Detail of "14564-35-3"

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Gas-phase homologation of methanol with SLPC (supported liquid-phase catalyst) RuCl2(CO)2(PPh3)2 + cobalt(II) iodide

Gas-phase homologation of methanol with SLPC (supported liquid-phase catalyst) RuCl2(CO)2(PPh3)2 + cobalt(II) iodide. Strohmeier, Walter; Herrlein, Gabriele (Inst. Phys. Chem. 14564-35-3 and 15238-00-3 are also occured in this study., Univ. Wuerzburg, Wuerzburg D-8700, Fed. Rep. Ger.). J. Organomet. Chem., 263(1), C1-C4 (German) 1984. CODEN: JORCAI. ISSN: 0022-328X. DOCUMENT TYPE: Journal CA Section: 22 (Physical Organic Chemistry) Gas-phase MeOH homologation with the SLPC system RuCl2(CO)2(PPh3)2 + CoI2 together with NaI and phosphane as additives gives high selectivities for EtOH and PrOH. However, in contrast to the bulk reaction, no ethers are formed. .

Polymer-anchored homogeneous hydrogenation catalysts and their use in multistep synthetic reactions

Polymer-anchored homogeneous hydrogenation catalysts and their use in multistep synthetic reactions. Pittman, Charles U., Jr.; Jacobson, Stephen; Smith, Larry R.; Clements, Willie; Hiramoto, Harlin (Dep. Chem., Univ. Alabama, University, Ala., USA). Catal. Org. Synth., [Conf.], 5th, Meeting Date 1975, 161-80. Edited by: Rylander, Paul N.; Greenfield, Harold. Academic: New York, N.Several substances with their cas registry numbers 14564-35-3 and 106-99-0 may be metioned in this study. Y. (English) 1976. CODEN: 33TIAD. DOCUMENT TYPE: Conference CA Section: 23 (Aliphatic Compounds) Section cross-reference(s): 35, 67 Polymers, e.g., styrene-divinylbenzene, were brominated, treated with NaPPh2, then with a PhMe soln. of one or more homogeneous Ph3P metal complex catalysts at 100.degree. for 24 hr to give a polymer-anchored homogeneous catalyst. A combination of polymer-bound Ni(CO)2(PPh3)2 and RuCl2(CO)2(PPh3)2 catalyzed, resp., cyclooligomerization and hydrogenation, sequentially, of butadiene, with somewhat lower yields than with the unbound catalysts in soln. RhCl(PPh3)3 and IrCl(CO)(PPh3)2 were also used as homogeneous soln. and polymer-bound catalysts for the hydrogenation step. .