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13863-41-7

Basic Information
CAS No.: 13863-41-7
Name: Bromine chloride
Article Data: 99
Molecular Structure:
Molecular Structure of 13863-41-7 (Bromine chloride)
Formula: BrCl
Molecular Weight: 115.357
Synonyms: Brominechloride; Bromine monochloride; Bromochloride
Density: 2.172g/cm3
Melting Point: -66℃ [HAW93]
Boiling Point: °Cat760mmHg
Flash Point: °C
Solubility: soluble H2O with ready hydrolysis, soluble carbon disulfide, ether [HAW93]
Appearance: colourless liquid with a fruity odour
Hazard Symbols: F,Xi
Risk Codes: R11; R36/37/38
Safety:
RIDADR 2901
HazardClass 2.3
PSA: 0.00000
LogP: 1.53510
Synthetic route
Conditions
ConditionsYield
Kinetics; HOBr/He mixt. (by He bubbling through aq. HOBr soln. at 10-15°C) and Cl excess flowing into quartz flow tube reactor at 300 K and 2.5-3.03 mbar; mass spectrometric monitoring;A 98%
B 98%
65597-24-2

Chlorine(I) trifluoromethanesulfonate

13997-93-8

bromine(I) fluorosulfate

A

926-08-9

trifluoromethyl fluorosulfate

B

21595-44-8

trifluoromethyldisulfurylfluoride

C

13863-41-7

bromine chloride

Conditions
ConditionsYield
byproducts: Br2, Cl2; at room temp. for 12 h;A n/a
B 85%
C n/a
7726-95-6

bromine

7782-50-5

chlorine

13863-41-7

bromine chloride

Conditions
ConditionsYield
In neat (no solvent) Br2 and Cl2 were mixed in a ratio of 1:15 in a 20 l bulb; total pressure 960 mbar; mixture was allowed to equilibrate for 48 h; fluorescence spectroscopy;12.3%
at -30 - 30℃; Neat (no solvent);
at -30 - 30℃;
H2O#dotNaCl#dotNaBr

H2O#dotNaCl#dotNaBr

15656-19-6

hypobromous acid

A

7726-95-6

bromine

B

13863-41-7

bromine chloride

C

7782-50-5

chlorine

Conditions
ConditionsYield
Kinetics; HOBr/He mixt. passing over doped ice at 240 K sprayed onto flow tube wall; monitoring by TOF MS;A n/a
B n/a
C 1%
15656-19-6

hypobromous acid

7647-14-5

sodium chloride

A

13863-41-7

bromine chloride

B

1310-73-2

sodium hydroxide

Conditions
ConditionsYield
In neat (no solvent) Kinetics; detected by MS;
In neat (no solvent) Kinetics;
16887-00-6

chloride

7726-95-6

bromine

A

10097-32-2

bromide

B

13863-41-7

bromine chloride

Conditions
ConditionsYield
Kinetics;
16887-00-6

chloride

7726-95-6

bromine

7782-50-5

chlorine

A

96607-00-0

BrClCl(1-)

B

13863-41-7

bromine chloride

C

trichloride(1-)

D

BrBrCl(1-)

Conditions
ConditionsYield
With NaClO4 or HClO4 In water 25°C, pH 1, const. ionic strength (NaClO4 or HClO4), equilibration; monitoring by vapour pressure measurements and spectrophotometry;
56-23-5

tetrachloromethane

7726-95-6

bromine

A

127-18-4

1,1,2,2-tetrachloroethylene

B

75-62-7

Bromotrichloromethane

C

594-18-3

dibromodichloromethane

D

67-72-1

hexachloroethane

E

13863-41-7

bromine chloride

Conditions
ConditionsYield
In tetrachloromethane other Radiation; γ-radiation of Br2 soln. in CCl4 (free from air) at 25°C; mechanism discussed;;
56-23-5

tetrachloromethane

7726-95-6

bromine

A

75-62-7

Bromotrichloromethane

B

67-72-1

hexachloroethane

C

13863-41-7

bromine chloride

Conditions
ConditionsYield
In tetrachloromethane other Radiation; γ-radiation of Br2 soln. in CCl4 (free from air); yield depends on temp.;;
10097-32-2

bromine

2696-92-6

nitrosylchloride

A

10102-43-9

nitrogen(II) oxide

B

13863-41-7

bromine chloride

Conditions
ConditionsYield
Kinetics; Discharge-flow system, ClNO in excess, He as buffer gas, Br source: Br2 and H or O or Cl in He.; Monitored by resonance fluorescence.;
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