Detail of "14630-42-3"

CAS Number:
14630-42-3
Name:
Silane,(3,3-dimethyl-1-butyn-1-yl)trimethyl-
Molecular Structure:
Formula:
C9H18 Si
Molecular Weight:
154.32
Synonyms:
Silane,(3,3-dimethyl-1-butynyl)trimethyl- (7CI,8CI,9CI);(3,3-Dimethyl-1-butynyl)trimethylsilane; 1-(Trimethylsilyl)-3,3-dimethyl-1-butyne;1-(tert-Butyl)-2-(trimethylsilyl)acetylene;3,3-Dimethyl-1-(trimethylsilyl)-1-butyne; tert-Butyl(trimethylsilyl)acetylene
Density:
0.786g/cm³
Boiling Point:
129.7°Cat760mmHg
Flash Point:
12.2°C
Safety:
Risk Statements 11-36/37/38
Safety Statements 16-26-36/37/39
RIDADR 1993
HazardClass 3.1
PackingGroup II
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Regioselective synthesis of substituted pyrroles: efficient palladium-catalyzed cyclization of internal alkynes and 2-amino-3-iodoacrylate derivatives: All Rights Reserved. In this study， 918827-39-1 and 14630-42-3 are also used. Regioselective synthesis of substituted pyrroles: efficient palladium-catalyzed cyclization of internal alkynes and 2-amino-3-iodoacrylate derivatives. Crawley, Matthew L.; Goljer, Igor; Jenkins, Douglas J.; Mehlmann, John F.; Nogle, Lisa; Dooley, Rebecca; Mahaney, Paige E. (Discovery Medicinal Chemistry and Discovery Analytical Chemistry, Wyeth Research, Collegeville, PA 19426, USA). Organic Letters, 8(25), 5837-5840 (English) 2006 American Chemical Society. CODEN: ORLEF7. ISSN: 1523-7060. DOCUMENT TYPE: Journal CA Section: 27 (Heterocyclic Compounds (One Hetero Atom)) The efficient and regioselective palladium-catalyzed cyclization of internal alkynes and 2-amino-3-iodoacrylates provided highly functionalized pyrroles, e.g., I, in moderate to excellent yields. This approach was applicable to a range of alkynes and afforded the deacylated pyrroles under reaction conditions for most substrates. .