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Detail of "1468-39-9"

  • MSDS Download
  • CAS Number:
  • 1468-39-9
  • Name:
  • Butanoic acid,3-methyl-,1,1'-anhydride

  • Molecular Structure:
  • Formula:
  • C10H18O3
  • Molecular Weight:
  • 186.25
  • Synonyms:
  • 3-Methylbutanoic anhydride;Butanoicacid,3-methyl-,anhydride;3-Methylbutanoyl 3-methylbutanoate;
  • EINECS:
  • 215-994-3
  • Density:
  • 0.955 g/cm3
  • Melting Point:
  • -65 °C
  • Boiling Point:
  • 215 °C at 760 mmHg
  • Flash Point:
  • 91.3 °C
  • Solubility:
  • Can be hydrolyzed
  • Appearance:
  • Colorless liquid
  • Hazard Symbols:
  • ToxicT
  • Risk Codes:
  • 24-34
  • Safety:
  • 26-36/37/39-45 Details
  • Transport Information:
  • UN 2922

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Reference

Murrayatin, a coumarin from Murraya exotica
Murrayatin, a coumarin from Murraya exotica. Barik, Bikash Ranjan; Dey, Ashesh Kumar; Chatterjee, Asima (Chem. Res. Unit, Univ. Coll. Sci., Calcutta, India).In this article, certain chemicals are used. Some of their cas registry numbers are 1468-39-9 and 5875-49-0 Phytochemistry, 22(10), 2273-5 (English) 1983. CODEN: PYTCAS. ISSN: 0031-9422. DOCUMENT TYPE: Journal CA Section: 11 (Plant Biochemistry) Murrayatin (I) was isolated from the leaves of M. exotica and its structure was detd. by chem. and spectral methods and by prepn. .
Stereoselective synthesis of (+)-blastmycinone
Stereoselective synthesis of (+)-blastmycinone. Fujisawa, Tamotsu; Kohama, Hiromasa; Tajima, Kazuhisa; Sato, Toshio (Chem. Dep. 1468-39-9 are also occured in this study. Resourc., Mie Univ., Tsu 514, Japan). Tetrahedron Lett., 25(45), 5155-6 (English) 1984. CODEN: TELEAY. ISSN: 0040-4039. DOCUMENT TYPE: Journal CA Section: 26 (Biomolecules and Their Synthetic Analogs) (+)-Blastmycinone (I) was prepd. diastereoselectively from (2R,3S)-2-hydroxy-3-(1-propenyl)heptanoic acid by the ester enolate Claisen rearrangement of (R)-(E)-1-methyl-2-heptenyl glycolate and stereoselective redn. of (3R,4S)-MeCOCH(OH)CHBuCH:CHMe with Zn(BH4)2. .
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