Detail of "142-96-1"

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CAS Number:
142-96-1
Name:
Butane, 1,1'-oxybis-
Superlist Name:
Di-n-butyl ether
Molecular Structure:
Formula:
C₈H₁₈O
Molecular Weight:
130.26
Synonyms:
Butyl ether(8CI);1,1'-Oxybisbutane;Butyl oxide;Dibutyl ether;Dibutyloxide;NSC 8459;n-Butyl ether;
EINECS:
205-575-3
Density:
0.78 g/cm³
Melting Point:
-98 °C(lit.)
Boiling Point:
142.1 °C at 760 mmHg
Flash Point:
25 °C
Solubility:
water: 0.03 g/100 mL (20 °C)
Appearance:
colourless liquid with ether-like odour
Hazard Symbols:
Xi
Risk Codes:
10-36/37/38-52/53
Safety:
61 Details
Transport Information:
UN 1149 3/PG 3

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Reference

Titanium trichloride catalyst component: Titanium trichloride catalyst component. Wristers, Harry J. (Exxon Research and Engineering Co. , USA). U.S. US 4431569 A 14 Feb 1984, 9 pp. Cont. of U.S. Ser. No. 102,676, abandoned. (English). (United States of America). CODEN: USXXAM. CLASS: IC: C08F004-64. NCL: 502154000. APPLICATION: US 82-377290 12 May 1982. PRIORITY: US 79-102676 12 Dec 1979. DOCUMENT TYPE: Patent CA Section: 35 (Chemistry of Synthetic High Polymers) TiCl3-contg. catalysts components, exhibiting no friability during mech. shearing and useful in the prepn. of a-olefin polymers with high heptane-insol. material content, are manufd. by redn. of TiCl4 with an organoaluminum compd. at low temp., treatment of the reduced material with 1-1000% a-olefin to obtain a prepolymd. TiCl3-reduced material, and activation with a halogenated hydrocarbon and a Lewis base complexing agent or with TiCl4 and a Lewis base complexing agent. Thus, 1100 mL heptane contg. 25587-79-5 and 67-72-1 which are cas registry numbers of chemicals are mentioned. TiCl4 250, Et2AlCl [96-10-6] 350, and EtAlCl2 [563-43-9] 117 mL was stirred 3 h at 0° and 2 h at 65° to give a heptane slurry of b-TiCl3, and propylene was polymd. in the presence of this slurry at 25°/1 psig to give a nonfriable red-violet product contg. 10% polypropylene (I) [9003-07-0]. This product (5 g) was shaken with 33.3 mL 1.75 M hexachloroethane [67-72-1] in heptane at 60° and heated 5 h with 2.95 mL Bu2O [142-96-1] at 80° to give an activated purple catalyst product. Propylene (800 mL) was polymd. in the presence of 600 mL H and 100 mg (based on TiCl3) purple catalyst and 4 mol Et2AlCl/g-atom Ti in purple catalyst to give I contg. 97.6% heptane-insol. material. .

Conversion of methanol and some other oxygen-containing compounds into aromatic hydrocarbons and components of high-octane fuel: Conversion of methanol and some other oxygen-containing compounds into aromatic hydrocarbons and components of high-octane fuel. Bragin, O. V.; Vasina, T. V.; Preobrazhenskii, A. V.; Palishkina, N. V.; Nefedov, B. K.; Polinina, E. V.; Minachev, Kh. M. (Inst. Org. Khim. im. Zelinskogo, Moscow, USSR). Izv. Akad. Nauk SSSR, Ser. Khim., (10), 2311-16 (Russian) 1983. CODEN: IASKA6. ISSN: 0002-3353. DOCUMENT TYPE: Journal CA Section: 51 (Fossil Fuels, Derivatives, and Related Products) Zeolites exchanged with group VIII metals and cryst. B2O3-contg. silicates catalyze the conversion of MeOH [67-56-1] to gaseous and liq. hydrocarbons. At 380°, the conversion of MeOH over these catalysts reaches 92-100%. A typical run over a B2O3-contg. catalyst gave 62% yield of liq. products (C5-8 alkanes 48, C6-8 aroms. 14, C9-12 aroms. 38%) and C2-4 hydrocarbons. These catalysts were also effective in the conversions of Me2O [115-10-6], Et2O [60-29-7], iso-Pr2O [108-20-3], Bu2O [142-96-1], acetone [67-64-1], and ethylene [74-85-1]. The conversions of all these compds. proceeded by the same mechanism and involved the same intermediates.

Detail of "142-96-1"

Butane, 1,1'-oxybis-

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CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

CAS No.142-96-1 Di-n-butyl ether

Reference