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14220-17-8

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Basic Information
CAS No.: 14220-17-8
Name: NICKEL POTASSIUM CYANIDE
Molecular Structure:
Molecular Structure of 14220-17-8 (NICKEL POTASSIUM CYANIDE)
Formula: C4N4 Ni . 2 K
Molecular Weight: 240.99
Synonyms: Nickelate(2-),tetracyano-, dipotassium (8CI);Nickelate(2-), tetrakis(cyano-C)-, dipotassium,(SP-4-1)-;Nickelate(2-), tetrakis(cyano-kC)-, dipotassium, (SP-4-1)- (9CI);Potassiumtetracyanonickelate(II) (6CI,7CI);Dipotassium nickel tetracyanide;Dipotassiumtetracyanonickelate;Dipotassium tetracyanonickelate(2-);Dipotassiumtetrakis(cyano)nickelate;Potassium nickel cyanide [K2Ni(CN)4];Potassiumtetracyanonickelate;
EINECS: 238-082-7
Density: g/cm3
Melting Point: 100°C -H₂O
Boiling Point: 25.7°Cat760mmHg
Flash Point: °C
Solubility: soluble H2O [MER06]
Hazard Symbols:
Risk Codes: 49-15/29-22-42/43
Safety: Confirmed human carcinogen. Poison by ingestion. When heated to decomposition it emits very toxic fumes of NOx, K2O, and CN−. See also NICKEL COMPOUNDS and CYANIDE.
PSA: 95.16000
LogP: 0.06712
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Chemistry

IUPAC Name: Dipotassium nickel(2+) tetracyanide
CAS: 14220-17-8
The Molecular formula of Dipotassium nickel(2+) tetracyanide (CAS NO.14220-17-8): C4K2N4Ni
The Molecular Weight of Dipotassium nickel(2+) tetracyanide (CAS NO.14220-17-8): 240.96
The Molecular Structure of Dipotassium nickel(2+) tetracyanide (CAS NO.14220-17-8):

Melting Point: 100°C
Density: 1.875 g/cm3
Boiling Point: 25.7 °C at 760 mmHg 
Vapour Pressure: 740 mmHg at 25°C 
Product Categories: inorganics

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 oral 275mg/kg (275mg/kg)   Journal of Pharmaceutical Sciences. Vol. 52, Pg. 59, 1963.

Consensus Reports

NTP 10th Report on Carcinogens. Nickel and its compounds, as well as cyanide and its compounds, are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

Safety Profile

Confirmed human carcinogen. Poison by ingestion. When heated to decomposition it emits very toxic fumes of NOx, K2O, and CN−. See also NICKEL COMPOUNDS and CYANIDE.
Safety Information about Dipotassium nickel(2+) tetracyanide (CAS NO.14220-17-8):
Hazard Codes: 
T:
Risk Statements about Dipotassium nickel(2+) tetracyanide (CAS NO.14220-17-8): 
R15/29: Contact with water liberates toxic, extremely flammable gas.
R22: Harmful if swallowed.
R42/43: May cause sensitization by inhalation and skin contact.
R49:   May cause cancer by inhalation.
Safety Statements about Dipotassium nickel(2+) tetracyanide (CAS NO.14220-17-8): 
S22: Do not breathe dust.
S36/37: Irritating to eyes and respiratory system.
S43: May cause sensitization by skin contact.
S45: May cause cancer.
S53: May cause long-term adverse effects in the aquatic environment.
F10: Keep under argon.
F21: Sensitive to humidity.
RIDADR: UN 1588 6.1/PG 2
WGK Germany: 3
RTECS: QR8650000
HazardClass: 6.1(b)
PackingGroup: III

Standards and Recommendations

OSHA PEL: TWA 0.1 mg (Ni)/m3
ACGIH TLV: TWA 0.2 mg(Ni)/m3; Human Carcinogen
NIOSH REL: (Inorganic Nickel) TWA 0.015 mg(Ni)/m3
DOT Classification:  6.1; Label: Poison, KEEP AWAY FROM FOOD

Specification

  Dipotassium nickel(2+) tetracyanide with CAS number of 14220-17-8 is also known as Potassium nickel cyanide ; Potassium tetracyanonickelate ; Potassium tetracyanonickelate (II) ; Nickel potassium cyanide ; Dipotassium tetracyanoniccolate ; Potassium tetracyanonickelate(II), 99.99% metals basis ; Nickelate(2-), tetrakis(cyano-.kappa.C)-, dipotassium, (SP-4-1)- ; Nickelpotassiumcyanide,crystal,purified .