Detail of "1466-88-2"

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CAS Number:
1466-88-2
Name:
2-Propenal,3-(2-nitrophenyl)-
Molecular Structure:
Formula:
C₉H₇NO₃
Molecular Weight:
177.16
Synonyms:
Cinnamaldehyde,o-nitro- (6CI,7CI,8CI);2-Nitrocinnamaldehyde;2-Nitrocinnamic aldehyde;3-(2-Nitrophenyl)-2-propenal;3-(2-Nitrophenyl)propenal;NSC 28458;o-Nitrocinnamaldehyde;
EINECS:
215-988-0
Density:
1.269g/cm³
Melting Point:
127-129 °C(lit.)
Boiling Point:
348.1 °C at 760 mmHg
Flash Point:
178.1 °C
Appearance:
light yellow to yellow-brown crystals or powder
Hazard Symbols:
Xi
Risk Codes:
36/38
Safety:
26-36 Details

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Bis[N,N'-bis(2-nitrocinnamaldehyde)phenylenediimine]copper(I) perchlorate: All Rights Reserved. Bis[N,N'-bis(2-nitrocinnamaldehyde)phenylenediimine]copper(I) perchlorate. Hadjikhani, Ramin; Dehghanpour, Saeed; Mahmoudia, Ali; Mojahed, Fresia (Faculty of Science, Islamic Azad University, Karaj, Iran).In this study， 1466-88-2 and 918548-44-4 are also used. Zeitschrift fuer Anorganische und Allgemeine Chemie, 632(5), 723-725 (English) 2006 Wiley-VCH Verlag GmbH & Co. KGaA. CODEN: ZAACAB. ISSN: 0044-2313. DOCUMENT TYPE: Journal CA Section: 78 (Inorganic Chemicals and Reactions) Section cross-reference(s): 25, 75 The complex [CuL2]ClO4 (L = bis(2-nitrophenylpropenylidenimino)benzene) crystallizes in the triclinic space group P1 with a = 13.167(1), b = 13.209(1), c = 14.465(1) ?, a = 83.209(9)°, b = 68.438(2)°, g = 70.803(2)°, V = 2209.4(3) ?3, Z = 2, Dcalc = 1.527 mg/m3. The coordination polyhedron about the Cu(I) atom is best described as a distorted tetrahedron. The Schiff ligand L acts as a bidentate ligand coordinating via two N atoms to the copper. The four Cu-N distances are 2.04(2), 2.038(2), 2.046(2) and 2.062(2) ?. .

Physicochemical study of complex compounds of tin and titanium tetrachlorides with o- and p-nitrocinnamic aldehydes: Physicochemical study of complex compounds of tin and titanium tetrachlorides with o- and p-nitrocinnamic aldehydes. Zolotareva, G. I.; Verkhovodova, D. Sh. (USSR). Vopr. Khim., 2, 3-8 (Russian) 1974. CODEN: VOKHDV. DOCUMENT TYPE: Journal CA Section: 78 (Inorganic Chemicals and Reactions) Section cross-reference(s): 22 The complex-forming ability of SnCl4 and TiCl4 with o- and p-nitrocinnamic aldehydes and the nature of the coordination bonding in the complexes were studied by IR absorption spectroscopy and dipole moment measurements. The results indicate that the introduction of a nitro group into the benzene ring causes a larger mesomeric effect and weakens the donor properties of the CO group. The complex-forming ability of SnCl4 is greater than that of TiCl4. 61818-93-7 and 1466-88-2 are just another two chemicals used in this study. .