimethyl-, chloride (138-24-9) is 171.67.
Synonyms of Benzenaminium, N,N,N-trimethyl-, chloride (138-24-9): Ammonium, phenyltrimethyl-, chloride ; Benzenaminium, N,N,N-trimethyl-, chloride ; N,N,N-Trimethylanilinium chloride ; N,N,N-Trimethylbenzenaminium chloride ; Phenyltrimethylammonium chloride
Product Categories: Ammonium Chlorides (Quaternary);Quaternary Ammonium Compounds
Form: White or greyish-bleu crystalline powder
Melting Point: 246-248 °C (dec.)(lit.)
Water Solubility: soluble
Sensitive: Hygroscopic
EINECS: 205-319-0
BRN: 3572527
Benzenaminium, N,N,N-trimethyl-, chloride (138-24-9) is used as pharmaceutical Intermediates.
1. | orl-mus LDLo:200 mg/kg | JPETAB Journal of Pharmacology and Experimental Therapeutics. 43 (1931),413. | ||
2. | ivn-mus LDLo:15 mg/kg | JPETAB Journal of Pharmacology and Experimental Therapeutics. 43 (1931),413. |
Reported in EPA TSCA Inventory.
Poison by ingestion and intravenous routes. When heated to decomposition it emits very toxic fumes of NOx, NH3, and Cl−.
Safety information of Benzenaminium, N,N,N-trimethyl-, chloride (138-24-9):
Hazard Codes T
Risk Statements
24/25 Toxic in contact with skin and if swallowed
Safety Statements
53 Avoid exposure - obtain special instruction before use
25 Avoid contact with eyes
39 Wear eye/face protection
45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
RIDADR UN 2811 6.1/PG 3
WGK Germany 1
RTECS BT2190000
HazardClass 6.1
PackingGroup III
HS Code 29239000