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CAS No.: | 13818-44-5 |
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Name: | 2-Propenoic acid, 2-methyl-, (2-oxo-1,3-dioxolan-4-yl)methyl ester |
Article Data: | 70 |
Molecular Structure: | |
Formula: | C8H10O5 |
Molecular Weight: | 186.164 |
Synonyms: | 2-methyl-acrylic acid 2-oxo-[1,3]dioxolan-4-ylmethyl ester;(2-oxo-1,3-dioxolane-4-yl)methylmethacrylate;1-methacrylate-2,3-propylene carbonate;2-Propenoic acid,2-methyl-,(2-oxo-1,3-dioxolan-4-yl)methyl ester;4-(methacryloyloxymethyl)-1,3-dioxolan-2-one; |
Density: | 1.219g/cm3 |
Boiling Point: | 337.576oC at 760 mmHg |
Flash Point: | 152.15oC |
PSA: | 61.83000 |
LogP: | 0.64110 |
carbon dioxide
2,3-Epoxypropyl methacrylate
(2-oxo-1,3-dioxolane-4-yl)methyl methacrylate
Conditions | Yield |
---|---|
With 1-methyl-1-N-propylpyrrolidinium bromide; triflate salt of a tricarbonyl rhenium(I) bipyridine complex at 80℃; under 11251.1 Torr; for 1h; | 99% |
With methyl-triphenylphosphonium iodide at 25℃; under 760.051 Torr; for 36h; Time; | 99% |
With tri-n-butyl-(2-hydroxyethyl)phosphonium iodide In neat (no solvent) at 90℃; under 7500.75 Torr; for 3h; | 99% |
4-hydroxymethyl-1,3-dioxolan-2-one
methacrylic acid methyl ester
(2-oxo-1,3-dioxolane-4-yl)methyl methacrylate
Conditions | Yield |
---|---|
Stage #1: methacrylic acid methyl ester With zirconium(IV) acetylacetonate; water; 4-methoxy-phenol Reflux; Large scale; Stage #2: 4-hydroxymethyl-1,3-dioxolan-2-one at 70 - 105℃; Large scale; | 90.1% |
With TEMPOL; zirconium(IV) acetylacetonate Product distribution / selectivity; Heating / reflux; | 80.6% |
With TEMPOL; lithium hydroxide; calcium oxide Product distribution / selectivity; Heating / reflux; | 79.6% |
4-hydroxymethyl-1,3-dioxolan-2-one
poly(methacrylic acid)
(2-oxo-1,3-dioxolane-4-yl)methyl methacrylate
Conditions | Yield |
---|---|
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 20℃; for 3h; Cooling with ice; | 67% |
Stage #1: 4-hydroxymethyl-1,3-dioxolan-2-one With dmap; dicyclohexyl-carbodiimide In dichloromethane for 0.5h; Cooling with ice; Stage #2: poly(methacrylic acid) In dichloromethane at 20℃; Cooling with ice; | 67% |
4-hydroxymethyl-1,3-dioxolan-2-one
Methacryloyl chloride
(2-oxo-1,3-dioxolane-4-yl)methyl methacrylate
Conditions | Yield |
---|---|
With triethylamine In dichloromethane |
(2-oxo-1,3-dioxolan-4-yl)methyl acetate
methacrylic acid methyl ester
A
acetic acid methyl ester
B
(2-oxo-1,3-dioxolane-4-yl)methyl methacrylate
Conditions | Yield |
---|---|
sodium methylate at 75 - 110℃; Product distribution / selectivity; |
(2-oxo-1,3-dioxolane-4-yl)methyl methacrylate
N-phenyl-N-(3-trimethoxysilylpropyl)amine
Conditions | Yield |
---|---|
at 20℃; | 100% |
(2-oxo-1,3-dioxolane-4-yl)methyl methacrylate
(2-oxo-1,3-dioxolan-4-yl)methyl isobutyrate
Conditions | Yield |
---|---|
With 1,2,2,3,4,4-hexamethylphosphetane 1-oxide; phenylsilane; water In toluene at 80℃; for 24h; Schlenk technique; Inert atmosphere; | 93% |
(2-oxo-1,3-dioxolane-4-yl)methyl methacrylate
2,3-Epoxypropyl methacrylate
Conditions | Yield |
---|---|
1-methyl-3-(n-butyl)imidazolium iodide Product distribution / selectivity; | 8.6% |
(2-oxo-1,3-dioxolane-4-yl)methyl methacrylate
Conditions | Yield |
---|---|
With methanesulfonic acid; 2,2-dimethoxy-2-phenylacetophenone at 25℃; for 0.0833333h; UV-irradiation; |
(2-oxo-1,3-dioxolane-4-yl)methyl methacrylate
1-amino-2-propene
C11H17NO5
Conditions | Yield |
---|---|
at 20 - 66℃; for 168h; |