CAS No.13859-65-9,TETRAKIS(TRIFLUOROPHOSPHINE)NICKEL (0) Suppliers

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Basic Information

CAS No.:

13859-65-9

Name:

TETRAKIS(TRIFLUOROPHOSPHINE)NICKEL (0)

Article Data:

Molecular Structure:

Formula:

F12Ni P4

Molecular Weight:

410.566

Synonyms:

Nickel,tetrakis(phosphorous trifluoride)-, (T-4)-; Nickel, tetrakis(phosphorustrifluoride)- (6CI,7CI,8CI); Phosphorous trifluoride, nickel complex;Phosphorous trifluoride, nickel deriv.; Tetrakis(trifluorophosphine)nickel

Density:

g/cm³

Boiling Point:

°Cat760mmHg

Flash Point:

°C

Risk Codes:

11-23/24/25

Safety:

Risk Statements	11-23/24/25
Safety Statements	16-36/37/39

PSA:

54.36000

LogP:

8.48720

Synthetic route

: bis(η3-allyl)nickel(II)

: 7783-55-3
trifluorophosphane

: 13859-65-9
tetrakis(trifluorophosphine)nickel

Conditions

Conditions	Yield
In neat (no solvent) 29% excess PF3 condensed onto Ni(allyl)2 and reagents allowed to react at 25°C for 1.5 h; react. mixt. fractionated, Ni(PF3)4 recovered in -80°C trap;	58%

: 13463-39-3, 71564-36-8
tetracarbonyl nickel

: 7783-55-3
trifluorophosphane

: 13859-65-9
tetrakis(trifluorophosphine)nickel

Conditions

Conditions	Yield
In neat (no solvent)
In neat (no solvent)
In neat (no solvent) High Pressure; react. of (Ni(CO)4) with PF3 at 150 °C under pressure;;
In neat (no solvent) High Pressure; react. of (Ni(CO)4) with PF3 at 150 °C under pressure;;
In melt passing PF3 into liq. (Ni(CO)4) for a longer period of time (carefully raising temp. to 71 °C);;	>99

: 13463-39-3, 71564-36-8
tetracarbonyl nickel

: 7783-55-3
trifluorophosphane

A: 13859-65-9
tetrakis(trifluorophosphine)nickel

B: 14219-40-0
NiCO(PF3)3

C: 14264-32-5
Ni(trifluorophosphine)(CO)3

D: 13859-78-4
Ni(CO)2(PF3)2

Conditions

Conditions	Yield
In neat (no solvent) at higher temp.;;
In neat (no solvent) at higher temp.;;
In neat (no solvent) at 0 - 71°C;;

...Expand

: 1271-28-9
nickelocene

: 13859-65-9
tetrakis(trifluorophosphine)nickel

Conditions

Conditions	Yield
With trifluorophosphane 100°C/30 at;
With trifluorophosphane 60°C/5 d; closed tube;
With PF3 100°C/30 at;
With PF3 60°C/5 d; closed tube;

: 7440-02-0
nickel

: 13859-65-9
tetrakis(trifluorophosphine)nickel

Conditions

Conditions	Yield
With PF3 In methyl cyclohexane absence of air and moisture; condensing Ni-vapour into methylcyclohexanecontg. excess of PF3 and cycloheptatriene (-130°C); IR and mass spectroscopy;

: 7440-02-0
nickel

: 7783-55-3
trifluorophosphane

: 13859-65-9
tetrakis(trifluorophosphine)nickel

Conditions

Conditions	Yield
In neat (no solvent) High Pressure; treating Ni-powder (prepd. by thermal decompn. of Ni-oxalate in N2- or H2-stream) in rotary autoclave (Cu-impeller) with PF3 (350 atm) for 42 h at 100 °C;; distilling off PF3 at -100 °C, further react. with PF3 for 16 h at 100 °C and 180 atm;;
In neat (no solvent) treating Ni (prepd. by decompn. of (Ni(CO)4)) at 100 °C for several weeks with PF3;;
In neat (no solvent) treating Ni (prepd. by decompn. of (Ni(CO)4)) at 100 °C for several weeks with PF3;;
In neat (no solvent) High Pressure; treating Ni-powder (prepd. by thermal decompn. of Ni-oxalate in N2- or H2-stream) in rotary autoclave (Cu-impeller) with PF3 (350 atm) for 42 h at 100 °C;; distilling off PF3 at -100 °C, further react. with PF3 for 16 h at 100 °C and 180 atm;;

: 14219-40-0
NiCO(PF3)3

: 7783-55-3
trifluorophosphane

: 13859-65-9
tetrakis(trifluorophosphine)nickel

Conditions

Conditions	Yield
In neat (no solvent) react. with PF3 above 70 °C;;

: 36421-86-0
tetrakis(phosphorustrichloride)nickel(0)

: 7783-55-3
trifluorophosphane

: 13859-65-9
tetrakis(trifluorophosphine)nickel

Conditions

Conditions	Yield
In neat (no solvent) byproducts: PCl3; heating (Ni(PCl3)4) with excess of PF3 in closed tube for 24 h on steam bath, cooling react. tube with liq. N2 after the react. is finished and distilling off PF3 at -115 °C (vac.), raising temp. to 0 °C;; sepg. upper layer of PCl3 from (Ni(PF3)4), fractional distillation in high vac. with addn. of SbF3 and traces of SbF5;;

: 36421-86-0
tetrakis(phosphorustrichloride)nickel(0)

: 7783-55-3
trifluorophosphane

A: 13859-65-9
tetrakis(trifluorophosphine)nickel

B: 7719-12-2, 52843-90-0
phosphorus trichloride

Conditions

Conditions	Yield
In neat (no solvent) react. at >100°C and 50-100 atm in a pressure pipe;;
In neat (no solvent) react. at >100°C and 50-100 atm in a pressure pipe;;

...Expand

: 15689-05-1
tetrakis(tribromophosphine)nickel(0)

: 7783-55-3
trifluorophosphane

: 13859-65-9
tetrakis(trifluorophosphine)nickel

Conditions

Conditions	Yield
In neat (no solvent) react. at >100°C and 50-100 atm in a pressure pipe;;
In neat (no solvent) react. at >100°C and 50-100 atm in a pressure pipe;;
In neat (no solvent) byproducts: PBr3; heating (Ni(PBr3)4) with excess of PF3 in closed tube for 24 h on steam bath, cooling react. tube with liq. N2 after the react. is finished and distilling off PF3 at -115 °C (vac.), raising temp. to 0 °C;; sepg. upper layer of PBr3 from (Ni(PF3)4), fractional distillation in high vac. with addn. of SbF3 and traces of SbF5;;

Downstream Products

7440-02-0