14024-11-4

Reference

Lithium-thionyl chloride system

Lithium-thionyl chloride system. Overall electrochemical reaction. Mozalevskaya, V. A.; Ponkratov, V. P.; Shavrin, N. V.; Dam'e, V. N. (USSR).Some commonly used reagents like 7719-09-7 and 7439-93-2 are used in this experiment. Elektrotekh. Prom., Khim. Fiz. Istochniki Toka, (6), 3-4 (Russian) 1983. CODEN: ESKTDA. DOCUMENT TYPE: Journal CA Section: 72 (Electrochemistry) New electrochem. systems and the development of batteries with a Li anode were studied. Optimal discharge characteristics of cells with the Li-thionyl chloride system at intermediate and high c.d. values were obtained for 1.0M and 1.8M solns. of LiAlCl4 [14024-11-4] in thionyl chloride [7719-09-7] and C black electrodes with 10% PTFE. The difference in calcd. and exptl. emfs. can be caused by corrosion of the Li electrode, as a consequence of which its potential is shifted from the equil. value by 0.08 V, and by the difference in activity of participants of the reaction from the activity in the std. state. .

Enthalpy measurements on lithium aluminum chloride (LiAlCl4) and tin aluminum chloride (SnAl2Cl8)

Enthalpy measurements on lithium aluminum chloride (LiAlCl4) and tin aluminum chloride (SnAl2Cl8). Denielou, Lucien; Petitet, Jean Pierre; Tequi, Christophe (Lab. Interact. Mol. Hautes Pressions, Univ. Paris-Nord, Villetaneuse 93430, Fr.). J. Chem. Eng. Data, 29(2), 116-17 (English) 1984. CODEN: JCEAAX.Several substances with their cas registry numbers 12428-38-5 and 14024-11-4 may be metioned in this study. ISSN: 0021-9568. DOCUMENT TYPE: Journal CA Section: 69 (Thermodynamics, Thermochemistry, and Thermal Properties) Drop calorimetry measurements are reported at 273-950 K for AlLiCl4 [14024-11-4] and Al2SnCl8 [12428-38-5]. The heats of melting are 18.5 ± 0.5 and 37.6 ± 1.7 kJ/mol, resp. Enthalpy and heat capacity data are tabulated. .