Detail of "14562-04-0"

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CAS Number:
14562-04-0
Name:
Acetonitrile,2-[[(4-methylphenyl)sulfonyl]oxy]-
Superlist Name:
Cyanomethyl p-toluenesulfonate
Molecular Structure:
Formula:
C9H9 N O3 S
Molecular Weight:
211.2377
Synonyms:
Acetonitrile,[[(4-methylphenyl)sulfonyl]oxy]- (9CI); Glycolonitrile, p-toluenesulfonate(7CI); Glycolonitrile, p-toluenesulfonate (ester) (8CI); Cyanomethyl4-methylbenzenesulfonate; Cyanomethyl p-toluenesulfonate; Cyanomethylp-tosylate; Cyanomethyl toluenesulfonate; Cyanomethyl tosylate;Toluene-4-sulfonic acid cyanomethyl ester
EINECS:
238-604-3
Density:
1.29 g/cm³
Boiling Point:
393.6 °C at 760 mmHg
Flash Point:
191.9 °C
Appearance:
Colorless and transparent liquid

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2-Alkylthiomethyl-4-hydroxypyrimidines: 2-Alkylthiomethyl-4-hydroxypyrimidines. Maurer, Fritz (Bayer A.-G. , Fed. Rep. Ger.). Ger. Offen. DE 3247926 A1 28 Jun 1984, 16 pp. (German). (Germany). CODEN: GWXXBX. CLASS: IC: C07D239-36; C07D239-52. APPLICATION: DE 82-3247926 24 Dec 1982. DOCUMENT TYPE: Patent CA Section: 28 (Heterocyclic Compounds (More Than One Hetero Atom)) The title compds. (I; R = alkyl; R1 = H, alkyl; R2 = H, alkyl, alkoxy; R1R2 = alkylene) were prepd. by cyclocondensation of R1COCHR2CO2R3 (R3 = alkyl), R4SO3CH2CN [R4 = alkyl, haloalyl, (un)substituted Ph], and NH4Cl in the presence of RSM (M = alkali metal). There are some commonly used reagents like 14562-04-0 in this article. Thus, to a soln. of 4-MeC6H4SO3CH2CN and MeONa in MeOH were added NH4Cl, MeSH, and MeCOCHMeCO2Et and the mixt. stirred 18 h at room temp. to give 70% I (R-R2 = Me). I are intermediates for insecticides. .