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14245-62-6

Basic Information
CAS No.: 14245-62-6
Name: Ethanesulfonic acid isopropyl ester
Article Data: 6
Molecular Structure:
Molecular Structure of 14245-62-6 (Ethanesulfonic acid isopropyl ester)
Formula: C5H12 O3 S
Molecular Weight: 152.214
Synonyms: Ethanesulfonicacid, isopropyl ester (7CI,8CI); Isopropyl ethanesulfonate
Density: 1.096g/cm3
Boiling Point: 236.8°Cat760mmHg
Flash Point: 97°C
Safety: Mutation data reported. When heated to decomposition it emits toxic vapors of SOx.
PSA: 51.75000
LogP: 1.84190
Synthetic route
67-63-0

isopropyl alcohol

594-44-5

Ethanesulfonyl chloride

14245-62-6

isopropyl ethanesulfonate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 3h;75%
With triethylamine In dichloromethane for 0.333333h;60%
With 2,6-dimethylpyridine; sulfuric acid for 2.5h; Ambient temperature;48%
With triethylamine In dichloromethane at 20℃; Rate constant;
683-60-3

sodium isopropylate

594-44-5

Ethanesulfonyl chloride

14245-62-6

isopropyl ethanesulfonate

926-06-7

isopropyl methanesulfonate

74-88-4

methyl iodide

14245-62-6

isopropyl ethanesulfonate

Conditions
ConditionsYield
(i) nBuLi, hexane, THF, (ii) /BRN= 969135/; Multistep reaction;
14245-62-6

isopropyl ethanesulfonate

814-49-3

diethyl chlorophosphate

1311290-66-0

1-(diethylphosphono)ethanesulfonic acid isopropyl ester

Conditions
ConditionsYield
Stage #1: isopropyl ethanesulfonate With n-butyllithium In tetrahydrofuran at -78℃; for 0.333333h;
Stage #2: diethyl chlorophosphate In tetrahydrofuran at -78℃; for 0.5h;
58%
14245-62-6

isopropyl ethanesulfonate

74-88-4

methyl iodide

27907-12-6

2-propyl 2-propanesulfonate ester

Conditions
ConditionsYield
(i) nBuLi, hexane, THF, (ii) /BRN= 969135/; Multistep reaction;
1083-48-3

4-Nitrobenzylpyridin

14245-62-6

isopropyl ethanesulfonate

Ethanesulfonate1-isopropyl-4-(4-nitro-benzyl)-pyridinium;

Conditions
ConditionsYield
With phosphate buffer; water In acetone at 37℃; Product distribution; pH 6.0;
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    propan-2-yl ethanesulfonate CAS NO.14245-62-6

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    Product details ProName: propan-2-yl ethanesulfonate CasNo: 14245-62-6 Molecular Formula: C5H12O3S Appearance: powder Application: Pharmaceutical Intermediates DeliveryTime: within 2-3 days after payment PackAge: foil b

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Chemistry

IUPAC Name: Propan-2-yl ethanesulfonate
Synonyms of Isopropyl ethanesulfonate (CAS NO.14245-62-6) : Ethanesulfonic acid, 1-methylethyl ester (9CI) ; Ethanesulfonic acid, isopropyl ester ; Isopropyl ethanesulfonate
CAS NO:14245-62-6
Molecular Formula:C5H12O3S
Molecular Weight :152.212
Molecular Structure :
Index of Refraction:1.428
Surface Tension: 32.4 dyne/cm
Density: 1.096 g/cm3
Flash Point: 97 °C
Enthalpy of Vaporization: 45.44 kJ/mol
Boiling Point: 236.8 °C at 760 mmHg
Vapour Pressure: 0.0714 mmHg at 25°C

Uses

 Isopropyl ethanesulfonate (CAS NO.14245-62-6) is used as  intermediate in organic synthesis.

Toxicity Data With Reference

1.    

mic-sat 12 mmol/L

    CPBTAL    Chemical and Pharmaceutical Bulletin. 32 (1984),3626.

Safety Profile

Mutation data reported. When Isopropyl ethanesulfonate (CAS NO.14245-62-6) is heated to decomposition ,it emits toxic vapors of SOx.