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Detail of > 139-25-3

  • MSDS Download
  • CAS Number:
  • 139-25-3
  • Name:
  • Benzene,1,1'-methylenebis[4-isocyanato-3-methyl-

  • Formula:
  • C17H14 N2 O2
  • Molecular Structure:
  • Synonyms:
  • Isocyanicacid, methylenebis(2-methyl-p-phenylene) ester (7CI,8CI);3,3'-Dimethyldiphenylmethane 4,4'-diisocyanate;4,4'-Diisocyanato-3,3'-dimethyldiphenylmethane;4,4'-Diphenyl-3,3'-dimethylmethane diisocyanate; NSC 84203; Nacconate 310
  • Molecular Weight:
  • 278.33
  • Density:
  • 1.1 g/cm3
  • Boiling Point:
  • 410.4 °C at 760 mmHg
  • Flash Point:
  • 169.5 °C
  • Safety:
  • Poison by intravenous route. A sensitizer. When heated to decomposition it emits toxic fumes of NOx and CN.Details
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CAS No. 

139-25-3 Benzene,1,1'-methylenebis[4-isocyanato-3-methyl-

4,4'-Diisocyanato-3,3'-dimethyldiphenylmethane
China (Mainland)   12
  • Tel:021-34979012 13311639313
  • Address:shanghai

CAS No. 

139-25-3 4,4'-DIISOCYANATO-3,3'-DIMETHYLDIPHENYLMETHANE

4,4'-DIISOCYANATO-3,3'-DIMETHYLDIPHENYLMETHANE
United States   2
  • Tel:1-800-248-2436 / 1-203-932-2489
  • Address:139 ALLINGS CROSSING ROAD, WEST HAVEN CT 06516 (USA)

CAS No. 

139-25-3 4,4'-DIISOCYANATO-3,3'-DIMETHYLDIPHENYLMETHANE

4,4'-DIISOCYANATO-3,3'-DIMETHYLDIPHENYLMETHANE
China (Mainland)  
  • Tel:86-0373-6200845
  • Address:henan,china
  • Total:3 Page 1 of 1 1
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    Reference

    Reactive polyester-amide polymers as coreactants or curing agents for polyepoxides and polyisocyanates
    Reactive polyester-amide polymers as coreactants or curing agents for polyepoxides and polyisocyanates. Simon, Eli (USA ). U.S. US 4042546 16 Aug 1977,5 pp. (English). (United States of America). CODEN: USXXAM. CLASS: IC: C08G069-44. NCL: 260022000R. APPLICATION: US 76-682474 3 May 1976. DOCUMENT TYPE: Patent CA Section: 36 (Plastics Manufacture and Processing) The title polymers are prepd. from a 1:1:2 mol ratio trihydric alc.-monoamino-monohydric alc.-aliph. dibasic acid mixt., and are cured at low temps. with polyepoxides and polyisocyanates to yield tough products with usable temp. ranges -40.degree. to +200.degree.. Thus, 257 g 1:1:2 2-amino-2-butanol-glycerol-sebacic acid polymer [64386-71-6] at acid no. 40 was treated with 138 g Epon 826 [25068-38-6] (av. oxirane equil. 184) and 35 g 3,3'-dimethyldiphenylmethane 4,4'-diisocyanate [139-25-3] (isocyanate equil. 139). The compn. could be cured at <80.degree., and could be cured within 1 h at 120.degree. to yield tough, flexible products. Without the epoxy or isocyanate, a curing temp. of .apprx.200.degree. was required for the polyester-amide.
    The study of the reactivity of epoxy resins in the reactions with diisocyanates by DTA method
    The study of the reactivity of epoxy resins in the reactions with diisocyanates by DTA method. Gromakov, N. S.; Hozin, V. G.; Voskresenskii, V. A. (V. A. Voskresenskii Civ.-Eng. Inst., Kazan, USSR). Therm. Anal., [Proc. Int. Conf.], 5th, 279-82. Edited by: Chihara, H. Heyden: London, Engl. (English) 1977. CODEN: 38WRAM. DOCUMENT TYPE: Conference CA Section: 36 (Plastics Manufacture and Processing) Differential thermal anal. (DTA) and IR spectroscopy show that 2-oxazolidones and urethanes are formed when epoxy resins are treated with diisocyanates. The reactivities of the epoxy resins increased as follows: 3,4-epoxycyclohexylmethyl 3,4-epoxcyclohexanecarboxylate polymer [25085-98-7] < bisphenol A diglycidyl ether polymer [25085-99-8] < triglycidyl isocyanurate [2451-62-9] < diglycidylaniline [32144-31-3]. The reactivities of the diisocyanates increased as follows: 3,3'-dimethyl-4,4'-diphenylmethane diisocyanate [139-25-3] < 4,4'-diphenylmethane diisocyanate [101-68-8] < TDI [26471-62-5].

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