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Detail of "14047-29-1"

  • MSDS Download
  • CAS Number:
  • 14047-29-1
  • Name:

  • 4-Carboxyphenylboronic acid

  • Molecular Structure:
  • Formula:
  • C7H7BO4
  • Molecular Weight:
  • 165.95
  • Synonyms:
  • Benzoic acid, p-borono-;(4-formyloxyphenyl)boronic acid;p-Carboxyphenylboronic acid;Benzoic acid, 4-borono-;4-16-00-01683 (Beilstein Handbook Reference);Benzeneboronic acid, p-carboxy-;p-Boronobenzoic acid;p-Carboxybenzeneboronic acid;Benzoic acid, p-borono- (6CI,7CI,8CI);Benzoic acid, 4-borono- (9CI);4-Carboxybenzeneboronic acid;
  • Density:
  • 1.406 g/cm3
  • Melting Point:
  • 220 °C (dec.)(lit.)
  • Boiling Point:
  • 406.383 °C at 760 mmHg
  • Flash Point:
  • 199.574 °C
  • Appearance:
  • Off-white to light beige powder
  • Hazard Symbols:
  • HarmfulXn,IrritantXi
  • Risk Codes:
  • 36/37/38-20/21/22
  • Safety:
  • 37/39-26-36 Details
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Reference

An expedient route to 3-chlorothioxanthen-9-one 10,10-dioxide and derivation by palladium-catalyzed coupling
All Rights Reserved. Several substances are used for example 87199-18-6 and 14047-29-1 which are their cas registry numbers. An expedient route to 3-chlorothioxanthen-9-one 10,10-dioxide and derivation by palladium-catalyzed coupling. Lory, Pedro M. J.; Agarkov, Anton; Gilbertson, Scott R. (Program in Chemical Biology, Department of Pharmacology & Toxicology, University of Texas-Medical Branch, Galveston, TX 77555-0650, USA). Synlett, (18), 3045-3048 (English) 2006 Georg Thieme Verlag. CODEN: SYNLES. ISSN: 0936-5214. DOCUMENT TYPE: Journal CA Section: 27 (Heterocyclic Compounds (One Hetero Atom)) Chem. was developed that allows for the synthesis of a series of novel tricyclic thioxanthen-9-one 10,10-dioxides. A regioselective synthesis of the novel core substrate 3-chlorothioxanthen-9-one 10,10-dioxide was achieved from thiophenol and 4-chloro-2-iodobenzoate in 85% yield over 3 steps without the need for chromatog. purifn. Subsequent microwave-assisted coupling methodol. afforded the desired novel 3-substituted tricyclic compds. in good to excellent yield. .
Boronic acids as versatile supramolecular reagents
All Rights Reserved. Boronic acids as versatile supramolecular reagents. Aakeroy, Christer B.; Desper, John; Levin, Brock; Salmon, Debra J. ( Dept. of Chemistry, Kansas State Univ. 28987-79-3 and 14047-29-1 are cas registry numbers. These chemicals are also mentioned in this article., Manhattan, KS 66506, USA). ACA Transactions, 39, 123-129 (English) 2004 American Crystallographic Association. URL: http://www.hwi.buffalo.edu/ACA/Publication_39/Aakeroy.pdf. CODEN: ATCRCS. DOCUMENT TYPE: Journal; (online computer file) CA Section: 75 (Crystallography and Liquid Crystals) Section cross-reference(s): 29 Crystal engineering and supramol. synthesis is governed by the structural consequences of intermol. forces, and by the way in which such interactions are used for controlling the assembly of mols. into predictable structural motifs. A vital part of crystal engineering is thus dedicated to identifying robust intermol. synthons that can be used as reliable connectors between mols. The authors describe how the H-bond capabilities of boronic acids R-B(OH)2 can be translated into versatile co-crystg. tools capable of forming heteromeric structure-directing H-bond interactions with a variety of complementary structural partners e.g. 2-aminopyrimidine and 4,4'-bipyridine. .
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