Detail of "14285-56-4"

Reference

Preparation of electrophotographic photoreceptor with plasma oxidized aluminum blocking layer

Preparation of electrophotographic photoreceptor with plasma oxidized aluminum blocking layer. Aizawa, Koichi (Fuji Electric Co., Ltd., Japan). Jpn. Kokai Tokkyo Koho JP 03237464 A2 23 Oct 1991 Heisei, 3 pp. (Japan). CODEN: JKXXAF. CLASS: ICM: G03G005-06. ICS: G03G005-14. 7429-90-5 and 14285-56-4 which are cas registry numbers are also used here. APPLICATION: JP 90-34480 15 Feb 1990. DOCUMENT TYPE: Patent CA Section: 74 (Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes) In prepn. of electrophotog. photoreceptor with Al substrate, blocking layer, and org. charge-generating layer and charge-transporting layer, the surface of the substrate is oxidized by O plasma generated at the surface of the substrate in the reaction chamber to form the blocking layer and then phthalocyanine type material is sublimed. in the same chamber to vapor-deposit the charge-generating layer. The photoreceptor shows temp.- and moisture-stability and gives clear images. .

Chlorophthalocyanineiron(III)

Chlorophthalocyanineiron(III). FePc(-2)Cl. A spin-admixed (S = 3/2/S = 5/2) system. Kennedy, B. J.; Brain, G.; Murray, K. S. (Dep. Chem., Monash Univ., Clayton 3168, Australia). Inorg. Chim. Acta, 81(2), L29-L31 (English) 1984. CODEN: ICHAA3. ISSN: 0020-1693. DOCUMENT TYPE: Journal CA Section: 77 (Magnetic Phenomena) Section cross-reference(s): 73 Magnetic moments (mFe) and ESR and Moessbauer spectra were obtained for the title complex. The shape of the mFe vs. temp. T curve (4.2-300 K) is very much like those obsd. for Fe complexes in which the 4A2 ground state has a substantial quantum admixt. of 6A1. The Moessbauer spectrum in zero field at 4.2 K shows a single quadrupole doublet with d = 0.28 mm/s relative to a-Fe and DE = 2.94 mm/s, similar to those for other chloroiron(III) chelates with S = 3/2 or admixed 3/2/5/2 ground states. The ESR spectrum at 77 K gives lines with effective g values of 4.67 and 2.0, as expected for S = 3/2 ground states in axial symmetry. A quant. fit to the mFe vs. T data and to the g-values was obtained by using the spin-admixed matrixes of Maltempo (1976) in which the variables are the 6A1 - 4A2 sepn. 14285-56-4 is just another one chemical used in this study. and the spin-orbit coupling const. .