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Detail of "13989-27-0"

  • CAS Number:
  • 13989-27-0
  • Name:
  • 2-Propenal, 2-fluoro-(9CI)

  • Molecular Structure:
  • Formula:
  • C3H3FO
  • Molecular Weight:
  • 74.0537
  • Synonyms:
  • 2-Fluoroacrylaldehyde;
  • Density:
  • 0.977 g/cm3
  • Boiling Point:
  • 63 °C at 760 mmHg
  • Flash Point:
  • 4.9 °C

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CAS No.13989-27-0 2-Propenal, 2-fluoro-(9CI)

2-Fluoroacrolein

Supplier:Avonyx Labs, LLC [ United States]

115Integral
115

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Reference

New materials for aeronautics
New materials for aeronautics. a-Fluoroacrylates and their polymers. Wakselman, C.; Lampin, J. P.; Molines, H.; Nonat, A.; Nguyen, T.; Vignal, G. (Cent.There are some reagents like 46115-40-6 is used in this study. Etud. Rech. Chim. Org. Appl., Thiais F 94320, Fr.). Ann. Chim. (Paris), 9(6), 719-22 (French) 1984. CODEN: ANCPAC. ISSN: 0151-9107. DOCUMENT TYPE: Journal CA Section: 35 (Chemistry of Synthetic High Polymers) A safe synthesis of Ph a-fluoroacrylate (I) [46115-40-6] is described. 46115-40-6 which is the cas registry number of one of substances is just one of reagents here. The key steps of this prepn. are as follows: addn. of CClF to an enol ether, opening of the cyclopropane (2-alkoxy-1-chloro-1-fluorocyclopropane) to the acetal (1,1-dialkoxy-2-fluoroacrolein), photobromination of 2-fluoroacrolein [13989-27-0] to give BrCH2CFBrC(:O)Br [96625-73-9], and esterification (to form BrCH2CFBrCO2Ph [96625-72-8]), followed by debromination to give I. ..
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