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1461-23-0

Basic Information
CAS No.: 1461-23-0
Name: Tri-n-butyltin bromide
Article Data: 157
Molecular Structure:
Molecular Structure of 1461-23-0 (Tri-n-butyltin bromide)
Formula: C12H27 Br Sn
Molecular Weight: 369.96
Synonyms: Tin,bromotributyl- (7CI); Tributyltin bromide (6CI); Bromotributylstannane;Bromotributyltin; NSC 202816; Tributylbromostannane; Tributylstannyl bromide
EINECS: 215-959-2
Density: 1,338 g/cm3
Melting Point: <0°C
Boiling Point: 302.1 °C at 760 mmHg
Flash Point: 136.5 °C
Hazard Symbols: VeryT+
Risk Codes: 34-26/27/28
Safety: 26-36/37/39-45-23
PSA: 0.00000
LogP: 5.72710
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Chemistry

IUPAC Name: Bromo(tributyl)stannane 
Molecular Formula: C12H27Sn•Br
Molecular Weight: 369.96g/mol
EINECS: 215-959-2
Density: 1.338 g/cm3
Melting Point: <0°C
Boiling Point: 302.1 °C at 760 mmHg
Flash Point: 136.5 °C
Freely Rotating Bonds: 9
Polar Surface Area: 0 Å2
Enthalpy of Vaporization: 52.07 kJ/mol
Vapour Pressure: 0.00181 mmHg at 25°C 
Sensitive: moisture sensitive
The Cas Register Number of Tri-n-butyltin bromide is 1461-23-0.The chemical synonyms of Tri-n-butyltin bromide (CAS NO.1461-23-0) are Bromotributyltin;tributyltin bromide ; Tri-n-butylbromotin ; Tri-n-butyltin bromide ; Bromotributyl-stannan;tributylbromo-stannan ; Tributylstanniumbromide ; Tri-n-butyl-tibromide .The molecular structure of Tri-n-butyltin bromide (CAS NO.1461-23-0) is.

Uses

 Tri-n-butyltin bromide (CAS NO.1461-23-0) is used as bactericide.

Toxicity Data With Reference

1.    

ihl-mus LCLo:1030 mg/m3

    NDRC**    National Defense Research Committee, Office of Scientific Research and Development, Progress Report NDCrc-132,Feb ,1942.
2.    

orl-rbt LD50:100 µg/kg

    85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,1250.
3.    

skn-rbt LDLo:935 mg/kg

    SAIGBL    Sangyo Igaku. Japanese Journal of Industrial Health. 15 (1973),3.

Safety Profile

A poison by ingestion. Moderately toxic by skin contact and inhalation. When heated to decomposition it emits toxic fumes of Br. See also BROMIDES and TIN COMPOUNDS.
Hazard Codes: VeryT+
Risk Statements: 34-26/27/28 
R34:Causes burns. 
R26/27/28: Very toxic by inhalation, in contact with skin and if swallowed.
Safety Statements: 26-36/37/39-45-23 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S23:Do not breathe vapour.
RIDADR: 1760
RTECS: WH6735000
TSCA: No
HazardClass: 6.1
PackingGroup: II
 

Standards and Recommendations

OSHA PEL: TWA 0.1 mg(Sn)/m3 (skin)
ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin).
NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3

Analytical Methods

For occupational chemical analysis use NIOSH: Organotin Compounds 5504.