Detail of "1468-39-9"
- MSDS Download

- CAS Number:
- 1468-39-9
- Name:
Butanoic acid,3-methyl-,1,1'-anhydride
- Molecular Structure:

- Formula:
- C10H18O3
- Molecular Weight:
- 186.25
- Synonyms:
- 3-Methylbutanoic anhydride;Butanoicacid,3-methyl-,anhydride;3-Methylbutanoyl 3-methylbutanoate;
- EINECS:
- 215-994-3
- Density:
- 0.955 g/cm3
- Melting Point:
- -65 °C
- Boiling Point:
- 215 °C at 760 mmHg
- Flash Point:
- 91.3 °C
- Solubility:
- Can be hydrolyzed
- Appearance:
- Colorless liquid
- Hazard Symbols:
T- Risk Codes:
- 24-34
- Safety:
- 26-36/37/39-45 Details
- Transport Information:
- UN 2922

Butanoic acid,3-methyl-,1,1'-anhydride

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Reference
- Murrayatin, a coumarin from Murraya exotica
- Murrayatin, a coumarin from Murraya exotica. Barik, Bikash Ranjan; Dey, Ashesh Kumar; Chatterjee, Asima (Chem. Res. Unit, Univ. Coll. Sci., Calcutta, India).In this article, certain chemicals are used. Some of their cas registry numbers are 1468-39-9 and 5875-49-0 Phytochemistry, 22(10), 2273-5 (English) 1983. CODEN: PYTCAS. ISSN: 0031-9422. DOCUMENT TYPE: Journal CA Section: 11 (Plant Biochemistry) Murrayatin (I) was isolated from the leaves of M. exotica and its structure was detd. by chem. and spectral methods and by prepn. .
- Stereoselective synthesis of (+)-blastmycinone
- Stereoselective synthesis of (+)-blastmycinone. Fujisawa, Tamotsu; Kohama, Hiromasa; Tajima, Kazuhisa; Sato, Toshio (Chem. Dep. 1468-39-9 are also occured in this study. Resourc., Mie Univ., Tsu 514, Japan). Tetrahedron Lett., 25(45), 5155-6 (English) 1984. CODEN: TELEAY. ISSN: 0040-4039. DOCUMENT TYPE: Journal CA Section: 26 (Biomolecules and Their Synthetic Analogs) (+)-Blastmycinone (I) was prepd. diastereoselectively from (2R,3S)-2-hydroxy-3-(1-propenyl)heptanoic acid by the ester enolate Claisen rearrangement of (R)-(E)-1-methyl-2-heptenyl glycolate and stereoselective redn. of (3R,4S)-MeCOCH(OH)CHBuCH:CHMe with Zn(BH4)2. .

